EN

基本情報

研究

社会活動

その他の活動

劒 隼人

Tsurugi Hayato

基礎工学研究科 物質創成専攻,准教授

keyword 有機合成化学,触媒化学,錯体化学,有機金属化学

研究内容・専門分野

  • ナノテク・材料,無機・錯体化学
  • ナノテク・材料,有機合成化学

論文

  • Syntheses of SGLT2 Inhibitors by Ni- and Pd-Catalyzed Fukuyama Coupling Reactions,Vol. 85,No. 19,p. 12382-12392,2020年10月02日,研究論文(学術雑誌)
  • Self-Assembled Multilayer Iron(0) Nanoparticle Catalyst for Ligand-Free Carbon–Carbon/Carbon–Nitrogen Bond-Forming Reactions,Vol. 22,No. 18,p. 7244-7249,2020年09月18日,研究論文(学術雑誌)
  • Trivalent Rare-earth Metal Amide Complexes as Catalysts for Hydrosilylation of Benzophenone Derivatives with HN(SiHMe2)2 via Amine Exchange Reaction.,2020年07月07日,研究論文(学術雑誌)
  • Cerium(IV) Carboxylate Photocatalyst for Catalytic Radical Formation from Carboxylic Acids: Decarboxylative Oxygenation of Aliphatic Carboxylic Acids and Lactonization of Aromatic Carboxylic Acids.,Vol. 142,No. 12,p. 5668-5675,2020年03月25日,研究論文(学術雑誌)
  • Chromium-catalyzed cyclopropanation of alkenes with bromoform in the presence of 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-dihydropyrazine,Vol. 11,No. 14,p. 3604-3609,2020年03月11日,研究論文(学術雑誌)
  • Synthesis, Structure, and Reactivity of Dicationic Bimetallic Tetrabenzyldihafnium Complexes Bearing a Chelating (2-Hydroxyethyl)amido Ligand,Vol. 39,No. 4,p. 614-622,2020年02月24日,研究論文(学術雑誌)
  • Cobalt-Catalyzed E-Selective Cross-Dimerization of Terminal Alkynes: A Mechanism Involving Cobalt(0/II) Redox Cycles,Vol. 59,No. 4,p. 1552-1556,2020年01月20日,研究論文(学術雑誌)
  • Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules,Vol. 407,p. 213118-213118,2020年01月14日,研究論文(学術雑誌)
  • 4,4'-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron,Hiromu Hosoya,Luis C. Misal Castro,Ibrahim Sultan,Yumiko Nakajima,Toshimichi Ohmura,Kazuhiko Sato,Hayato Tsurugi,Michinori Suginome,Kazushi Mashima,Org. Lett.,American Chemical Society,Vol. 21,No. 24,p. 9812-9817,2019年12月,研究論文(学術雑誌)
  • Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the N═N Bond of 2,2′-Azopyridine: Precursors for Early–Late Heterobimetallic Complexes,Kento Kawakita,Yuya Kakiuchi,Evan P. Beaumier,Ian A. Tonks,Hayato Tsurugi,Kazushi Mashima,Inorg. Chem.,American Chemical Society,Vol. 58,No. 22,p. 15155-15165,2019年11月,研究論文(学術雑誌)
  • Synthesis and Characterization of Alkoxide-Bridged Heterometallic Clusters of Cerium and Copper,Hayato Tsurugi,Yuri Ikeda,Koichi Shinohara,Satoru Shirase,Nozomi Toya,Shinji Tanaka,Kazushi Mashima,Inorg. Chem.,American Chemical Society,Vol. 58,No. 19,p. 12565-12572,2019年10月,研究論文(学術雑誌)
  • α-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride,Bernard F. Parker,Hiromu Hosoya,John Arnold,Hayato Tsurugi,Kazushi Mashima,Inorg. Chem.,American Chemical Society,Vol. 58,No. 19,p. 12825-12831,2019年10月,研究論文(学術雑誌)
  • Metal-free Reductive Deoxygenation of Sulfoxides by an Organosilicon Reductant, 1,1-Bis(trimethylsilyl)-1H,1 ' H-4,4 '-bipyridinylidene,Vol. 48,No. 8,p. 888-890,2019年08月,研究論文(学術雑誌)
  • Hydrodehalogenation of Alkyl Halides Catalyzed by a Trichloroniobium Complex with a Redox Active α-Diimine Ligand,Haruka Nishiyama,Hiromu Hosoya,Bernard,F. Parker,John Arnold,Hayato Tsurugi,Kazushi Mashima,Chem. Commun.,Royal Society of Chemistry,Vol. 55,No. 50,p. 7247-7250,2019年06月,研究論文(学術雑誌)
  • Salt-Free Reduction of Transition Metal Complexes by Bis(trimethylsilyl)cyclohexadiene, -dihydropyrazine, and -4,4′-bipyridinylidene Derivatives,Hayato Tsurugi,Kazushi Mashima,Acc. Chem. Res.,American Chemical Society,Vol. 52,No. 3,p. 769-779,2019年03月
  • Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles,Kento Kawakita,Evan P. Beaumier,Yuya Kakiuchi,Hayato Tsurugi,Ian A. Tonks,Kazushi Mashima,J. Am. Chem. Soc.,American Chemical Society,Vol. 141,No. 10,p. 4194-4198,2019年03月,研究論文(学術雑誌)
  • Cβ–Cβ Bond Fission of Metallacyclopentadiene over a Low-Valent Ditantalum Scaffold,Payel Laskar,Keishi Yamamoto,Kohei Nishi,Hideaki Ikeda,Hayato Tsurugi,Kazushi Mashima,Organometallics,American Chemical Society,Vol. 38,No. 3,p. 722-729,2019年02月,研究論文(学術雑誌)
  • Nickel-catalyzed cyanation of aryl halides and triflates using acetonitrile via C–CN bond cleavage assisted by 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine,Yohei Ueda,Nagataka Tsujimoto,Taiga Yurino,Hayato Tsurugi,Kazushi Mashima,Chem. Sci.,Royal Society of Chemistry,Vol. 10,No. 4,p. 994-999,2019年01月,研究論文(学術雑誌)
  • A New Protocol to Generate Catalytically Active Species of Group 4 ‐ 6 Metals by Organosilicon‐based Salt‐free Reductants,Hayato Tsurugi,Kazushi Mashima,Chem. Eur. J.,Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim,Vol. 25,No. 4,p. 913-919,2019年01月,研究論文(学術雑誌)
  • Activation of O2 by Organosilicon Reagents Yields Quantitative Amounts of H2O2 or (Me3Si)2O2 for Efficient O‐Transfer Reactions,Keishi Yamamoto,Shinji Tanaka,Hiromu Hosoya,Hayato Tsurugi,Kazushi Mashima,Christophe Copéret,Helv. Chim. Acta,Wiley‐VHCA AG, Zurich, Switzerland,Vol. 101,No. 12,2018年12月,研究論文(学術雑誌)
  • In Situ Catalyst Generation and Benchtop-Compatible Entry Points for TiII/TiIV Redox Catalytic Reactions,Zachary W. Davis-Gilbert,Kento Kawakita,Daniel R. Blechschmidt,Hayato Tsurugi,Kazushi Mashima,Ian A. Tonks,Organometallics,American Chemical Society,Vol. 37,No. 23,p. 4439-4445,2018年12月,研究論文(学術雑誌)
  • Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex,Tobias Schindler,Albert Paparo,Haruka Nishiyama,Thomas P. Spaniol,Hayato Tsurugi,Kazushi Mashima,Jun Okuda,Dalton Trans.,Royal Society of Chemistry,Vol. 47,No. 38,p. 13328-13331,2018年10月,研究論文(学術雑誌)
  • Bonding and structural features of metal-metal bonded homo- and hetero-dinuclear complexes supported by unsaturated hydrocarbon ligands,Vol. 869,p. 251-263,2018年08月,研究論文(学術雑誌)
  • Metal‐free Deoxygenation and Reductive Disilylation of Nitroarenes by Organosilicon Reducing Reagents,Argha Bhattacharjee,Hiromu Hosoya,Hideaki Ikeda,Kohei Nishi,Hayato Tsurugi,Kazushi Mashima,Chem. Eur. J.,Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim,Vol. 24,No. 44,p. 11278-11282,2018年08月,研究論文(学術雑誌)
  • Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Oxo-bridged Dinuclear Cerium Complexes with Pentadentate Schiff-base Ligands under Dioxygen Atmosphere,Satoru Shirase,Koichi Shinohara,Hayato Tsurugi,Kazushi Mashima,ACS Catal.,American Chemical Society,Vol. 8,No. 8,p. 6939-6947,2018年08月,研究論文(学術雑誌)
  • Functionalization of the C—H Bond of N-Heteroaromatics Assisted by Early Transition Metal Complexes,Haruki Nagae,Abhinanda Kundu,Mariko Inoue,Hayato Tsurugi,Kazushi Mashima,Asian J. Org. Chem.,Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim,Vol. 7,No. 7,p. 1256-1269,2018年07月
  • Planar and Bent BN-Embedded p-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane,Mao Noguchi,Katsunori Suzuki,Jun Kobayashi,Taiga Yurino,Hayato Tsurugi,Kazushi Mashima,Makoto Yamashita,Organometallics,American Chemical Society,Vol. 37,No. 12,p. 1833-1836,2018年06月,研究論文(学術雑誌)
