杉本 秀樹

Sugimoto Hideki

工学研究科 応用化学専攻,准教授


  • Oxido-alcoholato/thiolato-molybdenum(VI) complexes with a dithiolene ligand generated by oxygen atom transfer to the molybdenum(IV) complexes,Vol. 485,p. 42-48,2019年01月24日,研究論文(学術雑誌)
  • Structure and Reactivity of Copper Complexes Supported by a Bulky Tripodal N4 Ligand: Copper(I)/Dioxygen Reactivity and Formation of a Hydroperoxide Copper(II) Complex,Sayantan Paria,Takehiro Ohta,Yuma Morimoto,Hideki Sugimoto,Takashi Ogura,Shinobu Itoh,Z. Anorg. Allg. Chem. (ZAAC),Weiley,Vol. 644,p. 780-789,2018年10月,研究論文(学術雑誌)
  • 2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry,Shinobu Itoh,Tsukasa Abe,Yuma Morimoto,Hideki Sugimoto,Inorg. Chim. Acta,Elsevier,Vol. 481,p. 38-46,2018年06月
  • Copper(I)–Dioxygen Reactivity in the Isolated Cavity of a Nanoscale Molecular Architecture,Vol. 2018,No. 19,p. 1976-1983,2018年05月24日,研究論文(学術雑誌)
  • Non-innocent Ligand in Rhodium(III) Complex Catalyzed C–H Bond Amination with Tosyl Azide,Daiki Fujita,Hideki Sugimoto,Yuma Morimoto,Shinobu Itoh,Inorg. Chem.,ACS,Vol. 57,No. 16,p. 9738-9747,2018年05月,研究論文(学術雑誌)
  • Osmium Complexes Coordinated with Poly(pyridylmethyl)diamine-Based Hexadentate Ligands,Vol. 2018,No. 2,p. 178-185,2018年01月23日,研究論文(学術雑誌)
  • Geometric Effects on O–O Bond Scission of Copper(II)-alkylperoxide Complexes,Tsukasa Abe,Yuma Morimoto,Kaoru Mieda,Hideki Sugimoto,Nobutaka Fujieda,Takashi Ogura,Shinobu Itoh,J. Inorg. Biochem.,Elseviel,Vol. 177,p. 375-383,2017年12月01日,研究論文(学術雑誌)
  • 生体模倣型オスミウム錯体を触媒とするアルケンの酸化的変換反応,杉本秀樹,伊東 忍,有機合成化学協会誌,有機合成化学協会,Vol. 75,No. 9,p. 929-940,2017年09月
  • Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a Tris-tetramethylguanidinato Ligand,Vol. 56,No. 16,p. 9634-9645,2017年08月,研究論文(学術雑誌)
  • Generation and characterisation of a stable nickel(II)-aminoxyl radical complex,Vol. 46,No. 25,p. 8013-8016,2017年07月,研究論文(学術雑誌)
  • Catalytic C–H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium(III) center,Daiki Fujita,Hideki Sugimoto,Yoshihito Shiota,Yuma Morimoto,Kazunari Yoshizawa,Shinobu Itoh,Chem. Comm.,イギリス王立化学会,Vol. 53,No. 35,p. 4849-4852,2017年05月,研究論文(学術雑誌)
  • A Well-Defined Osmium-Cupin Complex: Hyperstable Artificial Osmium Peroxygenase,Vol. 139,No. 14,p. 5149-5155,2017年04月,研究論文(学術雑誌)
  • Oxidative Cyclization of 1,5-Dienes with Hydrogen Peroxide Catalyzed by an Osmium(III) Complex: Synthesis of cis- Tetrahydrofurans,Hideki Sugimoto,Takayuki Kanetake,Kazuki Maeda,Shinobu Itoh,Org. Lett.,Vol. 18,No. 6,p. 1246-1249,2016年03月,研究論文(学術雑誌)
  • A Model for the Active-Site Formation Process in DMSO Reductase Family Molybdenum Enzymes Involving Oxido−Alcoholato and Oxido−Thiolato Molybdenum(VI) Core Structures,Hideki Sugimoto,Masanori Sato,Kaori Asano,Takeyuki Suzuki,Kaoru Mieda,Takashi Ogura,Takashi Matsumoto,Logan J. Giles,Amrit Pokhrel,Martin L. Kirk,Shinobu Itoh,Inorg. Chem.,Vol. 55,No. 4,p. 1542-1550,2016年02月15日,研究論文(学術雑誌)
