顔写真

PHOTO

Hoshimoto Youichi
星本　陽一
Hoshimoto Youichi
星本　陽一
Institutional repository
Graduate School of Engineering　Center for Future Innovation, Associate Professor

keyword Transition metal complexes，Organoboron compounds，Hydrogenation，Carbenes，Catalysis，Main group chemistry，Organometallic chemistry

Institutional repository

Research History 5

  1. 2023/04 - Present
    Graduate School of Engineering　Center for Future Innovation (CFi)　Associate Professor

  2. 2019/04 - Present
    Faculty of Engineering, Osaka University　Department of Applied Chemistry　Associate Professor

  3. 2023/08 - 2023/11
    Ruhr University Bochum, Germany

  4. 2018/04 - 2019/03
    Faculty of Engineering, Osaka University　Department of Applied Chemistry　Associate Professor

  5. 2013/04 - 2018/03
    Graduate School of Engineering, Osaka University　Frontier Research Baase for Global Young Researchers　Assistant Professor

Education 2

  1. Osaka University　Graduate School of Engineering

    2008/04 - 2013/03

  2. Osaka University　School of Engineering

    2004/04 - 2008/03

Committee Memberships 4

  1. American Chemical Society　Precision Chemistry Early Career Board member　Academic society

    2024/12 - Present

  2. ChemRxiv　ChemRxiv Scientific Advisory Board　Other

    2022 - Present

  3. American Chemical Society　Early Career Advisory Board of ACS Catalysis　Academic society

    2019/04 - 2020/03

  4. 公益財団法人 有機合成化学協会　編集協力委員　Academic society

    2017/04 - 2020/03

Professional Memberships 3

  1. THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN

  2. AMERICAN CHEMICAL SOCIETY

  3. THE CHEMICAL SOCIETY OF JAPAN

Research Areas 1

  1. Nanotechnology/Materials / Synthetic organic chemistry /

Awards 11

  1. The Young Scientists’ Award in The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology

    Yoichi Hoshimoto　MEXT, Japan　2025/04

  2. Merck-Banyu Lectureship Award

    Yoichi Hoshimoto　MSD Life Science Foundation, Public Interest Incorporated Foundation　2024/02

  3. Yazaki Academic Incentive Award

    Yoichi Hoshimoto　Yazaki Memorial Foundation for Science and Technology　2024/02

  4. Thieme Chemistry Journal Award

    Yoichi Hoshimoto　Thieme Chemistry　2024/01

  5. Chemist Award BCA

    Yoichi Hoshimoto　MSD Life Science Foundation, Public Interest Incorporated Foundation　2023/11

  6. Award for Encouragement of Research in the 32nd Annual Meeting of MRS-Japan

    Yoichi Hoshimoto　The Materials Research Society of Japan　2023

  7. 学術奨励賞

    公益財団法人 宇部興産学術振興財団　2021/04

  8. 第６７回進歩賞

    星本陽一　（公財）日本化学会　2018/03

  9. 優秀講演賞（学術）

    星本陽一　（公財）日本化学会　2016/06

  10. IUPAC-SOLVAY Honorable Mention Award for Young Chemists

    HOSHIMOTO Yoichi　IUPAC　2014/09

  11. 研究企画賞

    星本陽一　（公財）有機合成化学協会　2013/12

Papers 52

  1. Main group catalysis for H 2 purification based on liquid organic hydrogen carriers

    Taiki Hashimoto, Takahiro Asada, Sensuke Ogoshi, Yoichi Hoshimoto

    Science Advances　Vol. 8　No. 43　2022/10/28　Research paper (scientific journal)

    Publisher: American Association for the Advancement of Science (AAAS)

  2. Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes

    Yasuhiro Yamauchi, Yoichi Hoshimoto, Takahiro Kawakita, Takuya Kinoshita, Yuta Uetake, Hidehiro Sakurai, Sensuke Ogoshi

    Journal of the American Chemical Society　Vol. 49th (CD-ROM)　2022/05/03　Research paper (scientific journal)

    Publisher: American Chemical Society ({ACS})

  3. A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts

    Yoichi Hoshimoto, Mahiro Sakuraba, Takuya Kinoshita, Masaki Ohbo, Manussada Ratanasak, Jun-ya Hasegawa, Sensuke Ogoshi

    Communications Chemistry　Vol. 4　No. 1　2021/10　Research paper (scientific journal)

    Publisher: Springer Science and Business Media LLC

  4. Development of Metal Complexes Equipped with Structurally Flexible Carbenes

    Yoichi Hoshimoto, Sensuke Ogoshi

    Bulletin of the Chemical Society of Japan　Vol. 94　No. 1　p. 327-338　2021/01/15　Research paper (scientific journal)

    Publisher: The Chemical Society of Japan

  5. Rotation-Triggered Transmetalation on a Heterobimetallic Cu/Al N-Phosphine-Oxide-Substituted Imidazolylidene Complex

    Takahiro Asada, Yoichi Hoshimoto, Sensuke Ogoshi

    Journal of the American Chemical Society　2020/05/27　Research paper (scientific journal)

