顔写真

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Hirose Keiji
廣瀬　敬治
Hirose Keiji
廣瀬　敬治
Institutional repository
Graduate School of Engineering Science　Department of Materials Engineering Science, Associate Professor

keyword Organic chemistry Functional material chemistry Analitical chemistry Bio-related chemistry

Institutional repository

Research History 5

  1. 1993 - 2000
    Osaka University

  2. 1988 - 1993
    三井石油化学工業株式会社 研究員

  3. 1988 - 1993
    Mitsui Petrochemical Industry LTD.,

  4. 2000 -
    - 大阪大学 助教授

  5. 2000 -
    - Osaka University,

Education 2

  1. Osaka University

    - 1988

  2. Osaka University　School of Science

    - 1983

Committee Memberships 3

  1. 日本化学会　日本化学会近畿支部常任幹事　Academic society

    2024/04 - Present

  2. 有機合成化学協会　幹事　Academic society

    2008 - Present

  3. 日本化学会　日本化学会近畿支部常任幹事

    2002/04 - 2004/03

Professional Memberships 10

  1. THE JAPAN SOCIETY FOR ANALYTICAL CHEMISTRY

  2. THE SOCIETY OF POLYMER SCIENCE

  3. 米国化学会

  4. 日本結晶学会

  5. 有機合成化学協会

  6. 日本化学会

  7. The American Chemical Society

  8. The crystallographic society of Japan

  9. The society of synthetic organic chemistry

  10. Japan Chemical Society

Research Areas 5

  1. Nanotechnology/Materials / Biochemistry /

  2. Nanotechnology/Materials / Functional solid-state chemistry /

  3. Nanotechnology/Materials / Analytical chemistry /

  4. Life sciences / Bioorganic chemistry /

  5. Nanotechnology/Materials / Structural/physical organic chemistry /

Awards 1

  1. HGCS Japan Award of Excellence 2009

    2009

Papers 45

  1. Editorial: Advances in mechanically bonded molecules

    Carson J. Bruns, Wei Wang, Keiji Hirose

    Frontiers in Chemistry　Vol. 10　2022/12/06　Research paper (scientific journal)

    Publisher: Frontiers Media SA

  2. Two‐step Conformational Control of a Dibenzo Diazacyclooctane Derivative by Stepwise Protonation

    Fumitaka Ishiwari, Sayuri Miyake, Keiki Inoue, Keiji Hirose, Takanori Fukushima, Akinori Saeki

    Asian Journal of Organic Chemistry　Vol. 10　No. 6　p. 1377-1381　2021/04/28　Research paper (scientific journal)

    Publisher: Wiley

  3. Editorial: Supramolecular Chirogenesis in Chemical and Related Sciences

    Yue Sun, Riina Aav, Akihiko Tsuda, Hiroyuki Miyake, Keiji Hirose, Victor Borovkov

    Frontiers in Chemistry　Vol. 9　2021/04/06　Research paper (scientific journal)

    Publisher: Frontiers Media SA

  4. Electrostatically Driven Guest Binding in Self-Assembled Molecular Network of Hexagonal Pyridine Macrocycle at the Liquid/Solid Interface: Symmetry Breaking Induced by Coadsorbed Solvent Molecules.

    Iritani K, Takeda H, Kather M, Yokoi M, Moeglen M, Ikeda M, Otsubo Y, Ozawa Y, Tahara K, Hirose K, De Feyter S, Tobe Y

    Langmuir : the ACS journal of surfaces and colloids　2019/11

  5. Electrostatically Driven Guest Binding in a Self-Assembled Porous Network at the Liquid/Solid Interface

    Kohei Iritani, Motoki Ikeda, Anna Yang, Kazukuni Tahara, Masaru Anzai, Keiji Hirose, Steven De Feyter, Jeffrey S. Moore, Yoshito Tobe

    Langmuir　Vol. 34　No. 21　p. 6036-6045　2018/05/29　Research paper (scientific journal)

  6. The Asymmetry is Derived from Mechanical Interlocking of Achiral Axle and Achiral Ring Components –Syntheses and Properties of Optically Pure [2]Rotaxanes–

    Keiji Hirose, Masaya Ukimi, Shota Ueda, Chie Onoda, Ryohei Kano, Kyosuke Tsuda, Yuko Hinohara, Yoshito Tobe

    Symmetry　Vol. 10　No. 1　p. 20-20　2018/01/09　Research paper (scientific journal)

  7. Hexagonal Molecular Tiling by Hexagonal Macrocycles at the Liquid/Solid Interface: Structural Effects on Packing Geometry

    Kohei Iritani, Motoki Ikeda, Anna Yang, Kazukuni Tahara, Keiji Hirose, Jeffrey S. Moore, Yoshito Tobe

    LANGMUIR　Vol. 33　No. 43　p. 12453-12462　2017/10　Research paper (scientific journal)

  8. DEVELOPMENT OF CROWN ETHER BASED ROTAXANES HAVING CHIRALITY SPECIFIC TO ROTAXANE STRUCTURE

    Hirose Keiji

    SYMMETRY-CULTURE AND SCIENCE　Vol. 28　No. 2　p. 191-194　2017

  9. Syntheses and stimuli-responsive rocking motions of a rotaxane bearing different stoppers

    Keiji Hirose, Shizuka Okada, Shota Umezaki, Philip G. Young, Yoshito Tobe

    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY　Vol. 331　p. 184-189　2016/12　Research paper (scientific journal)

  10. Construction of cyclic arrays of Zn-porphyrin units and their guest binding at the solid-liquid interface

    Kohei Iritani, Kazukuni Tahara, Keiji Hirose, Steven De Feyter, Yoshito Tobe

    CHEMICAL COMMUNICATIONS　Vol. 52　No. 100　p. 14419-14422　2016　Research paper (scientific journal)

  11. Square Tiling by Square Macrocycles at the Liquid/Solid Interface: Co-crystallisation with One- or Two-Dimensional Order

    Kazukuni Tahara, Jun Gotoda, Calden N. Carroll, Keiji Hirose, Steven De Feyter, Yoshito Tobe

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 21　No. 18　p. 6806-6816　2015/04　Research paper (scientific journal)

  12. Axle Length Does Not Affect Switching Dynamics in Degenerate Molecular Shuttles with Rigid Spacers

    Philip G. Young, Keiji Hirose, Yoshito Tobe

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 136　No. 22　p. 7899-7906　2014/06　Research paper (scientific journal)

  13. Molecular brake rotaxane systems composed of a dianthrylethane-based macrocycle as the ring component and a dumbbell shaped secondary ammonium as the axle component controlled by light and heat

    Keiji Hirose

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　Vol. 246　2013/09

  14. Reaxys for Students―Applying E‐Resources to Educational Settings―

    廣瀬敬治

    薬学図書館　Vol. 58　No. 1　p. 62-72　2013/01/31

    Publisher:

  15. Quantitative Analysis of Binding Properties

    Keiji Hirose

    Analytical Methods in Supramolecular Chemistry, Volume 1 & 2: Second Edition　Vol. 1　p. 27-66　2012/03/21　Part of collection (book)

    Publisher: Wiley-VCH

  16. Amplification of enantioselectivity and sensitivity based on non-linear response of molecular wire bearing pseudo-18-crown-6 to chiral amines

    Keiji Hirose, Shintaro Miura, Yui Senda, Yoshito Tobe

    CHEMICAL COMMUNICATIONS　Vol. 48　No. 48　p. 6052-6054　2012　Research paper (scientific journal)

  17. Novel chiral recognition beyond the limitation due to the law of mass action: highly enantioselective chiral sensing based on non-linear response in phase transition events

    Keiji Hirose, Yuka Yachi, Yoshito Tobe

    CHEMICAL COMMUNICATIONS　Vol. 47　No. 23　p. 6617-6619　2011　Research paper (scientific journal)

  18. Determination of Binding Constants

    Keiji Hirose

    Analytical Methods in Supramolecular Chemistry　p. 17-54　2007/01/16　Part of collection (book)