  • Direct ortho-C—H Aminoalkylation of 2-Substituted Pyridine Derivatives Catalyzed by Yttrium Complexes with N,Nʹ-Diarylethylenediamido Ligands,Abhinanda Kundu,Mariko Inoue,Haruki Nagae,Hayato Tsurugi,Kazushi Mashima,J. Am. Chem. Soc.,American Chemical Society,Vol. 140,No. 23,p. 7332-7342,2018年06月,研究論文(学術雑誌)
  • Metathesis cleavage of an N=N bond in benzo[c]cinnolines and azobenzenes by triply-bonded ditungsten complexes,Vol. 54,No. 30,p. 3709-3711,2018年04月,研究論文(学術雑誌)
  • Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis,Vol. 54,No. 32,p. 3989-3992,2018年04月,研究論文(学術雑誌)
  • Lanthanide Complexes Supported by a Trizinc Crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO2: Telomerization Controlled by Carboxylate Anions,Vol. 57,No. 9,p. 2492-2496,2018年02月,研究論文(学術雑誌)
  • Organosilicon Reducing Reagents for Stereoselective Formations of Silyl Enol Ethers from alpha-Halo Carbonyl Compounds,Vol. 83,No. 4,p. 2409-2417,2018年02月,研究論文(学術雑誌)
  • Multiply-bonded dinuclear complexes of early-transition metals as minimum entities of metal cluster catalysts,Vol. 355,p. 223-239,2018年01月
  • Dehalogenation of vicinal dihalo compounds by 1,1 '-bis(trimethylsilyl)-1H, 1 ' H-4,4 '- bipyridinylidene for giving alkenes and alkynes in a salt-free manner,Vol. 53,No. 98,p. 13157-13160,2017年12月,研究論文(学術雑誌)
  • Tantallacyclopentadiene as a unique metal-containing diene ligand coordinated to nickel for preparing tantalum-nickel heterobimetallic complexes,Vol. 46,No. 38,p. 13043-13054,2017年10月,研究論文(学術雑誌)
  • Propargylic C(sp(3))-H Bond Activation for Preparing eta(3)-Propargyl/Allenyl Complexes of Yttrium,Vol. 36,No. 16,p. 3061-3067,2017年08月,研究論文(学術雑誌)
  • Structural and Electronic Noninnocence of alpha-Diimine Ligands on Niobium for Reductive C-Cl Bond Activation and Catalytic Radical Addition Reactions,Vol. 139,No. 18,p. 6494-6505,2017年05月,研究論文(学術雑誌)
  • Inorganic-Salt-Free Reduction in Main-Group Chemistry: Synthesis of a Dibismuthene and a Distibene,Vol. 36,No. 7,p. 1224-1226,2017年04月,研究論文(学術雑誌)
  • Arylimido-Bridged Dinuclear Ti(mu-NAr)(2)Ti Scaffold for Alkyne Insertion into the ortho-C-H Bond of Arylimido Ligands,Vol. 23,No. 3,p. 586-596,2017年01月,研究論文(学術雑誌)
  • Mixed Ligated Tris(amidinate)dimolybdenum Complexes as Catalysts for Radical Addition of CCl4 to 1-Hexene: Leaving Ligand Lability Controls Catalyst Activity,Vol. 56,No. 1,p. 634-644,2017年01月,研究論文(学術雑誌)
  • C(sp(3))-H Alkenylation Catalyzed by Cationic Alkylhafnium Complexes: Stereoselective Synthesis of Trisubstituted Alkenes from 2,6-Dimethylpyridines and Internal Alkynes,Vol. 35,No. 22,p. 3816-3827,2016年11月,研究論文(学術雑誌)
  • Synthesis and Characterization of Heterobimetallic Tantalum-Rhodium and Tantalum-Iridium Complexes Connected by a Tantalacyclopentadiene Fragment,Vol. 99,No. 11,p. 848-858,2016年11月,研究論文(学術雑誌)
  • Low Temperature Activation of Supported Metathesis Catalysts by Organosilicon Reducing Agents,Vol. 2,No. 8,p. 569-576,2016年08月,研究論文(学術雑誌)
  • Synthesis and Reactions of Ditantalum-Allyl Complexes Derived from Intramolecular C-H Bond Activation of the Methylene of the Ethyl Group Bound to Ditantallacyclopentadiene,Vol. 35,No. 14,p. 2384-2390,2016年07月,研究論文(学術雑誌)
  • Alkyne-Induced Facile C-C Bond Formation of Two eta(2)-Alkynes on Dinuclear Tantalum Bis(alkyne) Complexes To Give Dinuclear Tantalacyclopentadienes,Vol. 35,No. 10,p. 1573-1581,2016年05月,研究論文(学術雑誌)
