顔写真

PHOTO

Ryo Shintani
新谷 亮
Ryo Shintani
新谷 亮
Institutional repository
Graduate School of Engineering Science　Department of Materials Engineering Science, Professor
Institutional repository

Research History 4

  1. 2017/04 - Present
    Osaka University　Graduate School of Engineering Science　Professor

  2. 2012/08 - 2017/03
    The University of Tokyo　Graduate School of Engineering　Associate Professor

  3. 2007/04 - 2012/08
    Kyoto University　Graduate School of Science　Assistant Professor

  4. 2003/10 - 2007/03
    Kyoto University　Graduate School of Science　Assistant Professor

Education 1

  1. Massachusetts Institute of Technology　Department of Chemistry

    1999/09 - 2003/07

Research Areas 1

  1. Nanotechnology/Materials / Synthetic organic chemistry /

Awards 9

  1. フロンティア材料研究所学術賞（研究業績部門）

    2025

  2. 日本化学会学術賞

    2025

  3. 日産化学・有機合成新反応／手法賞

    有機合成化学協会　2022

  4. Nagase Foundation Award 2019

    Ryo Shintani　2019/04

  5. The Young Scientists’ Prize by MEXT

    Ryo Shintani　2015/04

  6. Thieme Chemistry Journal Award 2013

    Ryo Shintani　2013

  7. Merck-Banyu Lectureship Award 2011

    Ryo Shintani　2012

  8. Chemical Society of Japan Award for Young Chemists

    Ryo Shintani　2012

  9. Banyu Chemist Award 2011

    Ryo Shintani　2011

Papers 132

  1. Multiple Near‐Infrared Chromisms of a Heteromerous Overcrowded Ethylene with Large Permanent Dipole Moment

    Akihiro Shimizu, Yuki Misaki, Chihiro Kondo, Ayane Kayama, Takashi Hirose, Hiroyasu Sato, Ryo Shintani

    Angewandte Chemie International Edition　2025/03/24　Research paper (scientific journal)

  2. Theoretical Investigation on the Copper‐Catalyzed anti‐Selective 1,2‐Silylboration of Internal Alkynes

    Hirokazu Moniwa, Masahiro Yamanaka, Ryo Shintani

    European Journal of Organic Chemistry　Vol. 28　No. 10　2025/02/27　Research paper (scientific journal)

    Publisher: Wiley

  3. Nucleophilic Substitution at Unactivated Arene C–H: Copper-Catalyzed anti-Selective Silylative Cyclization of Substituted Benzylacetylenes

    Hirokazu Moniwa, Ryo Shintani

    Organic Letters　Vol. 27　No. 7　p. 1763-1768　2025/02/13　Research paper (scientific journal)

    Publisher: American Chemical Society (ACS)

  4. Nickel-Catalyzed Synthesis of Silaindanes via Sequential C–H Activating 1,5-Nickel Migration and C–Si Activating 1,4-Nickel Migration

    Donghyeon Lee, Ikuya Fujii, Ryo Shintani

    ACS Catalysis　Vol. 15　No. 2　p. 907-916　2024/12/30　Research paper (scientific journal)

    Publisher: American Chemical Society (ACS)

  5. Radical Stitching Polymerization and Its Alternating Copolymerization.

    Yusuke Hamada, Soya Togawa, Ryo Shintani

    Journal of the American Chemical Society　Vol. 146　No. 28　p. 19310-19316　2024/07/17　Research paper (scientific journal)

  6. Photoredox-Enabled Dearomative [2π + 2σ] Cycloaddition of Phenols.

    Subhabrata Dutta, Donghyeon Lee, Kristers Ozols, Constantin G Daniliuc, Ryo Shintani, Frank Glorius

    Journal of the American Chemical Society　Vol. 146　No. 4　p. 2789-2797　2024/01/31　Research paper (scientific journal)

  7. Insertion of methylene groups into functional molecules for high thermal stability and superior functionality of single-molecule transistors: a first-principles study