    Publisher: American Chemical Society ({ACS})

  6. Triarylborane-Catalyzed Reductive N-Alkylation of Amines: A Perspective

    Yoichi Hoshimoto, Sensuke Ogoshi

    ACS Catalysis　Vol. 9　No. 6　p. 5439-5444　2019/06/07　Research paper (scientific journal)

  7. Main-Group-Catalyzed Reductive Alkylation of Multiply Substituted Amines with Aldehydes Using H2

    Yoichi Hoshimoto, Takuya Kinoshita, Sunit Hazra, Masato Ohashi, Sensuke Ogoshi

    Journal of the American Chemical Society　Vol. 140　No. 23　p. 7292-7300　2018/06/13　Research paper (scientific journal)

  8. A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes

    Hoshimoto, Yoichi, Kinoshita, Takuya, Ohashi, Masato, Ogoshi, Sensuke

    Angewandte Chemie-International Edition　Vol. 54　No. 40　p. 11666-11671　2015　Research paper (scientific journal)

  9. Monodentate σ-Accepting Boron-Based Ligands Bearing Square-Planar Ni(0) Centers

    Yutaka Mondori, Yasuhiro Yamauchi, Takahiro Kawakita, Sensuke Ogoshi, Yuta Uetake, Yasuo Takeichi, Hidehiro Sakurai, Yoichi Hoshimoto

    Journal of the American Chemical Society　2025/02/28　Research paper (scientific journal)

    Publisher: American Chemical Society (ACS)

  10. Transformation of CO2 and isocyanates mediated by N-borane-substituted cyclic phosphine imides (BCPIs) via λ5-oxazaphosphetanes

    Shun Nagai, Sensuke Ogoshi, Yoichi Hoshimoto

    Organic & Biomolecular Chemistry　2025　Research paper (scientific journal)

  11. Elucidating multicomponent mechanisms in the catalytic hydrogenation of 2-methylquinoline under crude-H2 conditions: a key H2-cleavage process by a boron–olefin Lewis pair

    Taiki Hashimoto, Yu Harabuchi, Sensuke Ogoshi, Satoshi Maeda, Yoichi Hoshimoto

    Bulletin of the Chemical Society of Japan　Vol. 98　No. 1　2024/12/30　Research paper (scientific journal)

    Publisher: Oxford University Press (OUP)

  12. Boosting Turnover in the Triarylborane-Catalyzed Hydrogenation of N-Substituted Indoles via Olefin-to-Nitrogen Lewis Base Switching in H2-Cleavage Steps

    Taiki Hashimoto, Masakazu Tanigawa, Kimitaka Kambe, Sensuke Ogoshi, Yoichi Hoshimoto

    Precision Chemistry　2024/12/18　Research paper (scientific journal)

  13. Recent Trends in Triarylborane Chemistry: Diversification of Structures and Reactivity via meta-Substitution of the Aryl Groups

    Yoichi Hoshimoto, Mahiro Sakuraba

    Synthesis　2024/11　Research paper (scientific journal)

  14. Reversible Modulation of the Local Environment around Metal Centers Bearing Multifunctional Carbenes

    Yasuhiro Yamauchi, Sensuke Ogoshi, Yuta Uetake, Yoichi Hoshimoto

    Chemistry Letters　2024/03/07　Research paper (scientific journal)

    Publisher: Oxford University Press (OUP)

  15. Electronic Profiling of N-Phosphine Oxide-Substituted Imidazolin-2-ylidenes (PoxIms) and Imidazolidin-2-ylidenes (SPoxIms)

    Jia Nuo Leung, Yutaka Mondori, Sensuke Ogoshi, Yoichi Hoshimoto, Han Vinh Huynh

    Inorganic Chemistry　Vol. 63　No. 9　p. 4344-4354　2024/03/04　Research paper (scientific journal)

  16. Strategic use of crude H2 for the catalytic reduction of carbonyl compounds

    Mahiro Sakuraba, Sensuke Ogoshi, Yoichi Hoshimoto

    Tetrahedron Chem　2024/03　Research paper (scientific journal)

  17. In-Silico-Assisted Derivatization of Triarylboranes for the Catalytic Reductive Functionalization of Amino Acids with H2

    Yusei Hisata, Takashi Washio, Shinobu Takizawa, Sensuke Ogoshi, Yoichi Hoshimoto

    Nature Communications　2023/11/03　Research paper (scientific journal)

  18. Reversible Modulation of the Electronic and Spatial Environment around Ni(0) Centers Bearing Multifunctional Carbene Ligands with Triarylaluminum

    Yasuhiro Yamauchi, Yutaka Mondori, Yuta Uetake, Yasuo Takeichi, Takahiro Kawakita, Hidehiro Sakurai, Sensuke Ogoshi, Yoichi Hoshimoto

    Journal of the American Chemical Society　2023/07/19　Research paper (scientific journal)

    Publisher: American Chemical Society (ACS)