  • Reversible Transformation between Alkylidene, Alkylidyne, and Vinylidene Ligands in High-Valent Bis(phenolate) Tungsten Complexes,Vol. 35,No. 7,p. 932-935,2016年04月,研究論文(学術雑誌)
  • Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On -Peroxo Dicerium(IV) Complex,Vol. 22,No. 12,p. 4008-4014,2016年03月,研究論文(学術雑誌)
  • Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids,Vol. 22,No. 12,p. 3956-3961,2016年03月,研究論文(学術雑誌)
  • Synthesis and Characterization of Paramagnetic Tungsten Imido Complexes Bearing alpha-Diimine Ligands,Vol. 55,No. 4,p. 1446-1452,2016年02月,研究論文(学術雑誌)
  • Recent Developments in Homogeneous Organomagnesium Catalysis,Vol. 8,No. 1,p. 10-20,2016年01月,研究論文(学術雑誌)
  • Mechanistic understanding of alkyne cyclotrimerization on mononuclear and dinuclear scaffolds: [4+2] cycloaddition of the third alkyne onto metallacyclopentadienes and dimetallacyclopentadienes,Vol. 45,No. 43,p. 17072-17081,2016年,研究論文(学術雑誌)
  • Salt- Free Reduction of Nonprecious Transition- Metal Compounds: Generation of Amorphous Ni Nanoparticles for Catalytic C-C Bond Formation,Vol. 54,No. 48,p. 14437-14441,2015年11月,研究論文(学術雑誌)
  • Cerium(IV) Hexanuclear Clusters from Cerium(III) Precursors: Molecular Models for Oxidative Growth of Ceria Nanoparticles,Vol. 21,No. 38,p. 13454-13461,2015年09月,研究論文(学術雑誌)
  • Direct Evidence for a [4+2] Cycloaddition Mechanism of Alkynes to Tantallacyclopentadiene on Dinuclear Tantalum Complexes as a Model of Alkyne Cyclotrimerization,Vol. 21,No. 32,p. 11369-11377,2015年08月,研究論文(学術雑誌)
  • Reduction of ((BuN)-Bu-t=)NbCl3(py)(2) in a Salt-Free Manner for Generating Nb(IV) Dinuclear Complexes and Their Reactivity toward Benzo[c]cinnoline,Vol. 54,No. 12,p. 6004-6009,2015年06月,研究論文(学術雑誌)
  • Organomagnesium-Catalyzed Isomerization of Terminal Alkynes to Allenes and Internal Alkynes,Vol. 21,No. 22,p. 8112-8120,2015年05月,研究論文(学術雑誌)
  • Synthesis of Alkyl and Alkylidene Complexes of Tungsten Bearing Imido and Redox-Active a-Diimine or o-Iminoquinone Ligands and Their Application as Catalysts for Ring-Opening Metathesis Polymerization of Norbornene,Vol. 34,No. 4,p. 731-741,2015年02月,研究論文(学術雑誌)
  • Non-bridged half-metallocene complexes of group 4-6 metals with chelating ligands as well-defined catalysts for alpha-olefin polymerization,Vol. 47,No. 1,p. 2-17,2015年01月
  • Aminomethylation Reaction of ortho-Pyridyl C-H Bonds Catalyzed by Group 3 Metal Triamido Complexes,Vol. 137,No. 2,p. 640-643,2015年01月,研究論文(学術雑誌)
  • 2,2 '-Bipyridyl formation from 2-arylpyridines through bimetallic diyttrium intermediate,Vol. 6,No. 10,p. 5394-5399,2015年,研究論文(学術雑誌)
  • Mixed-ligand complexes of paddlewheel dinuclear molybdenum as hydrodehalogenation catalysts for polyhaloalkanes,Vol. 6,No. 6,p. 3434-3439,2015年,研究論文(学術雑誌)
  • 1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes as Strong Salt-Free Reductants for Generating Low-Valent Early Transition Metals with Electron-Donating Ligands,Vol. 136,No. 13,p. 5161-5170,2014年04月,研究論文(学術雑誌)
  • Supramolecular assemblies of multi-nuclear transition metal complexes: Synthesis and redox properties,Vol. 265,p. 38-51,2014年04月
  • Direct functionalization of unactivated C-H bonds catalyzed by group 3-5 metal alkyl complexes,Vol. 43,No. 6,p. 2331-2343,2014年,研究論文(学術雑誌)
  • Hemilabile N-Xylyl-N '-methylperimidine Carbene Iridium Complexes as Catalysts for C-H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C-H Bond Activation and Reductive Bond Cleavage,Vol. 135,No. 35,p. 13149-13161,2013年09月,研究論文(学術雑誌)