    Miku Furushima, Mitsuharu Uemoto, Dongbao Yin, Seiichiro Izawa, Ryo Shintani, Yutaka Majima, Tomoya Ono

    New Journal of Chemistry　2024　Research paper (scientific journal)

    Publisher: Royal Society of Chemistry (RSC)

  8. Negative Differential Resistance in Single-Molecule Junctions Based on Heteroepitaxial Spherical Au/Pt Nanogap Electrodes

    Dongbao Yin, Miku Furushima, Eiji Tsuchihata, Seiichiro Izawa, Tomoya Ono, Ryo Shintani, Yutaka Majima

    Advanced Electronic Materials　2024　Research paper (scientific journal)

  9. Synthesis of (1-silyl)allylboronates by KOtBu-catalyzed ring-opening gem-silylborylation of cyclopropenes

    Ikuya Fujii, Haruka Hirata, Hirokazu Moniwa, Ryo Shintani

    Chemical Communications　Vol. 60　No. 54　p. 6921-6924　2024　Research paper (scientific journal)

    Publisher: Royal Society of Chemistry (RSC)

  10. Palladium-Catalyzed Skeletal Rearrangement of Substituted 2-Silylaryl Triflates via 1,5-C-Pd/C-Si Bond Exchange.

    Daigo Hayashi, Tomohiro Tsuda, Ryo Shintani

    Angewandte Chemie (International ed. in English)　Vol. 62　No. 50　2023/12/11　Research paper (scientific journal)

  11. Copper-Catalyzed Regio- and Stereoselective Formal Hydro(borylmethylsilyl)ation of Internal Alkynes via Alkenyl-to-Alkyl 1,4-Copper Migration.

    Hirokazu Moniwa, Masahiro Yamanaka, Ryo Shintani

    Journal of the American Chemical Society　Vol. 145　No. 43　p. 23470-23477　2023/11/01　Research paper (scientific journal)

  12. Zwitterionic Open‐Shell Singlet Diradical with Solvent‐Dependent Singlet–Triplet Energy Gap

    Akihiro Shimizu, Masaaki Hayashida, Yuta Ochi, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Ryo Shintani

    Asian Journal of Organic Chemistry　2023/06/06　Research paper (scientific journal)

    Publisher: Wiley

  13. Copper-Catalyzed Synthesis of 3-Silyl-1-silacyclopent-2-enes via Regio- and anti-Selective Addition of Silylboronates to Silicon-Containing Internal Alkynes

    Ryosuke Kondo, Hirokazu Moniwa, Ryo Shintani

    Organic Letters　Vol. 25　No. 22　p. 4193-4197　2023/05/25　Research paper (scientific journal)

    Publisher: American Chemical Society (ACS)

  14. A Kinetically Stabilized Nitrogen‐Doped Triangulene Cation: Stable and NIR Fluorescent Diradical Cation with Triplet Ground State

    Shinobu Arikawa, Akihiro Shimizu, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Hikaru Sotome, Hiroshi Miyasaka, Masahito Murai, Shigehiro Yamaguchi, Ryo Shintani

    Angewandte Chemie International Edition　Vol. 62　No. 29　2023/05/22　Research paper (scientific journal)

    Publisher: Wiley

  15. Palladium-catalyzed synthesis of benzosilacyclobutenes via position-selective C(sp3)–H arylation

    Naoya Hamada, Daigo Hayashi, Ryo Shintani

    Chemical Communications　Vol. 59　No. 59　p. 9122-9125　2023　Research paper (scientific journal)

    Publisher: Royal Society of Chemistry (RSC)

  16. Palladium-catalyzed synthesis of 4-sila-4H-benzo[d][1,3]oxazines by intramolecular Hiyama coupling

    Donghyeon Lee, Ryo Shintani

    Chemical Science　Vol. 14　No. 15　p. 4114-4119　2023　Research paper (scientific journal)

    Publisher: Royal Society of Chemistry (RSC)