  19. Remote Back Strain: A Strategy for Modulating the Reactivity of Triarylboranes

    Mahiro Sakuraba, Taichi Morishita, Taiki Hashimoto, Sensuke Ogoshi, Yoichi Hoshimoto

    Synlett　2023/06/14　Research paper (scientific journal)

  20. N-Borane-Substituted Cyclic Phosphine Imides (BCPIs)

    Shun Nagai, Takaya Hinogami, Sensuke Ogoshi, Yoichi Hoshimoto

    2023/02/17

  21. Complexation-Induced N‒P Axial Chirality in Sm(II) N-Phosphine-Oxide-Substituted Imidazolylidene and Imidazolinylidene Complexes

    Yoichi Hoshimoto, Yasuhiro Yamauchi, Tomoya Terada, Sensuke Ogoshi

    Canadian Journal of Chemistry　2022/10/06　Research paper (scientific journal)

  22. Ni(0)-Catalyzed Synthesis of Polycyclic α,β-Unsaturated γ-Lactams via Intramolecular Carbonylative Cycloaddition of Yne-imines with CO

    Keita Ashida, Yoichi Hoshimoto, Sensuke Ogoshi

    Synlett　Vol. 32　No. 15　p. 1537-1541　2021/09/16　Research paper (scientific journal)

  23. Sm(II)-mediated Single-electron Reduction of Pentafluorophenylcopper(I)

    Yasuhiro Yamauchi, Shun Nagai, Tomoya Terada, Yoichi Hoshimoto, Sensuke Ogoshi

    Chemistry Letters　Vol. 50　No. 7　p. 1394-1396　2021/07/05　Research paper (scientific journal)

    Publisher: The Chemical Society of Japan

  24. N ‐Phosphine Imide‐Substituted Imidazolylidenes

    Yoichi Hoshimoto, Shun Nagai, Takaya Hinogami, Sunit Hazra, Sensuke Ogoshi

    Asian Journal of Organic Chemistry　Vol. 10　No. 5　p. 1085-1089　2021/05/12　Research paper (scientific journal)

    Publisher: Wiley

  25. Axial Chirality around N–P Bonds Induced by Complexation between E(C6F5)3 (E = B, Al) and an N-Phosphine Oxide-Substituted Imidazolinylidene: A Key Intermediate in the Catalytic Phosphinoylation of CO2

    Takahiro Asada, Yoichi Hoshimoto, Takahiro Kawakita, Takuya Kinoshita, Sensuke Ogoshi

    The Journal of Organic Chemistry　Vol. 85　No. 22　p. 14333-14341　2020/11/20　Research paper (scientific journal)

    Publisher: American Chemical Society ({ACS})

  26. Catalytic synthesis of isoquinolines via intramolecular migration of n-aryl sulfonyl groups on 1,5-yne-imines

    Yoichi Hoshimoto, Chika Nishimura, Yukari Sasaoka, Ravindra Kumar, Sensuke Ogoshi

    Bulletin of the Chemical Society of Japan　Vol. 93　No. 2　p. 182-186　2020/02/01　Research paper (scientific journal)

  27. Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions without Stirring.

    Keita Ashida, Yoichi Hoshimoto, Norimitsu Tohnai, David E Scott, Masato Ohashi, Hanae Imaizumi, Yuichiro Tsuchiya, Sensuke Ogoshi

    Journal of the American Chemical Society　Vol. 142　No. 3　p. 1594-1602　2020/01/22　Research paper (scientific journal)

    Publisher: American Chemical Society ({ACS})

  28. Complexation between MOTf (M = Li and Na) and N-Phosphine Oxide-substituted Imidazolylidenes via Coordination of the N-Phosphoryl Groups

    Kinoshita Takuya, Sakuraba Mahiro, Hoshimoto Yoichi, Ogoshi Sensuke

    CHEMISTRY LETTERS　Vol. 48　No. 3　p. 230-233　2019/03

  29. Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel

    Ravindra Kumar, Yoichi Hoshimoto, Eri Tamai, Masato Ohashi, Sensuke Ogoshi

    Nature Communications　Vol. 8　2017/12　Research paper (scientific journal)

  30. N -Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes

    Sunit Hazra, Yoichi Hoshimoto, Sensuke Ogoshi

    Chemistry - A European Journal　Vol. 23　No. 61　p. 15238-15243　2017/11/02　Research paper (scientific journal)

  31. Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates

    Yoichi Hoshimoto, Keita Ashida, Yukari Sasaoka, Ravindra Kumar, Ken Kamikawa, Xavier Verdaguer, Antoni Riera, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie International Edition　Vol. 56　No. 28　p. 8206-8210　2017/07/03　Research paper (scientific journal)

  32. Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates

    Yoichi Hoshimoto, Keita Ashida, Yukari Sasaoka, Ravindra Kumar, Ken Kamikawa, Xavier Verdaguer, Antoni Riera, Masato Ohashi, Sensuke Ogoshi

    Angewandte Chemie　Vol. 129　No. 28　p. 8318-8322　2017/07/03　Research paper (scientific journal)