  • Redox-Triggered Helicity Inversion in Chiral Cobalt Complexes in Combination with H+ and NO3– Stimuli,Janusz Gregolinski,Masahiro Hikita,Tatsuya Sakamoto,Hideki Sugimoto,Hiroshi Tsukube,Hiroyuki Miyake,Inorganic Chemistry,Vol. 55,p. 633-643,2016年02月,研究論文(学術雑誌)
  • Generation, Characterization, and Reactivity of a CuII-Alkylperoxide/Anilino Radical Complex: Insight into the O−O Bond Cleavage Mechanism,Sayantan Paria,Takehiro Ohta,Yuma Morimoto,Takashi Ogura,Hideki Sugimoto,Nobutaka Fujieda,Kei Goto,Kaori Asano,Takeyuki Suzuki,Shinobu Itoh,J. Am. Chem. Soc.,Vol. 137,No. 34,p. 10870-10873,2015年08月,研究論文(学術雑誌)
  • cis-1,2-Aminohydroxylation of Alkenes Involving a Catalytic Cycle of Osmium(III) and Osmium(V) Centers: Os-V(O)(NHTs) Active Oxidant with a Macrocyclic Tetradentate Ligand,Vol. 54,No. 14,p. 7073-7082,2015年07月,研究論文(学術雑誌)
  • Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands,Vol. 137,No. 18,p. 5867-5870,2015年05月,研究論文(学術雑誌)
  • Redox behavior of novel nickel and palladium complexes supported by trianionic non-innocent ligand containing β-diketiminate and phenol groups,Yuma Morimoto,June Takaichi,Shinichi Hanada,Kei Ohkubo,Hideki Sugimoto,Nobutaka Fujieda,Shunichi Fukuzumi,Shinobu Itoh,J. Porphyrins Phthalocyanines,Vol. 19,p. 377-387,2015年03月,研究論文(学術雑誌)
  • Geometric Control of Nuclearity in Copper(I)/Dioxygen Chemistry,Vol. 53,No. 16,p. 8786-8794,2014年08月,研究論文(学術雑誌)
  • Redox chemistry of nickel(II) complexes supported by a series of noninnocent β-diketiminate ligands,Takaichi J,Morimoto Y,Ohkubo K,Shimokawa C,Hojo T,Mori S,Asahara H,Sugimoto H,Fujieda N,Nishiwaki N,Fukuzumi S,Itoh S,Inorganic Chemistry,Vol. 53,No. 12,p. 6159-6169,2014年06月,研究論文(学術雑誌)
  • Copper complexes supported by an N2S-tridentate ligand as active site models of copper monooxygenases,Tetsuro Tano,Hideki Sugimoto,Shinobu Itoh,Dalton Trans.,イギリス王立化学会,Vol. 43,No. 12,p. 4871-4877,2014年03月,研究論文(学術雑誌)
  • Osmium(III) and Osmium(V) Complexes Bearing a Macrocyclic Ligand: A Simple and Efficient Catalytic System for cis-Dihydroxylation of Alkenes with Hydrogen Peroxide,Hideki Sugimoto,Kenji Ashikari,Shinobu Itoh,Chemistry Asian Journal,Vol. 8,p. 2154-2160,2013年10月,研究論文(学術雑誌)
  • Redox properties of a mononuclear copper(II)-superoxide complex,Vol. 52,No. 18,p. 10431-10437,2013年09月16日,研究論文(学術雑誌)
  • Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligands related to the active site of type II DMSOR family molybdoenzymes,Vol. 42,No. 45,p. 15927-15930,2013年,研究論文(学術雑誌)
  • Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation,Vol. 49,No. 39,p. 4358-4360,2013年,研究論文(学術雑誌)