  17. Synthesis of Poly(arylenevinylene)s by Rhodium-Catalyzed Stitching Polymerization/Alkene Isomerization

    Soya Togawa, Ryo Shintani

    Journal of the American Chemical Society　Vol. 144　No. 40　p. 18545-18551　2022/09/22　Research paper (scientific journal)

    Publisher: American Chemical Society (ACS)

  18. Rhodium-catalyzed synthesis of 1-silabenzonorbornenes via 1,4-rhodium migration

    Ryo Shintani, Daichi Hama, Naoya Hamada, Takuya Miwa

    Tetrahedron Letters　Vol. 104　p. 154031-154031　2022/08　Research paper (scientific journal)

    Publisher: Elsevier BV

  19. Synthesis and Isolation of a Kekulé Hydrocarbon with a Triplet Ground State

    Akihiro Shimizu, Tetsuya Morikoshi, Kenji Sugisaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Ryo Shintani

    Angewandte Chemie International Edition　2022/05/31　Research paper (scientific journal)

    Publisher: Wiley

  20. Anionic stitching polymerization of styryl(vinyl)silanes for the synthesis of sila-cyclic olefin polymers

    Sho Ikeda, Ryo Shintani

    Chemical Communications　Vol. 58　No. 34　p. 5281-5284　2022　Research paper (scientific journal)

    Publisher: Royal Society of Chemistry (RSC)

  21. Synthesis and Isolation of a Kinetically Stabilized Crystalline Triangulene

    Shinobu Arikawa, Akihiro Shimizu, Daisuke Shiomi, Kazunobu Sato, Ryo Shintani

    Journal of the American Chemical Society　2021/11/24　Research paper (scientific journal)

    Publisher: American Chemical Society ({ACS})

  22. Rhodium-Catalyzed Stitching Polymerization of Alkynylsilylacetylenes

    Sho Ikeda, Yuki Hanamura, Hirokazu Tada, Ryo Shintani

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 143　No. 46　p. 19559-19566　2021/11　Research paper (scientific journal)

  23. Facile and Convergent Synthesis of Highly Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction

    Naoya Hamada, Tomohiro Tsuda, Ryo Shintani

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY　Vol. 2021　No. 34　p. 4824-4827　2021/09　Research paper (scientific journal)

  24. Anthracene-Based Zwitterion with a Small HOMO-LUMO Energy Gap

    Ayane Kayama, Akihiro Shimizu, Ryo Shintani

    SYNTHESIS-STUTTGART　2021/07　Research paper (scientific journal)

  25. Copper-Catalyzed Synthesis of Tetrasubstituted Alkenes via Regio- and anti-Selective Addition of Silylboronates to Internal Alkynes

    Hirokazu Moniwa, Ryo Shintani

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 27　No. 27　p. 7512-7515　2021/05　Research paper (scientific journal)

  26. Palladium-Catalyzed Synthesis of Dibenzosilepin Derivatives via 1,n-Palladium Migration Coupled with anti-Carbopalladation of Alkyne

    Tomohiro Tsuda, Seung-Min Choi, Ryo Shintani

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 143　No. 3　p. 1641-1650　2021/01　Research paper (scientific journal)

  27. Phosphinative cyclopropanation of allyl phosphates with lithium phosphides

    Ryo Shintani, Ayase Ohzono, Kentaro Shirota

    CHEMICAL COMMUNICATIONS　Vol. 56　No. 79　p. 11851-11854　2020/10　Research paper (scientific journal)

  28. Intermolecular Three-Component Synthesis of Fluorene Derivatives by a Rhodium-Catalyzed Stitching Reaction/Remote Nucleophilic Substitution Sequence.

    Masaki Nishida, Donghyeon Lee, Ryo Shintani

    The Journal of organic chemistry　Vol. 85　No. 13　p. 8489-8500　2020/07/02　Research paper (scientific journal)

  29. Palladium-Catalyzed Synthesis of Benzophenanthrosilines by C-H/C-H Coupling through 1,4-Palladium Migration/Alkene Stereoisomerization.