    Publisher: Wiley-VCH Verlag GmbH & Co. KGaA

  19. Structure-selective recognition by voltammetry: Enantiomeric determination of amines using azophenolic crowns in aprotic solvent

    Kyungmin Chun, Tae Hyun Kim, One-Sun Lee, Keiji Hirose, Taek Dong Chung, Doo Soo Chung, Hasuck Kim

    ANALYTICAL CHEMISTRY　Vol. 78　No. 21　p. 7597-7600　2006/11　Research paper (scientific journal)

  20. Properties of dendritic and cyclic thiourea derivatives as neutral carriers for anion sensors

    S Uchida, Y Komatsu, H Satoh, S Yajima, K Kimura, Y Tobe, S Sasaki, M Mizuno, Y Watanabe, K Hirose

    BUNSEKI KAGAKU　Vol. 53　No. 9　p. 943-952　2004/09　Research paper (scientific journal)

  21. Depression of the apparent chiral recognition ability obtained in the host-guest complexation systems by electrospray and nano-electrospray ionization mass spectrometry

    M Sawada, Y Takai, H Yamada, M Yoshikawa, R Arakawa, H Tabuchi, M Takada, J Tanaka, M Shizuma, H Yamaoka, K Hirose, K Fukuda, Y Tobe

    EUROPEAN JOURNAL OF MASS SPECTROMETRY　Vol. 10　No. 1　p. 27-37　2004　Research paper (scientific journal)

  22. Enantiomeric separations of stimulant materials using chiral stationary phase bonded with pseudocrown ether

    UESHIGE T, NISHIOKA R, NAKAMURA T, HIROSE K, TOBE Y

    Chromatography : journal of separation and detection sciences = クロマトグラフィー : 分離・検出科学　Vol. 21　No. 4　p. 368-369　2000/10/31

  23. Preparation and evaluation of novel chiral stationary phases chemically bonded with chiral pseudo crown ether

    NISHIOKA R, UESHIGE T, NAKAMURA T, HIROSE K, TOBE Y

    Chromatography : journal of separation and detection sciences = クロマトグラフィー : 分離・検出科学　Vol. 21　No. 4　p. 294-295　2000/10/31

  24. Chiral Recognition Ability of Crown Ethers toward Organic Amine Compounds : FAB Mass Spectrometry Coupled with the Enantiomer-Labeled Guest Method

    SAWADA Masami, HAGITA Kouji, IMAMURA Hiroyuki, TABUCHI Hiroyuki, YODOYA Shinya, UMEDA Maki, TAKAI Yoshio, YAMADA Hitoshi, YAMAOKA Hiroshi, HIROSE Keiji, TOBE Yoshito, TANAKA Toshikazu, TAKAHASHI Shigetoshi

    Journal of the Mass Spectrometry Society of Japan　Vol. 48 (5), 323-332/,　No. 5　p. 323-332　2000/10/01

    Publisher: 一般社団法人 日本質量分析学会

  25. CHIRAL RECOGNITION IN HOST-GUEST COMPLEXATION DETERMINED BY THE ENANTIOMER-LABELED GUEST METHOD USING FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY

    M SAWADA, Y TAKAI, H YAMADA, S HIRAYAMA, T KANEDA, T TANAKA, K KAMADA, T MIZOOKU, S TAKEUCHI, K UENO, K HIROSE, Y TOBE, K NAEMURA

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 117　No. 29　p. 7726-7736　1995/07

  26. SYNTHESIS OF AZOPHENOLIC CROWN-ETHERS OF C-S SYMMETRY INCORPORATING CIS-1-PHENYLCYCLOHEXANE-1,2-DIOL RESIDUES AS A STERIC BARRIER AND DIASTEREOTOPIC FACE SELECTIVITY IN COMPLEXATION OF AMINES BY THEIR DIASTEREOTOPIC FACES

    K NAEMURA, S TAKEUCHI, M ASADA, K UENO, K HIROSE, Y TOBE, T KANEDA, Y SAKATA

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1　No. 11　p. 1429-1435　1995/06　Research paper (scientific journal)

  27. PREPARATION AND ENANTIOMER RECOGNITION BEHAVIOR OF AZOPHENOLIC CROWN-ETHERS CONTAINING CIS-CYCLOHEXANE-1,2-DIOL AS THE CHIRAL CENTER

    K NAEMURA, S TAKEUCHI, K HIROSE, Y TOBE, T KANEDA, Y SAKATA

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1　No. 3　p. 213-219　1995/02　Research paper (scientific journal)

  28. Preparation and enantiomer recognition behaviour of azophenolic crown ethers containing cis-cyclohexane-1,2-diol as the chiral centre

    Koichiro Naemura, Sachiko Takeuchi, Keiji Hirose, Yoshito Tobe, Takahiro Kanada, Yoshiteru Sakata

    Journal of the Chemical Society, Perkin Transactions 1　No. 3　p. 213-219　1995　Research paper (scientific journal)

  29. Synthesis of azophenolic crown ethers of Cs symmetry incorporating cis-l-phenylcyclohexane-l,2-cliol residues as a steric barrier and diastereotopic face selectivity in complexation of amines by their diastereotopic faces

    Koichiro Naemura, Sachiko Takeuchi, Masaki Asada, Koji Ueno, Keiji Hirose, Yoshito Tobe, Takahiro Kaneda, Yoshiteru Sakata

    Journal of the Chemical Society, Perkin Transactions 1　p. 1429-1435　1995　Research paper (scientific journal)

  30. CHIRAL RECOGNITION IN MOLECULAR COMPLEXATION FOR THE CROWN-ETHER AMINO ESTER SYSTEM - A FACILE FAB MASS-SPECTROMETRIC APPROACH

    M SAWADA, Y TAKAI, H YAMADA, T KANEDA, K KAMADA, T MIZOOKU, K HIROSE, Y TOBE, K NAEMURA

    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS　No. 21　p. 2497-2498　1994/11　Research paper (scientific journal)

  31. PREPARATION OF HOMOCHIRAL CROWN-ETHER CONTAINING (S)-1-(1-ADAMANTYL)ETHANE-1,2-DIOL AS A CHIRAL SUBUNIT AND ITS ENANTIOSELECTIVE COMPLEXATION WITH AN ORGANIC AMMONIUM CATION

    K NAEMURA, T MIZOOKU, K KAMADA, K HIROSE, Y TOBE, M SAWADA, Y TAKAI

    TETRAHEDRON-ASYMMETRY　Vol. 5　No. 8　p. 1549-1558　1994/08　Research paper (scientific journal)

  32. LIPASE YS-CATALYZED ACYLATION OF ALCOHOLS - A PREDICTIVE ACTIVE-SITE MODEL FOR LIPASE YS TO IDENTIFY WHICH ENANTIOMER OF A PRIMARY OR A SECONDARY ALCOHOL REACTS FASTER IN THIS ACYLATION

    K NAEMURA, R FUKUDA, M KONISHI, K HIROSE, Y TOBE

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1　No. 10　p. 1253-1256　1994/05

  33. THE SYNTHESIS OF AZOPHENOLIC CROWN-ETHERS OF C(S) SYMMETRY INCORPORATING CIS-1-PHENYLCYCLOHEXANE-1,2-DIOL RESIDUES AND DIASTEREOTOPIC FACE SELECTIVITY IN COMPLEXATION OF ETHANOLAMINE BY THEIR DIASTEREOTOPIC FACES

    K NAEMURA, S TAKEUCHI, M ASADA, K HIROSE, Y TOBE, T KANEDA, Y SAKATA

    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS　No. 6　p. 711-712　1994/03　Research paper (scientific journal)

  34. Lipase YS-catalysed acylation of alcohols: A predictive active site model for lipase YS to identify which enantiomer of a primary or a secondary alcohol reacts faster in this acylation

    Koichiro Naemura, Ritsuko Fukuda, Masayoshi Konishi, Keiji Hirose, Yoshito Tobe

    Journal of the Chemical Society, Perkin Transactions 1　No. 10　p. 1253-1256　1994　Research paper (scientific journal)