    Publisher: Wiley-Blackwell

  33. Phosphorylation of Isocyanates and Aldehydes Mediated by Multifunctional N-Phosphine Oxide-substituted Imidazolylidenes

    Hoshimoto, Yoichi, Asada, Takahiro, Hazra, Sunit, Ohashi, Masato, Ogoshi, Sensuke

    Chemistry Letters　Vol. 46　No. 8　p. 1211-1213　2017　Research paper (scientific journal)

  34. Nickel(0)-catalyzed Coupling Reactions of Carbonyls and Alkenes with Reducing Reagents Giving Six- and Seven-membered Benzocycloalkanols

    Hayashi, Yukari, Hoshimoto, Yoichi, Kumar, Ravindra, Ohashi, Masato, Ogoshi, Sensuke

    Chemistry Letters　Vol. 46　No. 8　p. 1096-1098　2017　Research paper (scientific journal)

  35. Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand.

    Tao, W, Akita, S, Nakano, R, Ito, S, Hoshimoto, Y, Ogoshi, S, Nozaki, K

    Chemical communications (Cambridge, England)　Vol. 53　No. 17　p. 2630-2633　2017　Research paper (scientific journal)

  36. Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic-Phosphinic Mixed Anhydride from CO2.

    Hoshimoto, Yoichi, Asada, Takahiro, Hazra, Sunit, Kinoshita, Takuya, Sombut, Panukorn, Kumar, Ravindra, Ohashi, Masato, Ogoshi, Sensuke

    Angewandte Chemie (International ed. in English)　Vol. 55　No. 52　p. 16075-16079　2016　Research paper (scientific journal)

  37. Nickel-Catalyzed Enantioselective Synthesis of Cyclobutenes via [2+2] Cycloaddition of alpha,beta-Unsaturated Carbonyls with 1,3-Enynes

    Kumar, Ravindra, Tamai, Eri, Ohnishi, Akira, Nishimura, Akira, Hoshimoto, Yoichi, Ohashi, Masato, Ogoshi, Sensuke

    Synthesis-Stuttgart　Vol. 48　No. 17　p. 2789-2794　2016　Research paper (scientific journal)

  38. Nickel(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilanes

    Hayashi, Yukari, Hoshimoto, Yoichi, Kumar, Ravindra, Ohashi, Masato, Ogoshi, Sensuke

    Chemical Communications　Vol. 52　No. 37　p. 6237-6240　2016　Research paper (scientific journal)

  39. Kinetic and Theoretical Studies on Ni(0)/N-Heterocyclic Carbene-Catalyzed Intramolecular Alkene Hydroacylation.

    Hoshimoto, Yoichi, Hayashi, Yukari, Ohashi, Masato, Ogoshi, Sensuke

    Chemistry, an Asian journal　Vol. 12　No. 3　p. 278-282　2016　Research paper (scientific journal)

  40. Nickel(0)/N-Heterocyclic Carbene-Catalyzed Asymmetric [2+2+2] Cycloaddition of Two Enones and an Alkyne: Access to Cyclohexenes with Four Contiguous Stereogenic Centers

    Ravindra Kumar, Hiromu Tokura, Akira Nishimura, Tadashi Mori, Yoichi Hoshimoto, Masato Ohashi, Sensuke Ogoshi

    ORGANIC LETTERS　Vol. 17　No. 24　p. 6018-6021　2015/12　Research paper (scientific journal)

  41. Pentacoordinated Carboxylate π-Allyl Nickel Complexes as Key Intermediates for the Ni-Catalyzed Direct Amination of Allylic Alcohols

    Yusuke Kita, Hironobu Sakaguchi, Yoichi Hoshimoto, Daisuke Nakauchi, Yasuhito Nakahara, Jean François Carpentier, Sensuke Ogoshi, Kazushi Mashima

    Chemistry - A European Journal　Vol. 21　No. 41　p. 14571-14578　2015/10/01　Research paper (scientific journal)

  42. Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

    Ravindra Kumar, Yoichi Hoshimoto, Hayato Yabuki, Masato Ohashi, Sensuke Ogoshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 137　No. 36　p. 11838-11845　2015/09　Research paper (scientific journal)

  43. Catalytic Transformation of Aldehydes with Nickel Complexes through eta(2) Coordination and Oxidative Cyclization

    Hoshimoto, Yoichi, Ohashi, Masato, Ogoshi, Sensuke

    Accounts of Chemical Research　Vol. 48　No. 6　p. 1746-1755　2015　Research paper (scientific journal)

  44. Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions

    Ohashi, Masato, Hoshimoto, Yoichi, Ogoshi, Sensuke

    Dalton Transactions　Vol. 44　No. 27　p. 12060-12073　2015　Research paper (scientific journal)

  45. Highly Efficient Activation of Organosilanes with eta(2)-Aldehyde Nickel Complexes: Key for Catalytic Syntheses of Aryl-, Vinyl-, and Alkynyl-Benzoxasiloles

    Yoichi Hoshimoto, Hayato Yabuki, Ravindra Kumar, Haruka Suzuki, Masato Ohashi, Sensuke Ogoshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 136　No. 48　p. 16752-16755　2014/12　Research paper (scientific journal)