    Tomohiro Tsuda, Yuka Kawakami, Seung-Min Choi, Ryo Shintani

    Angewandte Chemie (International ed. in English)　Vol. 59　No. 21　p. 8057-8061　2020/05/18　Research paper (scientific journal)

  30. Synthesis of 7H-Benzo[e]naphtho[1,8-bc]silines by Rhodium-catalyzed [2 + 2 + 2] Cycloaddition

    Takumi Maesato, Ryo Shintani

    Chemistry Letters　Vol. 49　No. 4　p. 344-346　2020/04/05　Research paper (scientific journal)

    Publisher: The Chemical Society of Japan

  31. Convergent Synthesis of Fluorene Derivatives by a Rhodium-Catalyzed Stitching Reaction/Alkene Isomerization Sequence.

    Nishida M, Shintani R

    Chemistry (Weinheim an der Bergstrasse, Germany)　Vol. 25　No. 31　p. 7475-7479　2019/06

  32. Azoniadibenzo[a,j]phenalenide: A Polycyclic Zwitterion with Singlet Biradical Character.

    Arikawa S, Shimizu A, Shintani R

    Angewandte Chemie (International ed. in English)　Vol. 58　No. 19　p. 6415-6419　2019/05

  33. Rhodium-Catalyzed Stitching Polymerization of 1,5-Hexadiynes and Related Oligoalkynes.

    Ikeda S, Shintani R

    Angewandte Chemie (International ed. in English)　Vol. 58　No. 17　p. 5734-5738　2019/04

  34. Rhodium-Catalyzed Synthesis of Silicon-Bridged 1,2-Dialkenylbenzenes via 1,4-Rhodium Migration.

    Miwa T, Shintani R

    Organic letters　Vol. 21　No. 6　p. 1627-1631　2019/03

  35. Single-molecule single-electron transistor (SM-SET) based on π-conjugated quinoidal-fused oligosilole and heteroepitaxial spherical Au/Pt nanogap electrodes

    Seung Joo Lee, Jaeyeon Kim, Tomohiro Tsuda, Ryo Takano, Ryo Shintani, Kyoko Nozaki, Yutaka Majima

    Applied Physics Express　Vol. 12　No. 12　2019　Research paper (scientific journal)

  36. Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

    Ryo Shintani, Shinnosuke Kishikawa, Kimihiro Nakamura, Tomohiro Tsuda, Kyoko Nozaki

    Chemical Communications　Vol. 55　No. 8　p. 1072-1075　2019　Research paper (scientific journal)

  37. Palladium-Catalyzed Intramolecular C−H Arylation versus 1,5-Palladium Migration: A Theoretical Investigation

    Nana Misawa, Tomohiro Tsuda, Ryo Shintani, Koichi Yamashita, Kyoko Nozaki

    Chemistry - An Asian Journal　Vol. 13　No. 17　p. 2566-2572　2018/09/04　Research paper (scientific journal)

  38. Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds

    Ryo Shintani

    Synlett　Vol. 29　No. 4　p. 388-396　2018/03/01　Research paper (scientific journal)

    Publisher: Georg Thieme Verlag

  39. Structures and Physical Properties of Chemically Reduced Diindenosiloles and Their pi-Extended Derivatives

    Ryo Takano, Ryo Shintani, Aiko Fukazawa, Shigehiro Yamaguchi, Koji Nakabayashi, Shin-ichi Ohkoshi, Kyoko Nozaki

    ORGANOMETALLICS　Vol. 36　No. 14　p. 2646-2653　2017/07　Research paper (scientific journal)

  40. Synthesis of Quinoidal Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction and Theoretical Investigation of Their Properties

    Ryo Shintani, Nana Misawa, Tomohiro Tsuda, Ryo Iino, Mikiya Fujii, Koichi Yamashita, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 139　No. 10　p. 3861-3867　2017/03　Research paper (scientific journal)