  35. CROSS-CHIRAL EXAMINATIONS OF MOLECULAR ENANTIOSELECTIVE RECOGNITION BY FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY - HOST-GUEST COMPLEXATIONS BETWEEN CHIRAL CROWN-ETHERS AND CHIRAL ORGANIC AMMONIUM-IONS

    M SAWADA, Y OKUMURA, H YAMADA, Y TAKAI, S TAKAHASHI, T KANEDA, K HIROSE, S MISUMI

    ORGANIC MASS SPECTROMETRY　Vol. 28　No. 12　p. 1525-1528　1993/12　Research paper (scientific journal)

  36. ENANTIOSELECTIVE COMPLEXATION OF CARBOHYDRATE OR CROWN-ETHER HOSTS WITH ORGANIC AMMONIUM ION GUESTS DETECTED BY FAB MASS-SPECTROMETRY

    M SAWADA, Y OKUMURA, M SHIZUMA, Y TAKAI, Y HIDAKA, H YAMADA, T TANAKA, T KANEDA, K HIROSE, S MISUMI, S TAKAHASHI

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 115　No. 16　p. 7381-7388　1993/08　Research paper (scientific journal)

  37. ポリプロピレン製造技術の発展 (世界の中の日本の化学工業技術<特集>) -- (導入技術を追い越した素材製造プロセス技術)

    木岡 護, 広瀬 敬治, 柏 典夫

    化学工学　Vol. 56　No. 9　p. p629-631　1992/09

    Publisher: 化学工学会

  38. OLEFIN OLIGOMERIZATION WITH NICKEL PO CHELATE COMPLEXES

    K HIROSE, W KEIM

    JOURNAL OF MOLECULAR CATALYSIS　Vol. 73　No. 3　p. 271-276　1992/06　Research paper (scientific journal)

  39. チーグラー触媒によるポリエチレン製造法

    木岡 護, 広瀬 敬治, 柏 典夫

    化学史研究　Vol. 19,40/,　No. 1　p. p40-49　1992

    Publisher: 化学史学会

  40. 技術史シリ-ズ-2-チ-グラ-触媒によるポリエチレンの製造法<特集>

    木岡 護, 広瀬 敬治, 柏 典夫

    化学史研究　Vol. 19　No. 1　p. p40-49　1992

    Publisher: 化学史学会

  41. ポリプロピレン製造技術の発展

    木岡 護, 広瀬 敬治, 柏 典夫

    化学工学　Vol. 56,629/,　No. 9　p. p629-631　1992

    Publisher: 化学工学会

  42. CHIRAL AZOPHENOLIC ACERANDS - COLOR INDICATORS TO JUDGE THE ABSOLUTE-CONFIGURATION OF CHIRAL AMINES

    T KANEDA, K HIROSE, S MISUMI

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 111　No. 2　p. 742-743　1989/01

  43. FLUORESCENCE REACTIONS OF CROWNED BENZOTHIAZOLYLPHENOLS WITH ALKALI AND ALKALINE-EARTH METAL-IONS AND THEIR ANALYTICAL APPLICATIONS

    K NAKASHIMA, Y NAGAOKA, S NAKATSUJI, T KANEDA, TANIGAWA, I, K HIROSE, S MISUMI, S AKIYAMA

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN　Vol. 60　No. 9　p. 3219-3223　1987/09　Research paper (scientific journal)

  44. 電荷移動積層化合物から導電性ポリシクロファンへ (1986年の化学-7-)

    広瀬 敬治, 三角 荘一

    化学　Vol. 41　No. 7　p. p478-479　1986/07

    Publisher: 化学同人

  45. Chiral Recognition in Molecular Complexation for the Crown Ether-Amino Ester System. A Facile FAB Mass Spectrometric Approach

    J. Chem. Soc. , Chem. Commun.　1944

Misc. 132

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    入谷康平, 入谷康平, 鵜野裕基, 国元一樹, 田原和邦, 田原和邦, 廣瀬敬治, 戸部義人, 戸部義人

    高分子学会予稿集(CD-ROM)　Vol. 67　No. 2　2018/08/29

  2. アキラルな軸成分とアキラルな輪成分が機械的につながってできる光学活性[2]ロタキサンの合成とキラルセンサーへの応用

    廣瀬敬治, 浮見雅哉, 上田将太, 小野田知恵, 加納椋平, 津田恭祐, 日野原祐子, 魚井清香, 河合真, 戸部義人

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    久保有輝, 田原一邦, 田原一邦, 田原一邦, HIRSCH Brandon E, 廣瀬敬治, DE FEYTER Steven, 戸部義人, 戸部義人

    日本化学会春季年会講演予稿集(CD-ROM)　Vol. 98th　2018/03/06

  4. 光および熱応答性[2]ロタキサン型分子ラチェットの構築

    廣瀬敬治, 小野田知恵, 高林亮, 岡田静, 戸部義人

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  5. 固液界面においてゲストにより誘起される自己集合分子ネットワークの構造変化に及ぼすカルボニル基の効果

    辻孝史, 田原一邦, 田原一邦, 廣瀬敬治, 戸部義人, 戸部義人

    基礎有機化学討論会要旨集　Vol. 28th　2017/09/07

  6. 固液界面におけるアセチレンあるいはジアセチレン架橋をもつ六角形マクロサイクルによる分子タイリング

    入谷康平, 池田元城, 田原一邦, 廣瀬敬治, 戸部義人

    ホスト-ゲスト・超分子化学シンポジウム講演要旨集　Vol. 15th　2017/06/03

  7. ロタキサン構造に特有のキラリティを有する光学的に純粋なロタキサンのキラルアミンに対するエナンチオ選択的錯形成

    廣瀬敬治, 上田将太, 梅崎将太, 津田恭佑, 戸部義人

    日本化学会春季年会講演予稿集(CD-ROM)　Vol. 97th　2017/03/03

  8. ロタキサン型分子機械のシャトリング運動性に及ぼすハープーニング機構の寄与

    廣瀬敬治, 梅崎将太, 加納椋平, YOUNG Philip Geoffrey, 戸部義人

    ホスト・ゲスト化学シンポジウム講演要旨集　Vol. 14th　2016/06/04

  9. ロタキサン型分子機械の軸成分の構造がシャトリング運動性に及ぼす効果

    廣瀬敬治, 加納椋平, YOUNG Philip G, 戸部義人

    日本化学会春季年会講演予稿集(CD-ROM)　Vol. 96th　2016/03/10

  10. ロタキサン型分子機械のシャトリング運動性に及ぼすハープーニング機構の寄与

    廣瀬敬治, 梅崎将太, 加納椋平, YOUNG Philip G, 戸部義人

    日本化学会春季年会講演予稿集(CD-ROM)　Vol. 96th　2016/03/10

  11. [2]ロタキサン型分子シャトルの軸成分の柔軟性のシャトリング運動性に及ぼす効果

    廣瀬敬治, 梅崎将太, 加納椋平, YOUNG P. G, 戸部義人

    日本化学会講演予稿集　Vol. 95th　No. 4　2015/03/11

  12. プレロタキサン法に基づくロタキサン構造に固有の不斉を有する光学的に純粋なロタキサンの合成法の開発

    廣瀬敬治, 津田恭佑, 古谷創, 日野原裕子, 戸部義人

    日本化学会講演予稿集　Vol. 94th　No. 4　2014/03/12

  13. 光及び熱応答性[2]ロタキサンから成る分子ラチェットの構築

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    日本化学会講演予稿集　Vol. 94th　No. 4　2014/03/12