  • C-H Metalation Reaction of Diarylamine and Carbazole by Alkylaluminum Complexes at the Heteroatom-Bridged Dimeric Aluminum Core,Vol. 2013,No. 22-23,p. 3821-3825,2013年08月,研究論文(学術雑誌)
  • Salt-Free Reducing Reagent of Bis(trimethylsilyl)cyclohexadiene Mediates Multielectron Reduction of Chloride Complexes of W(VI) and W(IV),Vol. 135,No. 16,p. 5986-5989,2013年04月,研究論文(学術雑誌)
  • Synthesis of Rare-Earth-Metal Iminopyrrolyl Complexes from Alkyl Precursors: Ln -> Al N-Ancillary Ligand Transfer,Vol. 32,No. 5,p. 1199-1208,2013年03月,研究論文(学術雑誌)
  • Tetraplatinum cluster complexes bearing hydrophilic anchors as precursors for gamma-Al2O3-supported platinum nanoparticles,Vol. 42,No. 35,p. 12662-12666,2013年,研究論文(学術雑誌)
  • Isospecific polymerization of 1-hexene by C-1-symmetric half-metallocene dimethyl complexes of group 4 metals with bidentate N-substituted iminomethylpyrrolyl ligands,Vol. 42,No. 25,p. 9120-9128,2013年,研究論文(学術雑誌)
  • Dianion and Monoanion Ligation of 1,4-Diaza-1,3-butadiene to Barium, Strontium, and Calcium,Vol. 31,No. 8,p. 3178-3184,2012年04月,研究論文(学術雑誌)
  • Synthesis of Ir[mu 2-(N-N)]M (M = Ir and Ru) Homo- and Heterobimetallic Complexes through a Condensation Reaction of N-Amino and Formyl Groups Bound to Mononuclear (eta n-CnMen)M Units (n=5 for M = Ir; n=6 for M = Ru),No. 9,p. 1469-1476,2012年03月,研究論文(学術雑誌)
  • Preparation and Structure of Iminopyrrolyl and Amidopyrrolyl Complexes of Group 2 Metals,Vol. 31,No. 6,p. 2268-2274,2012年03月,研究論文(学術雑誌)
  • Diene Dissolution of the Heavier Alkaline Earth Metals,No. 6,p. 998-1003,2012年02月,研究論文(学術雑誌)
  • End-Functionalized Polymerization of 2-Vinylpyridine through Initial C-H Bond Activation of N-Heteroaromatics and Internal Alkynes by Yttrium Ene-Diamido Complexes,Vol. 133,No. 49,p. 19626-19629,2011年12月,研究論文(学術雑誌)
  • Carbon Radical Generation by d(0) Tantalum Complexes with alpha-Diimine Ligands through Ligand-Centered Redox Processes,Vol. 133,No. 46,p. 18673-18683,2011年11月,研究論文(学術雑誌)
  • Synthesis and Reaction of Neutral and Cationic Alkyltantalum Complexes with a Linked Cyclopentadienyl-Carboranyl Ligand,Vol. 30,No. 21,p. 5960-5964,2011年11月,研究論文(学術雑誌)
  • Reactivity of Permethylated Magnesium Complexes toward beta-Diimines,Vol. 30,No. 14,p. 3818-3825,2011年07月,研究論文(学術雑誌)
  • Oxidant-Free Direct Coupling of Internal Alkynes and 2-Alkylpyridine via Double C-H Activations by Alkylhafnium Complexes,Vol. 133,No. 4,p. 732-735,2011年02月,研究論文(学術雑誌)
  • Dinuclear molybdenum cluster-catalyzed radical addition and polymerization reactions by tuning the redox potential of a quadruple bonded Mo-2 core,Vol. 40,No. 37,p. 9358-9361,2011年,研究論文(学術雑誌)
  • First isolation of fully delocalized mixed-valent imido-bridged [Ti-2](7+) complexes by one-electron reduction of [(C5R5)TiCl](2)(mu-NAr)(2),Vol. 47,No. 19,p. 5620-5622,2011年,研究論文(学術雑誌)
  • Carboxylate Ligand-Induced Intramolecular C-H Bond Activation of Iridium Complexes with N-Phenylperimidine-Based Carbene Ligands,Vol. 29,No. 18,p. 4120-4129,2010年09月,研究論文(学術雑誌)
  • Intramolecular Alkylation of alpha-Diimine Ligands Giving Amido-Imino and Diamido Scandium and Yttrium Complexes as Catalysts for Intramolecular Hydroamination/Cyclization,Vol. 29,No. 15,p. 3463-3466,2010年08月,研究論文(学術雑誌)
  • Salt Metathesis and Direct Reduction Reactions Leading to Group 3 Metal Complexes with a N,N '-Bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene Ligand and Their Solid-State Structures,Vol. 29,No. 11,p. 2610-2615,2010年06月,研究論文(学術雑誌)