  41. Rhodium-Catalyzed Synthesis and Optical Properties of Silicon-Bridged Arylpyridines

    Ryo Shintani, Nana Misawa, Ryo Takano, Kyoko Nozaki

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 23　No. 11　p. 2660-2665　2017/02　Research paper (scientific journal)

  42. Selective synthesis of unsymmetric dibenzo[a,e]pentalenes by a rhodium-catalysed stitching reaction

    Keisuke Takahashi, Shingo Ito, Ryo Shintani, Kyoko Nozaki

    CHEMICAL SCIENCE　Vol. 8　No. 1　p. 101-107　2017/01　Research paper (scientific journal)

  43. Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration

    Yosuke Sato, Chihiro Takagi, Ryo Shintani, Kyoko Nozaki

    Angewandte Chemie - International Edition　Vol. 56　No. 31　p. 9211-9216　2017　Research paper (scientific journal)

  44. Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis

    Ryo Shintani, Hiroki Kurata, Kyoko Nozaki

    Journal of Organic Chemistry　Vol. 81　No. 8　p. 3065-3069　2016/04　Research paper (scientific journal)

  45. Rhodium-Catalyzed Stitching Reaction: Convergent Synthesis of Quinoidal Fused Oligosiloles

    Ryo Shintani, Ryo Iino, Kyoko Nozaki

    Journal of the American Chemical Society　Vol. 138　No. 11　p. 3635-3638　2016/03/23　Research paper (scientific journal)

  46. Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

    Ryo Shintani, Ryo Takano, Kyoko Nozaki

    Chemical Science　Vol. 7　No. 2　p. 1205-1211　2016　Research paper (scientific journal)

  47. Corrigendum: Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition.

    Shintani R, Takagi C, Ito T, Naito M, Nozaki K

    Angewandte Chemie (International ed. in English)　Vol. 54　No. 34　p. 9743-9743　2015/08

  48. Rhodium-catalyzed intramolecular alkynylsilylation of alkynes

    Ryo Shintani, Hiroki Kurata, Kyoko Nozaki

    Chemical Communications　Vol. 51　No. 57　p. 11378-11381　2015/07/21　Research paper (scientific journal)

  49. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

    Ryo Shintani, Chihiro Takagi, Tomoaki Ito, Masanobu Naito, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 54　No. 5　p. 1616-1620　2015/01　Research paper (scientific journal)

  50. Silylative Cyclopropanation of Allyl Phosphates with Silylboronates

    Ryo Shintani, Ryuhei Fujie, Momotaro Takeda, Kyoko Nozaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 53　No. 25　p. 6546-6549　2014/06　Research paper (scientific journal)

  51. Rhodium-Catalyzed Polymerization of 3,3-Diarylcyclopropenes Involving a 1,4-Rhodium Migration

    Ryo Shintani, Ryo Iino, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 136　No. 22　p. 7849-7852　2014/06　Research paper (scientific journal)

  52. Synthesis of Quaternary Carbon Stereocenters by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Arylboronates

    Momotaro Takeda, Keishi Takatsu, Ryo Shintani, Tamio Hayashi

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 79　No. 6　p. 2354-2367　2014/03　Research paper (scientific journal)

  53. Enantioselective synthesis of α-tri- and α-tetrasubstituted allylsilanes by copper-catalyzed asymmetric allylic substitution of allyl phosphates with silylboronates

    Momotaro Takeda, Ryo Shintani, Tamio Hayashi

    Journal of Organic Chemistry　Vol. 78　No. 10　p. 5007-5017　2013/05/17　Research paper (scientific journal)

    Publisher: 10

  54. Asymmetric hydrosilylation of cyclohexa-1,3-diene with trichlorosilane by palladium catalysts coordinated with chiral phosphoramidite ligands

    Hoon Seo Park, Jin Wook Han, Ryo Shintani, Tamio Hayashi

    TETRAHEDRON-ASYMMETRY　Vol. 24　No. 7　p. 418-420　2013/04　Research paper (scientific journal)