  14. [2]ロタキサン型分子シャトルの軸成分の長さおよび柔軟性のシャトリング運動性に及ぼす効果

    廣瀬敬治, 加納椋平, YOUNG P. G, 戸部義人

    日本化学会講演予稿集　Vol. 94th　No. 4　2014/03/12

  15. pyridine‐TiNClのドーピング機構

    草部浩一, 廣瀬敬治, 戸部義人

    日本物理学会講演概要集　Vol. 68　No. 2　2013/08/26

  16. [2]ロタキサン型分子シャトルの軸成分の長さと柔軟性のシャトリング運動性におよぼす効果

    YOUNG Philip G, 加納椋平, 廣瀬敬治, 戸部義人

    基礎有機化学討論会要旨集　Vol. 24th　2013/08/22

  17. A mechanism of electron doping for pyridine-TiNCl

    Kusakabe Koichi, Hirose Keiji, Tobe Yoshito

    Meeting Abstracts of the Physical Society of Japan　Vol. 68　No. 0　p. 441-441　2013

    Publisher: 一般社団法人 日本物理学会

  18. プレロタキサン法に基づくトポロジカルキラリティーを有する光学活性ロタキサンの合成法の開発

    廣瀬敬治, 津田恭佑, 古谷創, 日野原祐子, 戸部義人

    日本化学会講演予稿集　Vol. 92nd　No. 4　2012/03/09

  19. FABMSによる液体マトリクス中の錯安定度定数決定法

    靜間基博, 安達廣, 浅野芳織, 松崎剛, 佐藤博文, 鈴木健之, 廣瀬敬治, 戸部義人, 川崎英也, 荒川隆一, 小野大助

    質量分析総合討論会講演要旨集　Vol. 59th　2011/09/01

  20. ロッキング運動速度をスイッチするC∞v対称性を有するロタキサンの合成と動的挙動

    廣瀬敬治, 岡田静, 戸部義人

    日本化学会講演予稿集　Vol. 91st　No. 4　2011/03/11

  21. Syntheses and Dynamic Behaviors of Molecular Brakes of Rocking Motions of Rotaxanes with C v Symmetry

    Hirose Keiji, Okada Shizuka, Tobe Yoshito

    Abstracts of Papers: Host-Guest Chemistry Symposium　Vol. 2011　No. 0　p. 70-70　2011

    Publisher: ホスト-ゲスト・超分子化学研究会

  22. Molecular brake systems controlled by light and heat

    Keiji Hirose

    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY　Vol. 68　No. 1-2　p. 1-24　2010/10　Book review, literature introduction, etc.

  23. Molecular brake systems controlled by light and heat

    Keiji Hirose

    Journal of Inclusion Phenomena and Macrocyclic Chemistry　Vol. 68　No. 1　p. 1-24　2010　Book review, literature introduction, etc.

  24. Molecular Brake Systems Controlled by Light and Heat

    Keiji Hirose

    J. Incl. Phenom. Macrocycl. Chem.　Vol. 68　No. 1-2　p. 1-24　2010

  25. A Molecular Brake System for the Shuttling Motion Between Enantiomeric Rotaxanes

    Hirose Keiji, Furutani Hajime, Tobe Yoshito

    Abstracts of Papers: Host-Guest Chemistry Symposium　Vol. 2010　No. 0　p. 105-105　2010

    Publisher: ホスト-ゲスト・超分子化学研究会

  26. 光と熱でロッキング運動速度をスイッチするC∞vロタキサンの合成とその物性

    廣瀬敬治, 岡田静, 古谷創, 石橋和明, 戸部義人

    基礎有機化学討論会要旨集　Vol. 20th　2009/09/18

  27. Remarkable effect of hydrogen bonding between ring and axle components on deslipping reactions of rotaxanes

    Keiji Hirose, Yamato Nakamura, Hirokazu Takano, Keiji Nishihara, Yoshito Tobe

    TETRAHEDRON LETTERS　Vol. 50　No. 26　p. 3443-3445　2009/07

  28. Remarkable Effects of Chirality on Deslipping Reactions of Diastereomeric Rotaxanes and Relevant Mechanism Involving Pre-Equilibrium

    Keiji Hirose, Yamato Nakamura, Yoshito Tobe

    ORGANIC LETTERS　Vol. 11　No. 1　p. 145-147　2009/01

  29. Molecular Brake Systems Controlled by Light and Heat

    Hirose Keiji, Okada Shizuka, Ishibashi Kazuaki, Shiba Yoshinobu, Tobe Yoshito

    Abstracts of Papers: Host-Guest Chemistry Symposium　Vol. 2009　No. 0　p. 28-28　2009

    Publisher: ホスト-ゲスト・超分子化学研究会

  30. Syntheses and Properties of Rocking Rotaxanes with Cœv Symmetry Controlled by Light and Heat

    Hirose Keiji, Okada Shizuka, Furutani Hajime, Ishibashi Kazuaki, Tobe Yoshito

    Abstracts of Symposium on Physical Organic Chemistry　Vol. 2009　No. 0　p. 162-162　2009

    Publisher: 基礎有機化学会（基礎有機化学連合討論会）

  31. Solvophobically driven self-association of a butadiyne-bridged pyridine macrocycle

    Motohiro Sonoda, Yui Yamaguchi, Kazukuni Tahara, Keiji Hirose, Yoshito Tobe

    TETRAHEDRON　Vol. 64　No. 50　p. 11490-11494　2008/12

  32. Effect of Hydrogen Bonding between Axle and Ring Components on Deslipping Reactions of Rotaxanes

    Ikuta Kazuhiro, Hirose Keiji, Nakamura Yamato, Tobe Yoshito

    Abstracts of Symposium on Physical Organic Chemistry　Vol. 2008　No. 0　p. 3-3　2008/09/26

    Publisher: 基礎有機化学会（基礎有機化学連合討論会）

  33. Site-selective guest inclusion in molecular networks of butadiyne-bridged pyridino and benzeno square macrocycles on a surface

    Kazukuni Tahara, Shengbin Lei, Wael Mamdouh, Yui Yamaguchi, Tomoyuki Ichikawa, Hiroshi Uji-i, Motohiro Sonoda, Keiji Hirose, Frans C. De Schryver, Steven De Feyter, Yoshito Tobe

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 130　No. 21　p. 6666-+　2008/05

  34. 光学活性クラウンエーテルを有するポリ(N‐イソプロピルアクリルアミド)の合成と不斉選択的相分離挙動

    廣瀬敬治, 矢地佑佳, 戸部義人

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  35. ブタジイン架橋マクロサイクルの2次元分子ネッワーク:構造および錯形成能

    田原一邦, LEI Shengbin, MAMDOUH Wael, 山口結衣, 雲林院宏, 園田素啓, 廣瀬敬治, DE SCHRYVER Frans, DE FEYTER Steven, 戸部義人

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  36. A shuttling molecular machine with reversible brake function

    Keiji Hirose, Yoshinobu Shiba, Kazuaki Ishibashi, Yasuko Doi, Yoshito Tobe

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 14　No. 11　p. 3427-3433　2008

  37. An anthracene-based photochromic macrocycle as a key ring component to switch a frequency of threading motion

    Keiji Hirose, Yoshinobu Shiba, Kazuaki Ishibashi, Yasuko Doi, Yoshito Tobe

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 14　No. 3　p. 981-986　2008

  38. An anthracene-based photochromic macrocycle as a key ring component to switch a frequency of threading motion

    Keiji Hirose, Yoshinobu Shiba, Kazuaki Ishibashi, Yasuko Doi, Yoshito Tobe

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 14　No. 3　p. 981-986　2008

  39. A shuttling molecular machine with reversible brake function

    Keiji Hirose, Yoshinobu Shiba, Kazuaki Ishibashi, Yasuko Doi, Yoshito Tobe

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 14　No. 11　p. 3427-3433　2008

  40. Highly effective and reversible control of the rocking rates of rotaxanes by changes to the size of stimulus-responsive ring components

    Keiji Hirose, Kazuaki Ishibashi, Yoshinobu Shiba, Yasuko Doi, Yoshito Tobe

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 14　No. 19　p. 5803-5811　2008

  41. Kinetic Isotope Effect on Deslipping Reactions of Diastereomric Rotaxanes Having Chiral Centers on Both Ring and Axle Components

    Hirose Keiji, Nakamura Yamato, Tobe Yoshito

    Abstracts of Papers: Host-Guest Chemistry Symposium　Vol. 2008　No. 0　p. 104-104　2008