  • Copper complexes of the non-innocent beta-diketiminate ligand containing phenol groups,Vol. 42,No. 7,p. 2438-2444,2013年,研究論文(学術雑誌)
  • A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: Preparation, crystal structures and spectroscopic properties,Vol. 42,No. 9,p. 3059-3070,2013年,研究論文(学術雑誌)
  • C-H Bond Activation of the Supporting Ligand in an Osmium(III) Complex with H2O2: Formation of an Organometallic Osmium(IV) Complex,Hideki Sugimoto,Kenji Ashikari,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 52,No. 2,p. 543-545,2013年01月,研究論文(学術雑誌)
  • An Osmium(III)/Osmium(V) Redox Couple Generating Os-V(O)(OH) Center for cis-1,2-Dihydroxylation of Alkenes with H2O2: Os Complex with a Nitrogen-Based Tetradentate Ligand,Vol. 134,No. 46,p. 19270-19280,2012年11月,研究論文(学術雑誌)
  • Active Site Models for the CuB Site of Peptidylclycine α-Hydroxylating Monooxygenase and Dopamine β-Monooxygenase,Atsushi Kunishita,Mehmed Z. Ertem,Yuri Okubo,Tetsuro Tano,Hideki Sugimoto,Kei Ohkubo,Nobutaka Fujieda,Shuichi Fukuzumi,Christopher J. Cramer,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 51,No. 17,p. 9465-9480,2012年09月,研究論文(学術雑誌)
  • Heterolytic Alkyl Hydroperoxide O-O Bond Cleavage by Copper(I) Complexes,Vol. 2012,No. 26,p. 4099-4103,2012年09月,研究論文(学術雑誌)
  • Copper(I)-Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand. Formation and Reactivity of a Mononuclear Copper(II) End-on Superoxo Complex,Yuki Kobayashi,Kei Okubo,Takashi Nomura,Minoru Kubo,Nobutaka Fujieda,Hideki Sugimoto,Shunichi Fukuzumi,Kei Goto,Takashi Ogura,Shinobu Itoh,European Journal of Inorganic Chemistry,Vol. 2012,p. 4574-4578,2012年09月,研究論文(学術雑誌)
  • Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism,Vol. 48,No. 31,p. 3721-3723,2012年,研究論文(学術雑誌)
  • Synthesis and Properties of Oxo-carboxylato- and Dioxo-bridged Diosmium Complexes of Tris(2- pyridylmethyl)amine,Hideki Sugimoto,Kazuhiro Kitayama,Kenji Ashikari,Chikako Matsunami,Naomi Ueda,Keisuke Umakoshi,Yuko Hosokoshi,Yoichi Sasaki,Shinobu Itoh,Inorganic Chemistry,アメリカ化学会,Vol. 50,p. 9014-9023,2011年10月,研究論文(学術雑誌)
  • Redox Reaction of Bis(dithiolene)sulfidotungsten(IV) Complex with Elemental Sulfur: Functional Analogs of Polysulfide Reductase of Molybdoenzymes,Vol. 40,No. 10,p. 1146-1148,2011年10月,研究論文(学術雑誌)
  • Reactions of Copper(II)-Phenol Systems with O-2: Models for TPQ Biosynthesis in Copper Amine Oxidases,Kae Tabuchi,Mehmed Z. Ertem,Hideki Sugimoto,Atsushi Kunishita,Tetsuro Tano,Nobutaka Fujieda,Christopher J. Cramer,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 50,p. 1633-1547,2011年03月,研究論文(学術雑誌)
  • Reactivity of copper(II)-alkylperoxo complexes,Vol. 40,No. 40,p. 10326-10336,2011年,研究論文(学術雑誌)