  46. Nickel(0)-Catalyzed [2+2+1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to gamma-Lactams

    Yoichi Hoshimoto, Tomoya Ohata, Yukari Sasaoka, Masato Ohashi, Sensuke Ogoshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 136　No. 45　p. 15877-15880　2014/11　Research paper (scientific journal)

  47. Capturing 2,2-Diamino Enols: A "Missing Link" in Umpolung Reaction of Aldehydes by N-Heterocyclic Carbenes

    Yoichi Hoshimoto

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN　Vol. 72　No. 10　p. 1158-1159　2014/10　Research paper (scientific journal)

  48. Nickel-Catalyzed Synthesis of N-Aryl-1,2-dihydropyridines by [2+2+2] Cycloaddition of Imines with Alkynes through T-Shaped 14-Electron Aza-Nickelacycle Key Intermediates

    Yoichi Hoshimoto, Tomoya Ohata, Masato Ohashi, Sensuke Ogoshi

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 20　No. 14　p. 4105-4110　2014/04　Research paper (scientific journal)

  49. One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(eta(6)-arene)Ni(N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni-0-NHC Unit

    Yoichi Hoshimoto, Yukari Hayashi, Haruka Suzuki, Masato Ohashi, Sensuke Ogoshi

    ORGANOMETALLICS　Vol. 33　No. 5　p. 1276-1282　2014/03　Research paper (scientific journal)

  50. Synthesis of Five- and Six-Membered Benzocyclic Ketones through Intramolecular Alkene Hydroacylation Catalyzed by Nickel(0)/N-Heterocyclic Carbenes

    Yoichi Hoshimoto, Yukari Hayashi, Haruka Suzuki, Masato Ohashi, Sensuke Ogoshi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 51　No. 43　p. 10812-10815　2012　Research paper (scientific journal)

  51. Nickel-Catalyzed Selective Conversion of Two Different Aldehydes to Cross-Coupled Esters

    Yoichi Hoshimoto, Masato Ohashi, Sensuke Ogoshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 133　No. 13　p. 4668-4671　2011/04　Research paper (scientific journal)

  52. Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex

    Sensuke Ogoshi, Yoichi Hoshimoto, Masato Ohashi

    CHEMICAL COMMUNICATIONS　Vol. 46　No. 19　p. 3354-3356　2010　Research paper (scientific journal)

Misc. 26

  1. 粗水素から水素を抜き出す世界初の分子技術「粗水素活用社会」への扉は開かれた!?

    橋本大輝, 星本陽一

    クリーンエネルギー　Vol. 32　No. 4　2023

  2. Triarylborane-Catalyzed Reductive Alkylation of Amino Acids with H2

    久田悠靖, 生越専介, 星本陽一

    日本化学会春季年会講演予稿集(Web)　Vol. 103rd　2023

  3. Nickel Complexes Bearing Triarylborane and N-Phosphine Oxide-Substituted Imidazolinylidenes

    水取宥敬, 山内泰宏, 植竹裕太, 植竹裕太, 櫻井英博, 櫻井英博, 生越専介, 星本陽一

    日本化学会春季年会講演予稿集(Web)　Vol. 103rd　2023

  4. XAFSによる特異な構造をもつニッケル-ボラン錯体の電子状態解析

    植竹裕太, 植竹裕太, 水取宥敬, 山内泰宏, 星本陽一, 生越專介, 櫻井英博, 櫻井英博

    触媒討論会予稿集(CD-ROM)　Vol. 132nd　2023

  5. 化学系プレプリントサーバー ChemRxivが呼んでいる!

    星本陽一, 生長幸之助

    現代化学　No. 617　2022

  6. Synthesis of Nickel Complexes Bearing B(C6F5)3 and N-Phosphine Oxide-Substituted Imidazolinylidenes

    水取宥敬, 山内泰宏, 植竹裕太, 植竹裕太, 櫻井英博, 櫻井英博, 星本陽一, 生越専介

    日本化学会春季年会講演予稿集(Web)　Vol. 102nd　2022

  7. Organoborane-Catalyzed Reductive Alkylation of Amino Acids with H2

    久田悠靖, 橋本大輝, 木下拓也, 星本陽一, 生越専介

    日本化学会春季年会講演予稿集(Web)　Vol. 102nd　2022

  8. Catalytic Hydrogenation of Pyridine Derivatives Using Organoborane Catalysts

    橋本大輝, 浅田貴大, 星本陽一, 生越専介

    日本化学会春季年会講演予稿集(Web)　Vol. 102nd　2022

  9. Reductive Alkylation of Amino Acids with H2 using FLPs Comprising Cyclic Ethers and Triaryl Boranes

    久田悠靖, 星本陽一, 生越専介

    複素環化学討論会講演要旨集　Vol. 51st　2022

  10. Reductive Alkylation of Amino Acids Using H2 as the Reductant by the Strategic Introduction of Fluorine Groups into BAr3 Catalysts