    Publisher: ホスト-ゲスト・超分子化学研究会

  42. Clear Chirality Recognition in Water by Chiral Psudo-18-crown-6 Ether combined with Water Soluble Polymer

    Hirose Keiji Hirose, Yachi Yuka, Tobe Yoshito

    Abstracts of Papers: Host-Guest Chemistry Symposium　Vol. 2008　No. 0　p. 12-12　2008

    Publisher: ホスト-ゲスト・超分子化学研究会

  43. Syntheses of Inherently Chiral Rotaxanes

    Hirose Keiji, Hinohara Yuko, Nakamura Yamato, Tobe Yoshito

    Abstracts of Symposium on Physical Organic Chemistry　Vol. 37　No. 0　p. 112-112　2007/10/27

    Publisher: 基礎有機化学会（基礎有機化学連合討論会）

  44. Electronic and Steric Effects on Deslippage Reaction of Rotaxanes

    Hirose keiji, Nakamura Yamato, Takano Hirokazu, Tobe Yoshito

    Abstracts of Symposium on Physical Organic Chemistry　Vol. 57　No. 0　p. 18-18　2007/09/29

    Publisher: 基礎有機化学会（基礎有機化学連合討論会）

  45. Highly selective and high-yielding rotaxane synthesis via aminolysis of prerotaxanes consisting of a ring component and a stopper unit

    Keiji Hirose, Keiji Nishihara, Naoki Harada, Yamato Nakamura, Daisuke Masuda, Masami Araki, Yoshito Tobe

    ORGANIC LETTERS　Vol. 9　No. 16　p. 2969-2972　2007/08

  46. Highly selective and high-yielding rotaxane synthesis via aminolysis of prerotaxanes consisting of a ring component and a stopper unit

    Keiji Hirose, Keiji Nishihara, Naoki Harada, Yamato Nakamura, Daisuke Masuda, Masami Araki, Yoshito Tobe

    ORGANIC LETTERS　Vol. 9　No. 16　p. 2969-2972　2007/08

  47. Supramolecular method for the determination of absolute configuration of chiral compounds: Theoretical derivatization and a demonstration for a phenolic crown ether-2-amino-1-ethanol system

    Keiji Hirose, Yoko Goshima, Takanori Wakebe, Yoshito Tobe, Koichiro Naemura

    ANALYTICAL CHEMISTRY　Vol. 79　No. 16　p. 6295-6302　2007/08

  48. Control of rocking mobility of rotaxanes by size change of stimulus-responsive ring components

    Keiji Hirose, Kazuaki Ishibashi, Yoshinobu Shiba, Yasuko Doi, Yoshito Tobe

    CHEMISTRY LETTERS　Vol. 36　No. 6　p. 810-811　2007/06

  49. Control of rocking mobility of rotaxanes by size change of stimulus-responsive ring components

    Keiji Hirose, Kazuaki Ishibashi, Yoshinobu Shiba, Yasuko Doi, Yoshito Tobe

    CHEMISTRY LETTERS　Vol. 36　No. 6　p. 810-811　2007/06

  50. 光学活性ロタキサンの合成とデスリッピングにおよぼす立体化学効果

    廣瀬敬治, 中村大和, 戸部義人

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  51. 極性基を有するブタジイン架橋ピリジノファンの溶液中における自己会合挙動の調査

    山口結衣, 市川智之, 園田素啓, 田原一邦, 廣瀬敬治, 戸部義人

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  52. リング・ストッパー成分結合型プレロタキサンのアミノリシスによる新規ロタキサン合成の反応機構

    廣瀬敬治, 西原啓二, 原田直樹, 荒木正美, 戸部義人

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  53. Synthesis and anion-selective complexation of homobenzylic tripodal thiourea derivatives

    Ichiro Hisaki, Shin-ichi Sasaki, Keiji Hirose, Yoshito Tobe

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY　Vol. 4, 607-615　No. 4　p. 607-615　2007/02

  54. 「分子認識と超分子 」大環状化合物の分子認識と分子集積

    三共出版　Vol. 19ー35　2007

  55. Chapter 2, "Determination of Binding Constants", in "Analytical Methods in Supramolecular Chemistry"

    Wiley-VCH　2007

  56. Chapter 2, "Determination of Binding Constants", in "Analytical Methods in Supramolecular Chemistry"

    Wiley-VCH　2007

  57. リング・ストッパー成分結合型プレロタキサンのアミノリシスによる新規ロタキサン合成法―プレロタキサンの置換基と反応溶媒による生成物選択的反応加速効果―

    廣瀬敬治, 西原啓二, 原田直樹, 増田大輔, 荒木正美, 戸部義人

    基礎有機化学連合討論会予稿集　Vol. 18th　No. 0　p. 243-132　2006/10/07

    Publisher: 基礎有機化学会（基礎有機化学連合討論会）

  58. Preparation and evaluation of a chiral stationary phase covalently bound with a chiral pseudo-18-crown-6 ether having a phenolic hydroxy group for enantiomer separation of amino compounds

    Jin Yongzhu, Keiji Hirose, Takashi Nakamura, Ryota Nishioka, Tetsuro Ueshige, Yoshito Tobe

    JOURNAL OF CHROMATOGRAPHY A　Vol. 1129　No. 2　p. 201-207　2006/10

  59. Self-assembly of m-diethynylbenzene macrocycles containing exoannular chiral side chains

    Yoshito Tobe, Toshiro Nagai, Shunji Araki, Tomoyuki Ichikawa, Akihiro Nomoto, Motohiro Sonoda, Keiji Hirose

    ADVANCED FUNCTIONAL MATERIALS　Vol. 16　No. 12　p. 1549-1554　2006/08

  60. Development of Novel Rotaxane Synthesis via Prerotaxane Consisting of a Ring Component and a Stopper Unit―Effects of Prerotaxane Structure and Solvents―

    廣瀬敬治, 西原啓二, 原田直樹, 荒木正美, 戸部義人

    日本化学会講演予稿集　Vol. 86th　No. 2　2006/03/13

  61. Preparation and evaluation of novel chiral stationary phases covalently bound with chiral phenolic pseudo‐18‐crown‐6

    廣瀬敬治, JIN Yongzhu, 中村崇, 西岡亮太, 上重哲郎, 戸部義人

    日本化学会講演予稿集　Vol. 86th　No. 1　2006/03/13

  62. A clue to elusive macrocycles: Unusually facile, spontaneous polymerization of a hexagonal diethynylbenzene macrocycle

    A Nomoto, M Sonoda, Y Yamaguchi, T Ichikawa, K Hirose, Y Tobe

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 71　No. 1　p. 401-404　2006/01

  63. Remaekable effect of subtle structural change of chiral pseudo-18-crown-6 on enantiomer-selectivity in complexation with chiral amino alcohols

    K Hirose, P Aksharanandana, M Suzuki, K Wada, K Naemura, Y Tobe

    HETEROCYCLES　Vol. 66　p. 405-431　2005/12

  64. 蛍光性共役高分子骨格とフェノール性擬18‐クラウン‐6エーテル構造を用いたキラルセンサーのエナンチオ選択性の向上

    廣瀬敬治, 三浦新太郎, 仙田結, 戸部義人

    日本化学会西日本大会講演予稿集　Vol. 2005　p. 119-120　2005/10/22

  65. Preparation and evaluation of a chiral stationary phase covalently bound with chiral pseudo-18-crown-6 ether having 1-phenyl-1,2-cyclohexanediol as a chiral unit

    K Hirose, YZ Jin, T Nakamura, R Nishioka, T Ueshige, Y Tobe

    JOURNAL OF CHROMATOGRAPHY A　Vol. 1078　No. 1-2　p. 35-41　2005/06

  66. Unusual Ring Size Effect on Stability of Alkoxymethyl-substituted Diethynylbenzene Macrocycles

    戸部義人, 野元昭宏, 山口結衣, 市川智之, 園田素啓, 広瀬敬治

    日本化学会講演予稿集　Vol. 85th　No. 2　2005/03/11

  67. Chiral stationary phase covalently bound with a chiral pseudo-18-crown-6 ether for enantiomer separation of amino compounds using a normal mobile phase