  • Generation of bis(dithiolene)dioxomolybdenum(VI) complexes from bis(dithiolene)monooxomolybdenum(IV) complexes by proton-coupled electron transfer in aqueous media,Vol. 40,No. 10,p. 2358-2365,2011年,研究論文(学術雑誌)
  • Chalcogenidobis(ene-1,2-dithiolate)molybdenum(IV) complexes (chalcogenide E = O, S, Se): Probing Mo E and ene-1,2-dithiolate substituent effects on geometric and electronic structure,Vol. 40,No. 5,p. 1119-1131,2011年,研究論文(学術雑誌)
  • Seven-coordinate Rhenium(III) Complexes with a Labile Coordination Site Assembled on Indium-doped Tin Oxide (ITO) Electrodes: Catalytic Reduction of Dioxygen to Hydrogen Peroxide,Vol. 39,No. 9,p. 986-988,2010年09月,研究論文(学術雑誌)
  • Oxygenation Chemistry at Mononuclear Copper(II)-Hydroquinone Sysetm with O2,Kae Tabuchi,Hideki Sugimoto,Atsushi Kunishita,Nobutaka Fujieda,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 49,p. 6820-6822,2010年07月,研究論文(学術雑誌)
  • Monooxomolybdenum(VI) Complexes Possessing Olefinic Dithiolene Ligands: Probing Mo-S Covalency Contributions to Electron Transfer in DMSO Reductase Family Molybdoenzymes,Hideki Sugimoto,Susumu Tatemoto,Koichiro Suyama,Hiroyuki Miyake,Regina P. Mtei,Shinobu Itoh,Martin L. Kirk,Inorganic Chemistry,American Chemical Society,Vol. 49,p. 5368-5370,2010年06月,研究論文(学術雑誌)
  • H2O2-reactivity of nickel(II) complexes supported by TPA ligands with 6¬-phenyl substituents PhnTPA,Tetsuro Tano,Yoshitaka Doi,Masayuki Inosako,Atsushi Kunishita,Minoru Kubo,Hirohito Ishimaru,Takashi Ogura,Hideki Sugimoto,Shinobu Itoh,Bull. Chem. Soc. Jpn.,日本化学会,Vol. 83,p. 530-538,2010年05月,研究論文(学術雑誌)
  • Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (WOR4) from Pyrococcus furiosus,Hideki Sugimoto,Hiroyuki Tano,Kazuo Toyota,Reiko Tajima,Hiroyuki Miyake,Isao Takahashi,Shun Hirota,Shinobu Itoh,Journal of the American Chemical Society,American Chemical Society,Vol. 132,p. 8-9,2010年01月,研究論文(学術雑誌)
  • Dioxo-Molybdenum(VI) Complexes with Ene-1,2-dithiolene Ligands: Synthesis, Spectroscopy, and Oxygen Atom Transfer Reactivity,Hideki Sugimoto,Koichiro Suyama,Susumu Tatemoto,Hiroyuki Miyake,Shinobu Itoh,Chao Dong,Jing Yang,Martin L. Kirk,Inorganic Chemistry,American Chemical Society,Vol. 48,p. 10581-10590,2009年05月,研究論文(学術雑誌)
  • Ni(II)/H2O2 Reactivity in Bis[(pyridin-2-yl)methyl]amine Tridentate Ligand Sysetm. Aromatic Hydroxylation Reaction by Bis(μ-oxo)dinickel(III) Complex,Atsushi Kunishita,Yoshitaka Doi,Takashi Ogura,Hideki Sugimoto,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 48,p. 4997-5004,2009年03月,研究論文(学術雑誌)
  • Mononuclear Copper(II)-Superoxo Complex that Mimics the Structure and Reactivity of the Active Centers of PHM and DβH,Atsushi Kunishita,Minoru Kubo,Hideki Sugimoto,Takashi Ogura,Kazunobu Sato,Takeji Takui,Shinobu Itoh,Journal of the American Chemical Society,American Chemical Society,Vol. 131,p. 2788-2789,2009年02月,研究論文(学術雑誌)