    久田悠靖, 生越専介, 星本陽一

    フッ素化学討論会講演要旨集　Vol. 45th　2022

  11. Reductive Alkylation of Amino Acids with H2 using FLPs Comprising Ethers and Triaryl Boranes

    久田悠靖, 生越専介, 星本陽一

    有機典型元素化学討論会講演要旨集　Vol. 49th (CD-ROM)　2022

  12. Nickel Complexes Bearing B(C6F5)3 and N-Phosphine Oxide-Substituted Imidazolinylidene

    水取宥敬, 山内泰宏, 植竹裕太, 植竹裕太, 櫻井英博, 櫻井英博, 星本陽一, 生越専介

    有機典型元素化学討論会講演要旨集　Vol. 49th (CD-ROM)　2022

  13. Synthesis of Cyclic Phosphine Imides bearing N-Boryl Substituents

    長井駿, 星本陽一, 生越專介

    日本化学会春季年会講演予稿集(Web)　Vol. 102nd　2022

  14. H2 Purification through Sequential Hydrogenation/Dehydrogenation of N-Heterocycles Using Triarylborane Catalysts

    橋本大輝, 浅田貴大, 生越專介, 星本陽一

    複素環化学討論会講演要旨集　Vol. 51st　2022

  15. Synthesis and Reactivity of N-Borane Substituted Cyclic Phosphine Imides

    長井駿, 星本陽一, 生越專介

    複素環化学討論会講演要旨集　Vol. 51st　2022

  16. GEneration of Frustrated Lewis Pairs from N-Heterocyclic Carbene-Borane Adducts via Triarylborane Transfer

    櫻羽真煕, 星本陽一, 長谷川淳也, 生越專介

    複素環化学討論会講演要旨集　Vol. 51st　2022

  17. Catalytic Hydrogenation of Carbonyl Compounds Using H2/CO/CO2 Gas as H2 Source

    櫻羽真煕, 生越專介, 星本陽一

    有機典型元素化学討論会講演要旨集　Vol. 49th (CD-ROM)　2022

  18. N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms) as Multifunctional Multipurpose N-Heterocyclic Carbenes

    山内泰宏, 星本陽一, 生越專介

    有機合成化学協会誌　Vol. 79　No. 7　2021

  19. Effects of meta-Substituents in Triarylborane Catalysts on Hydrogenation of N-Heterocycles

    橋本大輝, 浅田貴大, 星本陽一, 生越專介

    日本化学会春季年会講演予稿集(Web)　Vol. 101st　2021

  20. Reversible Chemisorption of CO at Room Temperature on Solid-State Ni(0) Complexes Dispersing into Ionic Liquids

    山内泰宏, 星本陽一, 生越專介

    錯体化学会討論会講演要旨集　Vol. 71st (CD-ROM)　2021

  21. Synthesis of N-Phosphine Imide-Substituted Imidazolylidenes and Their Reactivity Toward Lewis Acids

    長井駿, 星本陽一, 生越專介

    有機典型元素化学討論会講演要旨集　Vol. 48th (CD-ROM)　2021

  22. Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions

    芦田慶太, 星本陽一, 生越専介

    Jasco Report　Vol. 62　No. 2　2020

  23. Multifunctional multipurpose Carbenes

    Manufactuaring ＆ Technology　Vol. 72　No. 1　p. 77-80　2020　Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)

  24. 高反応性ルイス酸-塩基会合体を触媒とした含窒素環式化合物の水素化/脱水素化を鍵とする粗水素からの水素貯蔵

    浅田貴大, 星本陽一, 生越専介

    触媒討論会討論会A予稿集(CD-ROM)　Vol. 124th　2019

  25. Multifunctional multipurpose Carbenes

    Yoichi Hoshimoto

    Chemical Industry　Vol. 69　No. 7　p. 1-5　2018　Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)

  26. ついに攻略!! 難攻不落の交差ティッシェンコ反応--Ni(O)を触媒とするアルデヒドの交差エステル合成

    星本 陽一, 大橋 理人, 生越 専介

    化学　Vol. 66　No. 9　p. 12-16　2011/09

    Publisher: 化学同人

Publications 3

  1. 水素の製造とその輸送,貯蔵,利用技術

    橋本大輝, 星本陽一

    技術情報協会　2022/09

    ISBN: 9784861048999

  2. Nickel Catalysis in Organic Synthesis: Methos and Reactions

    Wiley-VCH: Germany　2019/11

  3. 炭素循環社会に向けた製造・貯蔵・利用の最前線

    森下泰地、橋本大輝、櫻羽真熙、星本陽一

    エヌ・ティー・エス　2024/04

    ISBN: 9784860438937

Presentations 28

  1. PoxIms: Multifunctional Multipurpose Carbenes

    Yoichi Hoshimoto

    MPC Webinar, CDRI Luckow, India (on-ine)　2021/08/28

  2. Development of Organometallics Catalysts with Structual Flexible Carbene Ligands

    Yoichi Hoshimoto

  3. A Frustration Revival System: Concept Development

    Yoichi Hoshimoto

    International Symposium on Pure ＆ Applied Chemistry (ISPAC) 2017

  4. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    Merck-Banyu Lecture at Stanford University　2024/10