  55. Copper-catalyzed hydroboration of carbon dioxide

    Ryo Shintani, Kyoko Nozaki

    Organometallics　Vol. 32　No. 8　p. 2459-2462　2013/04　Research paper (scientific journal)

  56. Efficient catalyst removal and recycling in copolymerization of epoxides with carbon dioxide via simple liquid-liquid phase separation

    Koji Nakano, Ryuhei Fujie, Ryo Shintani, Kyoko Nozaki

    CHEMICAL COMMUNICATIONS　Vol. 49　No. 81　p. 9332-9334　2013　Research paper (scientific journal)

  57. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

    Ryo Shintani, Eleanor E. Maciver, Fumiko Tamakuni, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 134　No. 41　p. 16955-16958　2012/10　Research paper (scientific journal)

  58. Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

    Ryo Shintani, Kohei Moriya, Tamio Hayashi

    ORGANIC LETTERS　Vol. 14　No. 11　p. 2902-2905　2012/06　Research paper (scientific journal)

  59. Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C-H Bond Functionalization

    Ryo Shintani, Haruka Otomo, Kensuke Ota, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 134　No. 17　p. 7305-7308　2012/05　Research paper (scientific journal)

  60. Palladium-Catalyzed Synthesis of 4-Oxaspiro[2.4]heptanes via Central Attack of Oxygen Nucleophiles to pi-Allylpalladium Intermediates

    Ryo Shintani, Tomoaki Ito, Tamio Hayashi

    ORGANIC LETTERS　Vol. 14　No. 9　p. 2410-2413　2012/05　Research paper (scientific journal)

  61. (S)-Phenylalanine-derived chiral phosphorus-olefin ligands in rhodium-catalyzed asymmetric 1,4-addition reactions

    Rintaro Narui, Sayuri Hayashi, Haruka Otomo, Ryo Shintani, Tamio Hayashi

    TETRAHEDRON-ASYMMETRY　Vol. 23　No. 3-4　p. 284-293　2012/02　Research paper (scientific journal)

  62. Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis

    Keigo Sasaki, Takahiro Nishimura, Ryo Shintani, Eric Assen B. Kantchev, Tamio Hayashi

    CHEMICAL SCIENCE　Vol. 3　No. 4　p. 1278-1283　2012　Research paper (scientific journal)

  63. The Origins of Enantioselectivity in Rh-Diene Complex Catalysed Arylation of Cyclohex-2-enones

    Silvia Gosiewska, Jevgenij A. Raskatov, Ryo Shintani, Tamio Hayashi, John M. Brown

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 18　No. 1　p. 80-84　2012/01　Research paper (scientific journal)

  64. Palladium-catalyzed asymmetric synthesis of 2-pyrrolidinones with a quaternary carbon stereocenter

    Ryo Shintani, Tomoaki Ito, Midori Nagamoto, Haruka Otomo, Tamio Hayashi

    CHEMICAL COMMUNICATIONS　Vol. 48　No. 79　p. 9936-9938　2012　Research paper (scientific journal)

  65. Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

    Ryo Shintani, Kohei Moriya, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 133　No. 41　p. 16440-16443　2011/10　Research paper (scientific journal)

  66. Synthesis of Nine-Membered Azlactones by Palladium-Catalyzed Ring-Expansion of gamma-Methylidene-delta-valerolactones with Aziridines

    Ryo Shintani, Keiichi Ikehata, Tamio Hayashi

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 11　p. 4776-4780　2011/06　Research paper (scientific journal)

  67. Rhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates to N-Sulfonyl Ketimines

    Ryo Shintani, Momotaro Takeda, Ying-Teck Soh, Tomoaki Ito, Tamio Hayashi

    ORGANIC LETTERS　Vol. 13　No. 12　p. 2977-2979　2011/06　Research paper (scientific journal)

  68. Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to beta,beta-Disubstituted alpha,beta-Unsaturated Esters

    Ryo Shintani, Tamio Hayashi

    ORGANIC LETTERS　Vol. 13　No. 2　p. 350-352　2011/01　Research paper (scientific journal)