  • (μ-η2:η2-Disulfido)dinickel(II) complexes supported by 6-methyl-TPA ligands,Masayuki Inosako,Atsushi Kunisita,Minoru Kubo,Takashi Ogura,Hideki Sugimoto,Shinobu Itoh,Dalton Transactions,Royal Society of Chemistry,Vol. 2009,No. 43,p. 9410-9417,2009年,研究論文(学術雑誌)
  • H2O2-Reactivity of Copper(II) Complexes Supported by TPA Ligands with 6-Phenyl Substituents,Atsushi Kunishita,Minoru Kubo,Hirohito Ishimaru,Takashi Ogura,Hideki Sugimoto,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 47,p. 12032-12039,2008年12月,研究論文(学術雑誌)
  • A New Class of Sulfido/oxo(dithiolene)molybdenum(IV) Complexes Derived from Sulfido/oxo–bis(tetrasulfido)molybdenum(IV) Anions,Hideki Sugimoto,Koichiro Suyama,Kunihisa Sugimoto,Hiroyuki Miyake,Isao Takahashi,Shun Hirota,Shinobu Itoh,Inorganic Chemistry,American Chemical Society,Vol. 47,p. 10150-10157,2008年09月,研究論文(学術雑誌)
  • A Chemical Device that Exhibits Dual Mode Motions: Dynamic Coupling of Amide Coordination Isomerism and Metal-Centered Helicity Inversion in a Chiral Cobalt(II) Complex,Hiroyuki Miyake,Masahiro Hikita,Masumi Itazaki,Hiroshi Nakazawa,Hideki Sugimoto,Hiroshi Tsukube,Chemistry A European Journal,Vol. 14,p. 5162-5165,2008年05月,研究論文(学術雑誌)
  • Selenido-Bis(dithiolene) M(IV) Complexes (M = Mo and W) Potentially Related to the Nicotinic Acid Hydeosylase Reaction Center: Redox Aspects in Electrochemistry and Oxygen Atom Transfer from Me3NO to M(IV) Centers,Hiroyuki Tano,Reiko Tajima,Hiroyuki Miyake,Shinobu Itoh,Hideki Sugimoto,Inorganic Chemistry,American Chemical Society,Vol. 47,p. 7465-7467,2008年05月,研究論文(学術雑誌)
  • New Bis(pyranodithiolene) Tungsten(IV) and (VI) Complexes as Chemical Analogues of the Active Sites of Tungstoenzymes,Hideki Sugimoto,Kunihisa Sugimoto,Inorganic Chemistry Communication,Elsevier,Vol. 11,p. 77-80,2008年02月,研究論文(学術雑誌)
  • Chemical analogues relevant to molybdenum and tungsten enzyme reaction centres toward structural dynamics and reaction diversity,Vol. 37,No. 12,p. 2609-2619,2008年
  • Time-programmed peptide helix inversion of a synthetic metal complex triggered by an achiral NO3- anion,Vol. 130,No. 3,p. 792-+,2008年01月,研究論文(学術雑誌)
  • In situ generation of oxo-sulfidobis(dithiolene)tungsten(VI) complexes: Active-site models for the aldehyde ferredoxin oxidoreductase family of tungsten enzymes,Vol. 46,No. 21,p. 8460-8462,2007年10月,研究論文(学術雑誌)
  • Reaction of Copper(II) Complexes and Na2S2. An Alternative Method for the Preparation of Disulfido-Dicopper(II) Complexes,Masayuki Inosako,Chizu Shimokawa,Hideki Sugimoto,Nobuhiro Kihara,Toshikazu Takata,Shinobu Itoh,Chemistry Letters,Vol. 2007,p. 1306-1307,2007年10月,研究論文(学術雑誌)
  • モリブデンおよびタングステン含有酵素活性中心に関連する合成モデルの化学,杉本 秀樹,錯体化学会誌,Vol. 50,p. 26-39,2007年08月