  • Silicon-Bridged Tetramethylcyclopentadienyl-Phenoxy Complexes of Tantalum: Preparation and Alkylation of Et2Si(eta(5)-C5Me4)(3-Bu-t-5-Me-2-C6H2O)TaCl3 and Generation of Its Cationic Complex,Vol. 29,No. 9,p. 2080-2084,2010年05月,研究論文(学術雑誌)
  • Rational Design of Silicon-Bridged Fluorenyl-Phenoxy Group 4 Metal Complexes as Catalysts for Producing High Molecular Weight Copolymers of Ethylene and 1-Hexene at Elevated Temperature,Vol. 43,No. 5,p. 2299-2306,2010年03月,研究論文(学術雑誌)
  • Copper-Mediated Direct Cross-Coupling of 1,3,4-Oxadiazoles and Oxazoles with Terminal Alkynes,Vol. 16,No. 6,p. 1772-1775,2010年,研究論文(学術雑誌)
  • Highly Reactive Metal-Nitrogen Bond Induced C-H Bond Activation and Azametallacycle Formation,Vol. 29,No. 1,p. 34-37,2010年01月,研究論文(学術雑誌)
  • Rhodium/Phosphine/Amine center dot HBr Catalyst System for Highly Selective Cross-Cyclodimerization of Aryl- and Alkylalkynes: Efficient Access to Multisubstituted Naphthalene Derivatives,Vol. 16,No. 2,p. 445-449,2010年,研究論文(学術雑誌)
  • Titanium Complexes of Silicon-Bridged Cyclopentadienyl-Phenoxy Ligands Modified with Fused-Thiophene: Synthesis, Characterization, and Their Catalytic Performance in Copolymerization of Ethylene and 1-Hexene,Vol. 28,No. 24,p. 6915-6926,2009年12月
  • Substituent Effects on Silicon of Bridged Tetramethylcyclopentadienyl-Phenoxy Titanium Complexes for Controlling the Regiochemistry and Molecular Weight in 1-Olefin Polymerization,Vol. 42,No. 21,p. 8006-8009,2009年11月,研究論文(学術雑誌)
  • Synthesis and Characterization of Proximal Dinuclear Complexes of Palladium Supported by 2,6-Bis(arylimino)phenoxy (aryl = 2,6-diisopropylphenyl and 2,4,6-tri-tert-butylphenyl) and 3,6-Bis(imino(2,6-diisopropylphenyl))pyridazine Ligands,Vol. 28,No. 11,p. 3256-3263,2009年06月,研究論文(学術雑誌)
  • New Tantalum Ligand-Free Catalyst System for Highly Selective Trimerization of Ethylene Affording 1-Hexene: New Evidence of a Metallacycle Mechanism,Vol. 131,No. 15,p. 5370-+,2009年04月,研究論文(学術雑誌)
  • Tantalum-Benzylidene Complexes Supported by C5Me5 and Diazadiene Ligands: Synthesis, Kinetic Analysis of the Formation, and Reactive Studies,Vol. 28,No. 6,p. 1950-1960,2009年03月,研究論文(学術雑誌)
  • Controlled Benzylation of alpha-Diimine Ligands Bound to Zirconium and Hafnium: An Alternative Method for Preparing Mono- and Bis(amido)M(CH2Ph)(n) (n=2, 3) Complexes as Catalyst Precursors for Isospecific Polymerization of alpha-Olefins,Vol. 28,No. 3,p. 680-687,2009年02月,研究論文(学術雑誌)
  • Ligand-Controlled Cross-Dimerization and -Trimerization of Alkynes under Nickel Catalysis,Vol. 350,No. 14-15,p. 2274-2278,2008年10月,研究論文(学術雑誌)
  • Rhodium-catalyzed regioselective arylation of phenylazoles and related compounds with arylboron reagents via C - H bond cleavage,Vol. 693,No. 14,p. 2438-2442,2008年07月,研究論文(学術雑誌)
  • Rhodium-catalyzed anti selective cross-addition of bis(trimethylsilyl)-acetylene to diarylacetylenes via carbon-silicon bond cleavage,Vol. 10,No. 9,p. 1751-1754,2008年05月,研究論文(学術雑誌)
  • Palladium-catalyzed perarylation of 3-thiophene- and 3-furancarboxylic acids accompanied by C-H bond cleavage and decarboxylation,Vol. 10,No. 9,p. 1851-1854,2008年05月,研究論文(学術雑誌)
  • Regioselective C-H functionalization directed by a removable carboxyl group: Palladium-catalyzed vinylation at the unusual position of indole and related heteroaromatic rings,Vol. 10,No. 6,p. 1159-1162,2008年03月,研究論文(学術雑誌)