    K Hirose, YZ Jin, T Nakamura, R Nishioka, T Ueshige, Y Tobe

    CHIRALITY　Vol. 17　No. 3　p. 142-148　2005/03

  68. Remarkable Effect of Subtle Structural Change of Chiral Keiji Hirose, Pakatip Aksharanandana, Michiko Suzuki, Kiyoshi Wada, Koichiro Naemura and Yoshito Tobe

    Heterocycles　Vol. 66　2005

  69. Properties of dendritic and cyclic thiourea derivatives as neutral carriers for anion sensors

    S Uchida, Y Komatsu, H Satoh, S Yajima, K Kimura, Y Tobe, S Sasaki, M Mizuno, Y Watanabe, K Hirose

    BUNSEKI KAGAKU　Vol. 53　No. 9　p. 943-952　2004/09

  70. Chiral recognition in NMR spectroscopy using crown ethers and their ytterbium(III) complexes

    TJ Wenzel, BE Freeman, DC Sek, JJ Zopf, T Nakamura, YZ Jin, K Hirose, Y Tobe

    ANALYTICAL AND BIOANALYTICAL CHEMISTRY　Vol. 378　No. 6　p. 1536-1547　2004/03

  71. Depression of the apparent chiral recognition ability obtained in the host-guest complexation systems by electrospray and nano-electrospray ionization mass spectrometry

    M Sawada, Y Takai, H Yamada, M Yoshikawa, R Arakawa, H Tabuchi, M Takada, J Tanaka, M Shizuma, H Yamaoka, K Hirose, K Fukuda, Y Tobe

    EUROPEAN JOURNAL OF MASS SPECTROMETRY　Vol. 10　No. 1　p. 27-37　2004

  72. Novel Rotaxane Synthesis via Aminolyses of Prerotaxanes Consisting of a Ring Component and a Stopper Unit

    Hirose Keiji, Harada Naoki, Masuda Daisuke, Araki Masami, Tobe Yoshito

    Abstracts of Symposium on Physical Organic Chemistry　Vol. 17　No. 0　p. 333-333　2004

    Publisher: The Society of Physical Organic Chemistry, Japan

  73. Preparation of phenolic chiral crown ethers and podands and their enantiomer recognition ability toward secondary amines

    Keiji Hirose, Akihito Fujiwara, Kazuhisa Matsunaga, Nobuaki Aoki, Yoshito Tobe

    Tetrahedron Asymmetry　Vol. 14　No. 5　p. 555-566　2003/03/07

    Publisher: Elsevier Ltd

  74. Self-Association Behavior of Diethynylbenzene Macrocycles in Solution

    戸部義人, 永井敏朗, 野元昭宏, 荒木俊二, 園田素啓, 広瀬敬治

    日本化学会講演予稿集　Vol. 83rd　No. 2　2003/03/03

  75. Preparation of phenolic chiral crown ethers and podands and their enantiomer recognition ability toward secondary amines

    K Hirose, A Fujiwara, K Matsunaga, N Aoki, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 14　No. 5　p. 555-566　2003/03

  76. Preparation and evaluation of novel chiral stationary phases covalently bound with chiral pseudo-18-crown-6 ethers

    Keiji Hirose, Takashi Nakamura, Ryota Nishioka, Tetsuro Ueshige, Yoshito Tobe

    Tetrahedron Letters　Vol. 44　No. 8　p. 1549-1551　2003/02/17

  77. Preparation and evaluation of novel chiral stationary phases covalently bound with chiral pseudo-18-crown-6 ethers

    K Hirose, T Nakamura, R Nishioka, T Ueshige, Y Tobe

    TETRAHEDRON LETTERS　Vol. 44　No. 8　p. 1549-1551　2003/02

  78. バイアスのかかったブラウン運動を作り出す －超分子の一方向性回転を実現するスマートな解答－

    化学　2003

  79. バイアスのかかったブラウン運動をつくりだす 超分子の一方向性回転を実現するスマートな解答

    化学　Vol. 58, 11, 50-51/,　2003

  80. Creat the Brown Motion with Bias

    Kagaku　2003

  81. Chiral recognition of secondary amines by using chiral crown ether and podand

    Keiji Hirose, Akihito Fujiwara, Kazuhisa Matsunaga, Nobuaki Aoki, Yoshito Tobe

    Tetrahedron Letters　Vol. 43　No. 47　p. 8539-8542　2002/11/18

  82. Chiral recognition of secondary amines by using chiral crown ether and podand

    K Hirose, A Fujiwara, K Matsunaga, N Aoki, Y Tobe

    TETRAHEDRON LETTERS　Vol. 43　No. 47　p. 8539-8542　2002/11

  83. Chiral recognition of secondary amines by using chiral crown ether and podand

    K Hirose, A Fujiwara, K Matsunaga, N Aoki, Y Tobe

    TETRAHEDRON LETTERS　Vol. 43　No. 47　p. 8539-8542　2002/11

  84. m-diethynylbenzene macrocycles: Syntheses and self-association behavior in solution

    Y Tobe, N Utsumi, K Kawabata, A Nagano, K Adachi, S Araki, M Sonoda, K Hirose, K Naemura

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 124　No. 19　p. 5350-5364　2002/05

  85. m-diethynylbenzene macrocycles: Syntheses and self-association behavior in solution

    Y Tobe, N Utsumi, K Kawabata, A Nagano, K Adachi, S Araki, M Sonoda, K Hirose, K Naemura

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 124　No. 19　p. 5350-5364　2002/05

  86. Chiral Recognition of Secondary Amines Using Chiral Crown Ethers and Podands

    Tetrahedron Letters., 43, in press (2002)　Vol. press　2002

  87. Chiral Recognition of Secondary Amines Using Chiral Crown Ethers and Podands

    Vol. press　2002

  88. A practical guide for the determination of binding constants

    K Hirose

    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY　Vol. 39　No. 3-4　p. 193-209　2001/04　Book review, literature introduction, etc.

  89. A practical guide for the determination of binding constants

    Keiji Hirose

    Journal of Inclusion Phenomena　Vol. 39　No. 3-4　p. 193-209　2001/04　Book review, literature introduction, etc.

  90. A Practical Guide for the Determination of Binding Constants

    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY　Vol. 39, 193-209　2001

  91. Chiral recognizable host-guest interactions detected by fast-atom bombardment mass spectrometry: application to the enantiomeric excess determination of primary amines

    M Sawada, Y Takai, H Imamura, H Yamada, S Takahashi, H Yamaoka, K Hirose, Y Tobe, J Tanaka

    EUROPEAN JOURNAL OF MASS SPECTROMETRY　Vol. 7　No. 6　p. 447-459　2001

  92. Improvement of enantioselectivity in kinetic resolution of a primary alcohol through lipase-catalyzed transesterification by using a chiral acyl donor

    K Hirose, H Naka, M Yano, S Ohashi, K Naemura, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 11　No. 5　p. 1199-1210　2000/03

  93. Improvement of enantioselectivity in kinetic resolution of a primary alcohol through lipase-catalyzed transesterification by using a chiral acyl donor

    K Hirose, H Naka, M Yano, S Ohashi, K Naemura, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 11　No. 5　p. 1199-1210　2000/03

  94. Enantioselective complexation of phenolic crown ethers with chiral aminoethanol derivatives: effects of substituents of aromatic rings of hosts and guests on complexation

    K Hirose, K Ogasahara, K Nishioka, Y Tobe, K Naemura

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2　Vol. 2, 1984-1993　No. 9　p. 1984-1993　2000

  95. Enantioselective Complexation of Pho nolic Crown Ethers with Chiral Aminoethanol Derivatives : Effects of Substituents of Aromatic Rings of Hosts and Guests on Complexation

    Vol. 2, 1984-1993　2000

  96. Enantioselective complexation of phenolic crown ethers with chiral aminoethanol derivatives: effects of substituents of aromatic rings of hosts and guests on complexation