  5. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    Merck-Banyu Lecture at UC Berkeley　2024/10

  6. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    Merck-Banyu Lecture at Massachusetts Institute of Technology　2024/10

  7. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    Merck-Banyu Lecture at ETH Zurich　2024/10

  8. Molecule-Based Approaches for Sustainable H2 Production

    Yoichi Hoshimoto

    Special Lecture at t at University of Cape Town　2024/08

  9. A New Strategy for Molecule-Based Gas Purification

    Yoichi Hoshimoto

    6th South Africa-Japan University Forum (SAJU 6)　2024/08

  10. Exploring Novel Strategies for Harnessing Triarylboranes Catalysis

    Yoichi Hoshimoto

    The 9th Sino-Japanese Symposium on Organic Chemistry for Young Scientists　2024/06

  11. 分子触媒の新手 フラストレーションを制御する機能の探求

    星本 陽一

    第35 回万有仙台シンポジウム　2024/05

  12. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    2024/04

  13. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    Organic Chemistry Colloquium, RWTH Aachen University, Germany　2023/11

  14. Exploring Ways to Harness N-Heterocyclic Carbenes and Triarylboranes in Organometallic and Synthetic Chemistry

    Yoichi Hoshimoto

    Anorganisch-Chemische Colloquium, Universität Würzburg, Germany　2023/09

  15. Molecular-Based Approaches for Sustainable H2 Production Promoting Waste-to-H2 Strategy

    Yoichi Hoshimoto

    RESOLV Colloquium, Ruhr University Bochum, Germany　2023/09

  16. Exploring Novel Strategies for Harnessing ‘Molecular Frustration’ in Main-Group-Catalyzed Organic Synthesis

    Yoichi Hoshimoto

    ACS Science Talk　2023/08

  17. A New Strategy for Gas Purification using Ni/PoxIm Complexes or Frustrated Lewis Pairs

    Yoichi Hoshimoto

    Asian International Symposium, The 103rd CSJ Annual Meeting　2023/03

  18. Main-group Catalysis for H2 Purification Based on Liquid Organic Hydrogen Carriers

    Yoichi Hoshimoto

    11th Singapore International Chemistry Conference (SICC-11)　2022/12

  19. Multifunctional Multipurpose Carbenes

    Yoichi Hoshimoto

    2019/06/28

  20. Multifunctional Multipurpose Carbenes

    Y. Hoshimoto

    Workshop of Hybrid Catalysis for Enabling Molecular Synthesis on Demand

  21. Multifunctional Multipurpose Carbenes

    Yoichi Hoshimoto

    ITbM/IGER Chemistry Workshop 2017　2017/11/06

  22. A Frustration Revival Strategy with Shelf-Stable Carbene-Borane Adducts

    Yoichi Hoshimoto, Takuya Kinoshita, Masato Ohashi, Sensuke Ogoshi

    The 12th International Conference of Heteroatom Chemistry (ICHAC-12)

  23. A Frustration Revival System

    Yoichi Hoshimoto

    398th Institute for Catalysis (ICAT) Colloquium　2017/02/09

  24. Frustration Revival System: Concept and Utilization

    Yoichi Hoshimoto

    The 9th Symposium on Organocatalyst

  25. Thermally Induced Generation of Frustrated Lewis Pairs From Shelf-stable Carbene Borane Complexes

    Yoichi Hoshimoto, Takuya Kinoshita, Masato Ohashi, Sensuke Ogoshi

    the 27th International Conference on Organometallic Chemistry (ICOMC 2016)

  26. A Novel N-Heterocyclic Carbene Equipped With Multifunctional Phosphine Oxide

    Yoichi Hoshimoto, Sensuke Ogoshi

    27TH European Colloquium on Heterocyclic Chemistry (ECHC)

  27. Catalytic Synthesis of Benzoxasiloles via Activation of Organosilanes Using h2-Aldehyde Nickel(0)/Complexes

    Yoichi Hoshimoto, Ravindra Kumar, Masato Ohashi, Sensuke Ogoshi

    The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)