  • Copper-mediated direct arylation of benzoazoles with aryl iodides,Vol. 49,No. 10,p. 1598-1600,2008年03月,研究論文(学術雑誌)
  • Palladium/phosphite-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives,Vol. 73,No. 4,p. 1590-1592,2008年02月,研究論文(学術雑誌)
  • Palladium/phosphite or phosphate catalyzed oxidative coupling of arylboronic acids with alkynes to produce 1,4-diaryl-1,3-butadienes,Vol. 350,No. 3,p. 509-514,2008年02月,研究論文(学術雑誌)
  • Rhodium-catalyzed oxidative coupling between salicylaldehydes and internal alkynes with C-H bond cleavage to produce 2,3-disubstituted chromones,Vol. 3,No. 5,p. 881-886,2008年,研究論文(学術雑誌)
  • Fluorescent naphthyl- and anthrylazoles from the catalytic coupling of phenylazoles with internal alkynes through the cleavage of multiple, C-H bonds,Vol. 47,No. 21,p. 4019-4022,2008年,研究論文(学術雑誌)
  • Rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes via successive C-H and C-C bond cleavages,Vol. 73,No. 1,p. 298-300,2008年01月,研究論文(学術雑誌)
  • Catalytic Synthesis of Oligoene and Enyne Derivatives through Carbometalation of Internal Alkynes,Vol. 8,No. 5,p. 326-336,2008年,研究論文(学術雑誌)
  • Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes,No. 29,p. 3405-3407,2008年,研究論文(学術雑誌)
  • Benzylation of alpha-diimine ligands bound to zirconium and hafnium. A new convenient route to olefin polymerization catalysts,Vol. 36,No. 12,p. 1420-1421,2007年12月,研究論文(学術雑誌)
  • Synthesis of alkylated benzo[2,1-b : 3,4-b ']dithiophenes by annulative coupling and their direct arylation under palladium catalysis,Vol. 36,No. 11,p. 1336-1337,2007年11月,研究論文(学術雑誌)
  • Rhodium-catalyzed selective cross-coupling of internal alkynes with a terminal silylacetylene,Vol. 36,No. 7,p. 830-831,2007年07月,研究論文(学術雑誌)
  • Regio- and stereoselective cross-coupling of tert-propargyl alchols with bis(trimethylsilyl)acetylene and its utilization in constructing a fluorescent donor-acceptor system,Vol. 9,No. 11,p. 2231-2233,2007年05月,研究論文(学術雑誌)
  • Preparation and characterization of a zwitterionic (iminopyrrolyl) zirconium complex with benzylaluminate anion and its catalytic performance for 1-hexene polymerization,Vol. 25,No. 22,p. 5210-5212,2006年10月,研究論文(学術雑誌)
  • Preparation and characterization of iminopyrrolyl hafnium complexes as catalyst precursors for alpha-olefin polymerization,Vol. 254,No. 1-2,p. 131-137,2006年07月,研究論文(学術雑誌)
  • Synthesis, structure, and reactivity of tantalum and tungsten homoenolate complexes,Vol. 25,No. 13,p. 3179-3189,2006年06月
  • Neutral versus cationic Group 3 metal alkyl catalysts: performance in intramolecular hydroamination/cyclisation,No. 9,p. 1157-1161,2006年,研究論文(学術雑誌)
  • Uniqueness and versatility of iminopyrrolyl ligands for transition metal complexes,Vol. 690,No. 20,p. 4414-4423,2005年10月,研究論文(学術雑誌)
  • Intramolecular benzylation of an imino group of tridentate 2,5-bis(N-aryliminomethyl)pyrrolyl ligands bound to zirconium and hafnium gives amido-pyrrolyl complexes that catalyze ethylene polymerization,Vol. 23,No. 11,p. 2797-2805,2004年05月,研究論文(学術雑誌)
  • Synthesis and structural characterization of 2,5-Bis(N-aryliminomethyl)pyrrolyl complexes of aluminum,Vol. 76,No. 10,p. 1965-1968,2003年10月,研究論文(学術雑誌)
  • Unusual enhancement of ethylene polymerization activity of benzyl zirconium complexes by benzylation of the imino moiety of 2-(N-aryliminomethyl)pyrrolyl ligand,Vol. 32,No. 8,p. 756-757,2003年08月,研究論文(学術雑誌)