    K Hirose, K Ogasahara, K Nishioka, Y Tobe, K Naemura

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2　No. 9　p. 1984-1993　2000

  97. Improvement of enantioselectivity in kinetic resolution of a primary alcohol through lipase-catalyzed transesterification by using a chiral acyl donor

    Keiji Hirose, Hiroyuki Naka, Masashi Yano, Sozaburo Ohashi, Koichiro Naemura, Yoshito Tobe

    Tetrahedron Asymmetry　Vol. 11　No. 5　p. 1199-1210　1999/03/24

  98. 光学活性色素化クラウンエーテルによる鏡像体識別呈色-紫外可視分光光度計を用いた錯形成定数測定法-

    廣瀬 敬治, 戸部 義人, 苗村 浩一郎

    Jasco report　Vol. 41　No. 1　p. 6-17　1999/03

    Publisher: ジャスコレポ-ト社

  99. Novel self-assembly of m-xylylene type dithioureas by head-to-tail hydrogen bonding

    Y Tobe, S Sasaki, M Mizuno, K Hirose, K Naemura

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 63　No. 21　p. 7481-7489　1998/10

  100. Novel self-assembly of m-xylylene type dithioureas by head-to-tail hydrogen bonding

    Y Tobe, S Sasaki, M Mizuno, K Hirose, K Naemura

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 63　No. 21　p. 7481-7489　1998/10

  101. Novel self-assembly of m-xylylene type dithioureas by head-to-tail hydrogen bonding

    Y Tobe, S Sasaki, M Mizuno, K Hirose, K Naemura

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 63　No. 21　p. 7481-7489　1998/10

  102. Chiral amino acid recognition detected by electrospray ionization (ESI) and fast atom bombardment (FAB) mass spectrometry (MS) coupled with the enantiomer-labelled (EL) guest method

    M Sawada, Y Takai, H Yamada, J Nishida, T Kaneda, R Arakawa, M Okamoto, K Hirose, T Tanaka, K Naemura

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2　Vol. 2, 701-710　No. 3　p. 701-710　1998/03

  103. Chiral amino acid recognition detected by electrospray ionization (ESI) and fast atom bombardment (FAB) mass spectrometry (MS) coupled with the enantiomer-labelled (EL) guest method

    M Sawada, Y Takai, H Yamada, J Nishida, T Kaneda, R Arakawa, M Okamoto, K Hirose, T Tanaka, K Naemura

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2　No. 3　p. 701-710　1998/03

  104. Preparation and temperature-dependent enantioselectivities of homochiral phenolic crown ethers having aryl chiral barriers: thermodynamic parameters for enantioselective complexation with chiral amines

    K Naemura, K Nishioka, K Ogasahara, Y Nishikawa, K Hirose, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 9　No. 4　p. 563-574　1998/02

  105. Temperature dependence of enantioselectivity in complexations of optically active phenolic crown ethers with chiral amines in solution

    K Naemura, K Matsunaga, J Fuji, K Ogasahara, Y Nishikawa, K Hirose, Y Tobe

    ANALYTICAL SCIENCES　Vol. 14　No. 1　p. 175-182　1998/02

  106. Preparation of optically active azophenolic crown ethers containing 1-phenylethane-1,2-diol and 2,4-dimethyl-3-oxapentane-1,5-diol as a chiral subunit: temperature-dependent enantiomer selectivity in the complexation with chiral amines

    K Ogasahara, K Hirose, Y Tobe, K Naemura

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1　No. 21　p. 3227-3236　1997/11

  107. Temperature dependent inversion of enantiomer selectivity in the complexation of optically active azophenolic crown ethers containing alkyl substituents as chiral barriers with chiral amines

    K Hirose, J Fuji, K Kamada, Y Tobe, K Naemura

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2　No. 9　p. 1649-1657　1997/09

  108. Preparation of homochiral phenolic crown ether having chiral subunits derived from (1R,2S)-cis-1,2,3,4-tetrahydronaphthalene-1,2-diol: temperature-dependent enantioselectivity in complexations with neutral amines

    K Naemura, T Wakebe, K Hirose, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 8　No. 15　p. 2585-2595　1997/08

  109. Novel self-assembly of m-Xylylene type dithioureas

    Yoshito Tobe, Shin-Ichi Sasaki, Keiji Hirose, Koichiro Naemura

    Tetrahedron Letters　Vol. 38　No. 27　p. 4791-4794　1997/07/07

  110. Novel self-assembly of m-Xylylene type dithioureas

    Yoshito Tobe, Shin-Ichi Sasaki, Keiji Hirose, Koichiro Naemura

    Tetrahedron Letters　Vol. 38　No. 27　p. 4791-4794　1997/07/07

  111. Preparation of homochiral phenolic crown ethers containing para-substituted phenol moiety and chiral subunits derived from (S)-1-phenylethane-1,2-diol: Their chiral recognition behaviour in complexation with neutral amines

    K Naemura, Y Nishikawa, J Fuji, K Hirose, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 8　No. 6　p. 873-882　1997/03

  112. Novel Self-Assembly of m-Xylylene Type Dithioureas

    Tetrahedron Letters, 38 (27), 4791-4794 (1997).　Vol. 38 (27), 4791-4794　1997

  113. Preparation of homochiral azophenolic crown ethers containing 1-phenyltethane-1,2-diol and 2,4-dimethyl-3-oxapentane-1,5-diol as a chiral subunit: Enantiomer recognition behaviour towards chiral 2-aminoethanol derivatives

    K Naemura, K Ogasahara, K Hirose, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 8　No. 1　p. 19-22　1997/01

  114. Temperature dependent reversal of enantiomer selectivity in the complexation of optically active phenolic crown ethers with chiral amines

    K Naemura, J Fuji, K Ogasahara, K Hirose, Y Tobe

    CHEMICAL COMMUNICATIONS　No. 24　p. 2749-2750　1996/12

  115. Temperature dependent reversal of enantiomer selectivity in the complexation of optically active phenolic crown ethers with chiral amines

    K Naemura, J Fuji, K Ogasahara, K Hirose, Y Tobe

    CHEMICAL COMMUNICATIONS　No. 24　p. 2749-2750　1996/12

  116. Temperature dependent reversal of enantiomer selectivity in the complexation of optically active phenolic crown ethers with chiral amines

    K Naemura, J Fuji, K Ogasahara, K Hirose, Y Tobe

    CHEMICAL COMMUNICATIONS　No. 24　p. 2749-2750　1996/12

  117. Enantioselective acylation of primary and secondary alcohols catalyzed by lipase QL from Alcaligenes sp: A predictive active site model for lipase QL to identify which enantiomer of an alcohol reacts faster in this acylation

    K Naemura, M Murata, R Tanaka, M Yano, K Hirose, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 7　No. 11　p. 3285-3294　1996/11

  118. Chiral molecular recognition in electrospray ionization mass spectrometry

    M Sawada, Y Takai, T Kaneda, R Arakawa, M Okamoto, H Doe, T Matsuo, K Naemura, K Hirose, Y Tobe

    CHEMICAL COMMUNICATIONS　No. 15　p. 1735-1736　1996/08

  119. Enantioselective acylation of alcohols catalyzed by lipase QL from Alcaligenes sp: A predictive active site model for lipase QL to identify the faster reacting enantiomer of an alcohol in this acylation

    K Naemura, M Murata, R Tanaka, M Yano, K Hirose, Y Tobe

    TETRAHEDRON-ASYMMETRY　Vol. 7　No. 6　p. 1581-1584　1996/06

  120. Preparation and enantiomer recognition behaviour of azophenolic crown ethers containing cis-1-phenylcyclohexane-1,2-diol as the chiral subunit and 2,4-dinitrophenylazophenol as the chromophore

    K Naemura, K Ueno, S Takeuchi, K Hirose, Y Tobe, T Kaneda, Y Sakata

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1　No. 4　p. 383-388　1996/02

  121. Lipase-catalyzed enantioselective alcoholysis of enol acetates: Optical resolution of ketones and aldehydes using lipases in organic solvents