  • Synthesis and Characterization of Bis(dithiolene) Tungsten-(VI), -(V), and –(IV) Complexes and Their Reactivities in Coupled Electron-Proton Transfer: A New Series of Active Site Models of Tungstoenzymes,Hideki Sugimoto,Makoto Tarumizu,Hiroyuki Miyake,Hiroshi Tsukube,European Journal of Inorganic Chemistry,Vol. 2007,No. 29,p. 4663-4668,2007年,研究論文(学術雑誌)
  • Molybdenum-Bis(dithiolene) Complex that Promotes Combined Coupled Electron-Proton Transfer and Oxygen Atom Transfer Reactions: A Water-Active Model of the Arsenite Oxidase Molybdenum Center,Hideki Sugimoto,Makoto Tarumizu,Hiroyuki Miyake,Hiroshi Tsukube,European Journal of Inorganic Chemistry,Vol. 2006,p. 4494-4497,2006年10月,研究論文(学術雑誌)
  • Reversible sulfurization-desulfurization of tungsten bis(dithiolene) complexes,Vol. 45,No. 21,p. 3520-3522,2006年,研究論文(学術雑誌)
  • Mononuclear five-coordinate molybdenum(IV) and -(V) monosulfide complexes coordinated with dithiolene ligands: Reversible redox of Mo(V)/Mo(IV) and irreversible dimerization of [(MoS)-S-V](-) cores to a dinuclear [Mo-2(V)(mu-S)(2)](2-) core,Vol. 44,No. 20,p. 6927-6929,2005年10月,研究論文(学術雑誌)
  • Dioxo-molybdenum(VI) and mono-oxo-molybdenum(IV) complexes supported by new aliphatic dithiolene ligands: New models with weakened Mo=O bond characters for the arsenite oxidase active site,Vol. 44,No. 18,p. 6386-6392,2005年09月,研究論文(学術雑誌)
  • Synthesis and crystal structures of [W(3,6-dichloro-1,2-benzenedithiolate)(3)](n)=1, 2) and [Mo(3,6-dichloro-1,2-benzenedithiolate)(3)](2-) : Dependence of the coordination geometry on the oxidation number and counter-cation in trigonal-prismatic and octahedral structures,Vol. 2005,No. 15,p. 3088-3092,2005年08月,研究論文(学術雑誌)
  • Cytochrome c-Crown Ether Complexes as Supramolecular Catalysts: Cold-Active Synzymes for Asymmetric Sulfoxide Oxidation in Methanol,Atsuko Suzumura,Dual Paul,Hideki Sugimoto,Satoshi Shinoda,Junji Teraoka,Hiroshi Tsukube,Inorganic Chemistry,Vol. 44,p. 904-910,2005年03月,研究論文(学術雑誌)
  • A New Series of Molybdenum –(VI), -(V), and –(IV) Dithiolate Compounds as Models of the Active Sites of Molybdoenzymes: Preparation, Crystal Structures, Spectroscopic / Electrochemical Properties, and Reactivity in Oxygen Atom Transfer,Hideki Sugimoto,Makoto Tarumizu,Koji Tanaka,Hiroyuki Miyake,Hiroshi Tsukube,Dalton Transactions,Vol. 2005,No. 21,p. 3558-3565,2005年,研究論文(学術雑誌)
  • Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism,Vol. 2005,No. 34,p. 4291-4293,2005年,研究論文(学術雑誌)


  • 学術書,Synthesis of mono- and bisdithiolene Mo and W model compounds. In Molybdenum and Tungsten Enzymes,Hideki Sugimoto,Royal Society of Chemistry,ISBN:9781782628774,2017年12月
  • 学術書,モリブデン・タングステン含有酵素,杉本 秀樹,三共出版,ISBN:9784782707562,2017年11月
  • 教科書・概説・概論,Click ケミストリー,篠田 哲史,杉本 秀樹,宗宮 創,高木 秀明,高木 由美子,田所 誠,三宅 弘之,矢野 将文,余田 威啓,三共出版,ISBN:4782704747,2004年04月