MISC

  • 視覚的に解析できる速度論解析法,長江春樹,劒隼人,真島和志,化学,Vol. 74,No. 8,2019年08月01日
  • Iron(0) nanoparticle-catalyzed ligand-free C-C/C-N bond forming tandem reaction,Vol. 257,2019年03月,研究発表ペーパー・要旨(国際会議)
  • Lanthanoidkomplexe mit Trizink-Kronenether als Katalysatoren für die alternierende Copolymerisation von Epoxid und CO2 : eine durch Carboxylat-Anionen kontrollierte Telomerisierung,Haruki Nagae,Ryota Aoki,Shin-nosuke Akutagawa,Julian Kleemann,Risa Tagawa,Tobias Schindler,Gyeongshin Choi,Thomas P. Spaniol,Hayato Tsurugi,Jun Okuda,Kazushi Mashima,Angewandte Chemie,Wiley-Blackwell,Vol. 130,No. 9,2018年02月
  • 有機ケイ素化合物による固体担持単一分子種の還元によるオレフィンメタセシス触媒の開発と活性種生成メカニズムの解明,長江 春樹,劒 隼人,真島 和志,生産と技術,Vol. 69,No. 2,p. 53-58,2017年
  • Catalytic aerobic oxidation of alcohols catalyzed by cerium complexes supported by a pentadentate Schiff-base ligand,Shirase S,Tsurugi H,Mashima K,Abstracts of Papers of the American Chemical Society,Vol. 253,2017年
  • Hydroalkylation of internal alkynes via C(sp3)-H bond activation of 2,6-dimethyl-N-heterocycles by cationic alkylhafnium complexes supported by dianionic multidentate ligands,Lopez M,Kondo A,Yamamoto K,Tsurugi H,Mashima K,Abstracts of Papers of the American Chemical Society,Vol. 251,2016年
  • Hydroalkylation of alkynes via C(sp3)-H bond activation of 2,6-lutidine by alkylhafnium complexes with tridentate nitrogen-based ligands,Vol. 249,2015年03月,研究発表ペーパー・要旨(国際会議)
  • Dehydrogenative silylation catalyzed by iridium complexes with hemilabile neutral and monoanioic perimidine-based carbene ligands,Vol. 246,2013年09月,研究発表ペーパー・要旨(国際会議)
  • Reductive cleavage of carbon-halogen bonds mediated by (a-diimine)MCl3 (M = Ta and Nb) complexes through ligand-based redox events,Vol. 244,2012年08月,研究発表ペーパー・要旨(国際会議)
  • C-H bond activation of imine-based substrates by (acetate)iridium complexes with perimidine-based carbene ligands,Vol. 244,2012年08月,研究発表ペーパー・要旨(国際会議)
  • Synthesis and reactivity of 1,4-diaza-1,3-butadiene complexes of group 3 metals,Vol. 242,2011年08月,研究発表ペーパー・要旨(国際会議)
  • Redox behavior of group 5 metal complexes with 1,4-diaza-1,3-butadiene ligands and their activity for carbon-halogen bond activation,Vol. 241,2011年03月,研究発表ペーパー・要旨(国際会議)
  • Coupling reaction of 2-alkylpyridine with alkynes catalyzed by alkylhafnium complexes,Vol. 241,2011年03月,研究発表ペーパー・要旨(国際会議)
  • Substituent Effects on Silicon of Bridged Tetramethylcyclopentadienyl-Phenoxy Titanium Complexes for Controlling the Regiochemistry and Molecular Weight in I-Olefin Polymerization (vol 42, pg 8006, 2009),Vol. 43,No. 11,p. 5162-5162,2010年06月
  • ChemInform Abstract: Ligand-Controlled Cross-Dimerization and -Trimerization of Alkynes under Nickel Catalysis.,Naoto Matsuyama,Hayato Tsurugi,Tetsuya Satoh,Masahiro Miura,ChemInform,Wiley-Blackwell,Vol. 40,No. 8,2009年02月
  • ChemInform Abstract: Rhodium-Catalyzed (E)-Selective Cross-Dimerization of Terminal Alkynes.,Takashi Katagiri,Hayato Tsurugi,Tetsuya Satoh,Masahiro Miura,ChemInform,Wiley-Blackwell,Vol. 39,No. 47,2008年11月
  • Rhodium-Catalyzed Selective Cross-Coupling of Internal Alkynes with a Terminal Silylacetylene.,Takashi Katagiri,Hayato Tsurugi,Atsushi Funayama,Tetsuya Satoh,Masahiro Miura,ChemInform,Wiley-Blackwell,Vol. 38,No. 50,2007年
  • Synthesis and reactivity of tantalum and tungsten homoenolate complexes,Vol. 230,p. U2218-U2218,2005年08月,研究発表ペーパー・要旨(国際会議)
  • Neutral versus cationic rare earth alkyl complexes complexes: Relative stability and catalytic activity.,Vol. 229,p. U1100-U1100,2005年03月,研究発表ペーパー・要旨(国際会議)
  • Selective formation of homoleptic and heteroleptic 2,5-bis(N-aryliminomethyl)pyrrolyl yttrium complexes and their catalytic performance as initiators of epsilon-caprolactone polymerization.,Vol. 222,p. U586-U586,2001年08月,研究発表ペーパー・要旨(国際会議)
  • 3座ビスイミノピロリル配位子をもつイットリウム錯体 : 選択的錯形成とラクトンの重合,松尾 豊,剱 隼人,真島 和志,谷 一英,希土類 = Rare earths,No. 38,p. 62-63,2001年05月02日

著書

  • 視覚的に解析できる速度論解析法,長江 春樹,劒 隼人,真島 和志,化学同人,2019年07月