    K Naemura, K Kittaka, M Murata, H Ida, K Hirose, Y Tobe

    ENANTIOMER　Vol. 1　No. 3　p. 219-222　1996

  122. LIPASE-CATALYZED ENANTIOSELECTIVE ACYLATION OF ALCOHOLS - A PREDICTIVE ACTIVE-SITE MODEL FOR LIPASE YS TO IDENTIFY WHICH ENANTIOMER OF AN ALCOHOL REACTS FASTER IN THIS ACYLATION

    K NAEMURA, R FUKUDA, M MURATA, M KONISHI, K HIROSE, Y TOBE

    TETRAHEDRON-ASYMMETRY　Vol. 6　No. 9　p. 2385-2394　1995/09

  123. PREPARATION AND ENANTIOMER RECOGNITION OF CHIRAL AZOPHENOLIC CROWN-ETHERS HAVING 3 CHIRAL BARRIERS ON EACH OF THE HOMOTOPIC FACES

    K NAEMURA, M ASADA, K HIROSE, Y TOBE

    TETRAHEDRON-ASYMMETRY　Vol. 6　No. 8　p. 1873-1876　1995/08　Article, review, commentary, editorial, etc. (scientific journal)

  124. PREPARATION AND ENANTIOMER RECOGNITION BEHAVIOR OF AZOPHENOLIC CROWN-ETHERS CONTAINING CIS-CYCLOHEXANE-1,2-DIOL AS THE CHIRAL CENTER

    K NAEMURA, S TAKEUCHI, K HIROSE, Y TOBE, T KANEDA, Y SAKATA

    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1　No. 3　p. 213-219　1995/02

  125. 海外研究室レポート:アーヘン工科大学

    1995

  126. Preparation and enantiomer recognition behaviour of azophcnolic crown ethers containing cis-1-,2-diol as the Chiral subunit and 2,4- dinitrophenylazophenol as the chromophore

    J.Chem.Soc.Perkin trans,I　1995

  127. 超分子を研究する

    生産と技術　Vol. 46　1994

  128. The Development of Polypropylene Production

    Vol. 56,629　1992

  129. Polyethylene Production Method with Ziegler Catalyst

    Vol. 19,40　1992

  130. Polyethylene Production Method with Ziegler Catalyst

    Vol. 19,40/,　1992

  131. The Development of Polypropylene Production

    Vol. 56,629/,　1992

  132. 電荷移動積層化合物から導電性ポリシクロファンへ

    広瀬 敬治, 三角 荘一

    化学　Vol. 41　No. 7　p. 64-479　1986

    Publisher: 化学同人

Publications 6

  1. Chiral Luminescence: From Molecules to Materials and Devices,Binding Constants as Fundamental Physical Properties for;Quantitative Treatments of Sensing;Processes in Supramolecular Systems

    Complexations between a sensor molecule, substrates are fundamental, processes to develop, sensing, devices. The, ratio of, he, bindin, c, a, ions, is, eated, as, a, measure of selectivity of, a, sensor, molecule. Therefore, binding constants, have to be, determined for a quantitative analysis of a complex, formation. This chapter is devoted to, rovide a description of, heoretical backgrou, o determine, a, binding, consta, as a, fundamental, physical property, ypical determination methods using ultraviolet-visible absorption, photo-luminescence spectroscopies, followed by circular dichroism, d circular polarized luminescence spectroscopies applicable to chiral specie

    Wiley　2023

    ISBN: 9783527351800

  2. 「化学を学ぶ人のレポート・論文・発表マスターガイド 」

    化学同人　2010

  3. 「超分子サイエンス&テクノロジー」超分子生成の解析と評価

    株）エヌ・ティー・エス　2009

  4. Analytical Methods in Supramolecular Chemistry, (Ed.: Christoph A. Schalley)

    WILEY-VCH　2007

  5. 「分子認識と超分子」大環状化合物の分子認識と分子集積

    三共出版　2007

  6. 「20世紀の日本の化学技術」低圧法ポリエチレンの開発史

    ㈱ティー・アイ・シィー　2004

Works 19

  1. Chiral recognition in NMR spectroscopy using crown ethers and their ytterbium(III) complexes

    2002 - 2003

  2. Chiral recognition in NMR spectroscopy using crown ethers and their ytterbium(III) complexes

    2002 - 2003

  3. 分子認識型キラルカラムの高性能化

    2000 - 2001

  4. Improvement of molecular recognition type chiral column

    2000 - 2001

  5. 分子認識型汎用キラルカラムの開発

    1999 - 2000

  6. Development of moleculare recognition type chiral column

    1999 - 2000

  7. 刺激応答性ロタキサン型分子スケールダイオードの創製

    2008 -

  8. 刺激応答性ロタキサン型分子スケールダイオードの創製

    2007 -

  9. 混合混成型巨大炭素パイ電子系の創出

    2005 -

  10. 超高性能キラルセレクターの創出と化学結合型キラルカラムの実用化

    2004 -

  11. 混合混成型巨大炭素パイ電子系の創出

    2004 -

  12. 超高性能キラルセレクターの創出と化学結合型キラルカラムの実用化

    2003 -

  13. クラウン化合物を鍵とする方向記憶型ロタキサンメモリーの構築

    2003 -

  14. クラウン化合物を鍵とする方向記憶型ロタキサンメモリーの構築

    2002 -

  15. クラウン化合物を鍵とする方向記憶型ロタキサンメモリーの構築

    2001 -

  16. ホスト-ゲスト錯体形成による不斉認識の熱力学パラメータと分子構造との相関解明

    2001 -

  17. 分子認識型キラルカラムの高性能化

    2001 -

  18. ホスト-ゲスト錯体形成による不斉認識の熱力学パラメータと 分子構造との相関解明

    2000 -

  19. 分子認識型汎用キラルカラムの開発

    2000 -

Industrial Property Rights 26

  1. クロマトグラフィー用固定相

  2. キラルセンサー

  3. 分子ワイヤー型蛍光性キラルセンサー

  4. クロマトグラフィー用固定相

  5. 円二色性分光分析を用いるイオン検出方法

  6. オレフィン重合用触媒およびオレフィンの重合方法

  7. 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法

  8. α－オレフィンのオリゴメリゼーション触媒およびα－オレフィンのオリゴメリゼーション法

  9. オレフィン重合用触媒およびオレフィンの重合方法

  10. Fluorescent-molecule for chiral sensor, comprises fluorescent polymer with principal chain coupled to specific optically active substituent

  11. New optically active compound for use for chiral sensors has an unsaturated bond at the optically active combining site, and a conjugated fluorescent substituent

  12. High activity oligomerisation catalyst for alpha-olefin(s) comprises nickel compound, organo:aluminium oxy-compound, and trivalent phosphorus compound

  13. 分子ワイヤー型蛍光性キラルセンサー

  14. キラルセンサー

  15. クロマトグラフィー用固定相

  16. オレフィン重合用触媒およびオレフィンの重合方法

  17. 円二色性分光分析を用いるイオン検出方法

  18. フﾟロヒﾟレン重合体組成物

  19. 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法

  20. オレフィン重合用触媒およびオレフィンの重合方法

  21. α−オレフィンのオリゴメリゼーション触媒およびα−オレフィンのオリゴメリゼーション法

  22. オレフィン重合用触媒成分およびオレフィンの重合方法

  23. 環状オレフィン系共重合体の製造方法

  24. α-オレフィン系ランダム共重合体の製造方法

  25. Chiral Senser

  26. エチレン・α-オレフィンランダム共重合体の製造方法

Institutional Repository 3

Content Published in the University of Osaka Institutional Repository (OUKA)

  1. KHSynergy-Appendices E1-E4 Fundamental Aspects of Host-Guest Complexation

    Hirose Keiji

    2015/05/07

  2. Reaxys for Students : Applying E-Resources to Educational Settings

    Hirose Keiji

    薬学図書館　Vol. 58　No. 1　p. 62-72　2013/01/31

  3. ホスト－ゲスト錯形成に基づく鏡像体識別呈色の研究

    廣瀬 敬治