  28. Practical Synthesis of (η6-Arene)Ni(NHC) Complexes and Their Application for Organonickel Chemistry

    Yoichi Hoshimoto

    ICOMC 2014 Post-Symposium in Osaka　2014/07/19

Industrial Property Rights 8

  1. ホウ素化合物、およびそれを用いた水素化物、重合体ならびに付加体の製造方法

    星本 陽一, 生越 專介, 川本 教博, 田中 智章

    特許第7079696号

    出願日:2018/08/29

    登録日:2022/05/25

  2. ホウ素化合物、およびそれを用いた水素化、重合体ならびに付加体の製造方法

    星本 陽一, 生越 專介, 川本 教博, 田中 智章

    特許7079696

    出願日:2018/08/29

    登録日:2022/05/25

  3. ルイス塩基-ルイス酸錯体及びその製造方法

    星本 陽一, 生越 專介, 川本 教博

    特許第6569973号

    出願日:2014/10/07

    登録日:2019/08/16

  4. ルイス塩基−ルイス酸錯体及びその製造方法

    星本 陽一, 生越 專介, 川本 教博

    特許6569973

    出願日:2014/10/07

    登録日:2019/08/16

  5. ホウ素化合物、およびそれを用いた水素化物、重合体ならびに付加体の製造方法

    星本 陽一, 生越 專介

    出願日:2023/10/30

  6. ホウ素化合物、およびそれを用いた水素化物、重合体ならびに付加体の製造方法

    星本 陽一, 生越 專介, 川本 教博, 田中 智章

    出願日:2018/08/29

  7. 不飽和化合物の水素化方法

    星本 陽一, 生越 專介, 田中 智章, 川本 教博

    出願日:2016/05/20

  8. ルイス塩基-ルイス酸錯体及びその製造方法

    星本 陽一, 生越 專介, 川本 教博

    出願日:2014/10/07

Institutional Repository 11

Content Published in the University of Osaka Institutional Repository (OUKA)

  1. Monodentate σ-Accepting Boron-Based Ligands Bearing Square-Planar Ni(0) Centers

    Mondori Yutaka, Yamauchi Yasuhiro, Kawakita Takahiro, Ogoshi Sensuke, Uetake Yuta, Takeichi Yasuo, Sakurai Hidehiro, Hoshimoto Yoichi

    Journal of the American Chemical Society　Vol. 147　No. 10　p. 8326-8335　2025/03/12

  2. In-silico-assisted derivatization of triarylboranes for the catalytic reductive functionalization of aniline-derived amino acids and peptides with H₂

    Hisata Yusei, Washio Takashi, Takizawa Shinobu, Ogoshi Sensuke, Hoshimoto Yoichi

    Nature Communications　Vol. 15　2024/05/07

  3. Reversible modulation of the local environment around metal centers bearing multifunctional carbenes

    Yamauchi Yasuhiro, Ogoshi Sensuke, Uetake Yuta, Hoshimoto Yoichi

    Chemistry Letters　Vol. 53　No. 3　2024/03/07

  4. Electronic Profiling of N-Phosphine Oxide-Substituted Imidazolin-2-ylidenes (PoxIms) and Imidazolidin-2-ylidenes (SPoxIms)

    Leung Jia Nuo, Mondori Yutaka, Ogoshi Sensuke, Hoshimoto Yoichi, Huynh Han Vinh

    Inorganic Chemistry　Vol. 63　No. 9　p. 4344-4354　2024/03/04

  5. Reversible Modulation of the Electronic and Spatial Environment around Ni(0) Centers Bearing Multifunctional Carbene Ligands with Triarylaluminum

    Yamauchi Yasuhiro, Mondori Yutaka, Uetake Yuta, Takeichi Yasuo, Kawakita Takahiro, Sakurai Hidehiro, Ogoshi Sensuke, Hoshimoto Yoichi

    Journal of the American Chemical Society　Vol. 145　No. 30　p. 16938-16947　2023/07/19

  6. Main group catalysis for H2 purification based on liquid organic hydrogen carriers

    Hashimoto Taiki, Asada Takahiro, Ogoshi Sensuke, Hoshimoto Yoichi

    Science Advances　Vol. 8　No. 43　2022/10/28

  7. Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes

    Yamauchi Yasuhiro, Hoshimoto Yoichi, Kawakita Takahiro, Kinoshita Takuya, Uetake Yuta, Sakurai Hidehiro, Ogoshi Sensuke

    Journal of the American Chemical Society　Vol. 144　No. 19　p. 8818-8826　2022/05/03

  8. A boron-transfer mechanism mediating the thermally induced revival of frustrated carbene–borane pairs from their shelf-stable adducts

    Hoshimoto Yoichi, Sakuraba Mahiro, Kinoshita Takuya, Ohbo Masaki, Ratanasak Manussada, Hasegawa Jun ya, Ogoshi Sensuke

    Communications Chemistry　Vol. 4　No. 1　2021/10/01

  9. Axial chirality around N-P bonds induced by complexation between E(C6F5)3 (E = B, Al) and an N-phosphine oxide-substituted imidazolinylidene: A key intermediate in the catalytic phosphinoylation of CO2

    Asada Takahiro, Hoshimoto Yoichi, Kawakita Takahiro, Kinoshita Takuya, Ogoshi Sensuke

    Journal of Organic Chemistry　Vol. 85　No. 22　p. 14333-14341　2020/11/20

  10. Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic–Phosphinic Mixed Anhydride from CO2

    Hoshimoto Yoichi, Asada Takahiro, Hazra Sunit, Kinoshita Takuya, Sombut Panukorn, Kumar Ravindra, Ohashi Masato, Ogoshi Sensuke

    Angewandte Chemie - International Edition　Vol. 55　No. 52　p. 16075-16079　2015/07/08

  11. Studies on Catalytic Transformation of Aldehydes via η^2-Coordination to Nickel(0)

    Hoshimoto Yoichi