  69. Guiding the nitrogen nucleophile to the middle: palladium-catalyzed decarboxylative cyclopropanation of 2-alkylidenetrimethylene carbonates with isocyanates

    Ryo Shintani, Kohei Moriya, Tamio Hayashi

    CHEMICAL COMMUNICATIONS　Vol. 47　No. 11　p. 3057-3059　2011　Research paper (scientific journal)

  70. Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines

    Ryo Shintani, Rintaro Narui, Yosuke Tsutsumi, Sayuri Hayashi, Tamio Hayashi

    CHEMICAL COMMUNICATIONS　Vol. 47　No. 21　p. 6123-6125　2011　Research paper (scientific journal)

  71. Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

    Keishi Takatsu, Ryo Shintani, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 50　No. 24　p. 5548-5552　2011　Research paper (scientific journal)

  72. Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

    Ryo Shintani, Keishi Takatsu, Momotaro Takeda, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 50　No. 37　p. 8656-8659　2011　Research paper (scientific journal)

  73. Rhodium-Catalyzed Asymmetric Arylation of Azomethine Imines

    Ryo Shintani, Ying-Teck Soh, Tamio Hayashi

    ORGANIC LETTERS　Vol. 12　No. 18　p. 4106-4109　2010/09　Research paper (scientific journal)

  74. Rhodium-Catalyzed Asymmetric Arylation of N-Tosyl Ketimines

    Ryo Shintani, Momotaro Takeda, Takaoki Tsuji, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 132　No. 38　p. 13168-13169　2010/09　Research paper (scientific journal)

  75. Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cyclization of gamma-Methylidene- delta-valerolactones with lsocyanates: Kinetic Studies and Origin of the Site Selectivity in the Nucleophilic Attack at a (pi-Allyl)palladium

    Ryo Shintani, Takaoki Tsuji, Soyoung Park, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 132　No. 21　p. 7508-7513　2010/06　Research paper (scientific journal)

  76. Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to beta-Phthaliminoacrylate Esters toward the Synthesis of beta-Amino Acids

    Takahiro Nishimura, Jun Wang, Makoto Nagaosa, Kazuhiro Okamoto, Ryo Shintani, Fuk-yee Kwong, Wing-yiu Yu, Albert S. C. Chan, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 132　No. 2　p. 464-+　2010/01　Research paper (scientific journal)

  77. Palladium-catalyzed intramolecular decarboxylative allylic arylation of alpha-aryl-gamma-methylidene-delta-valerolactones

    Ryo Shintani, Takaoki Tsuji, Soyoung Park, Tamio Hayashi

    CHEMICAL COMMUNICATIONS　Vol. 46　No. 10　p. 1697-1699　2010　Research paper (scientific journal)

  78. Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to beta,beta-Disubstituted alpha,beta-Unsaturated Ketones

    Ryo Shintani, Momotaro Takeda, Takahiro Nishimura, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 49　No. 23　p. 3969-3971　2010　Research paper (scientific journal)

  79. Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes

    Ryo Shintani, Shingo Isobe, Momotaro Takeda, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 49　No. 22　p. 3795-3798　2010　Research paper (scientific journal)

  80. Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

    Ryo Shintani, Keishi Takatsu, Tamio Hayashi

    CHEMICAL COMMUNICATIONS　Vol. 46　No. 36　p. 6822-6824　2010　Research paper (scientific journal)

  81. Palladium-Catalyzed Decarboxylative [4+3] Cyclization of gamma-Methylidene-delta-valerolactones with 1,1-Dicyanocyclopropanes

    Ryo Shintani, Masataka Murakami, Takaoki Tsuji, Hideyuki Tanno, Tamio Hayashi

    ORGANIC LETTERS　Vol. 11　No. 24　p. 5642-5645　2009/12　Research paper (scientific journal)

  82. Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to beta,beta-Disubstituted alpha,beta-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters

    Ryo Shintani, Yosuke Tsutsumi, Makoto Nagaosa, Takahiro Nishimura, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 131　No. 38　p. 13588-+　2009/09　Research paper (scientific journal)

  83. Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of gamma-Methylidene-delta-valerolactones with Isatins

    Ryo Shintani, Shin-ya Hayashi, Masataka Murakami, Momotaro Takeda, Tamio Hayashi

    ORGANIC LETTERS　Vol. 11　No. 16　p. 3754-3756　2009/08　Research paper (scientific journal)

  84. Chiral Diene Ligands for Asymmetric Catalysis

    Ryo Shintani, Tamio Hayashi

    ALDRICHIMICA ACTA　Vol. 42　No. 2　p. 31-38　2009　Research paper (scientific journal)

  85. Tuning the Chiral Environment of C-2-Symmetric Diene Ligands: Development of 3,7-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes

    Ryo Shintani, Yoshitaka Ichikawa, Keishi Takatsu, Fu-Xue Chen, Tamio Hayashi

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 2　p. 869-873　2009/01　Research paper (scientific journal)

  86. Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium-Catalyzed Decarboxylative Cyclization of gamma-Methylidene-delta-valerolactones with Imines

    Ryo Shintani, Masataka Murakami, Tamio Hayashi

    ORGANIC LETTERS　Vol. 11　No. 2　p. 457-459　2009/01　Research paper (scientific journal)

  87. Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Alkyne-Vinylcyclopropanes

    Ryo Shintani, Hiroki Nakatsu, Keishi Takatsu, Tamio Hayashi

    CHEMISTRY-A EUROPEAN JOURNAL　Vol. 15　No. 35　p. 8692-8694　2009　Research paper (scientific journal)

  88. Palladium-Catalyzed Asymmetric Decarboxylative Lactamization of gamma-Methylidene-delta-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams

    Ryo Shintani, Soyoung Park, Fumitaka Shirozu, Masataka Murakami, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 130　No. 48　p. 16174-+　2008/12　Research paper (scientific journal)

  89. Ruthenium-catalyzed 1,4-addition of organoboronic acids to alpha,beta-unsaturated ketones

    Ryo Shintani, Tamio Hayashi

    CHEMISTRY LETTERS　Vol. 37　No. 7　p. 724-725　2008/07　Research paper (scientific journal)

  90. gamma-Methylidene-delta-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones

    Ryo Shintani, Masataka Murakami, Tamio Hayashi

    PURE AND APPLIED CHEMISTRY　Vol. 80　No. 5　p. 1135-1140　2008/05　Research paper (scientific journal)

  91. Rhodium-catalyzed addition of organo[2-(hydroxymethyl)phenyl]dimethylsilanes to arenesulfonylimines

    Yoshiaki Nakao, Masahide Takeda, Jinshui Chen, Tamejiro Hiyama, Yoshitaka Ichikawa, Ryo Shintani, Tamio Hayashi

    CHEMISTRY LETTERS　Vol. 37　No. 3　p. 290-291　2008/03　Research paper (scientific journal)

  92. Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage

    Ryo Shintani, Keishi Takatsu, Tamio Hayashi

    ORGANIC LETTERS　Vol. 10　No. 6　p. 1191-1193　2008/03　Research paper (scientific journal)

  93. Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones

    Ryo Shintani, Keishi Takatsu, Taisuke Katoh, Takahiro Nishimura, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 47　No. 8　p. 1447-1449　2008　Research paper (scientific journal)

  94. Palladium-catalyzed synthesis of spiro[2.4]heptanes: Ligand-dependent position control in the nucleophilic attack to a pi-allyipalladium intermediate

    Ryo Shintani, Soyoung Park, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 48　p. 14866-+　2007/12　Research paper (scientific journal)

  95. Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: Synthetic equivalent to asymmetric conjugate alkynylation of enones

    Takahiro Nishimura, Taisuke Katoh, Keishi Takatsu, Ryo Shintani, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 46　p. 14158-+　2007/11　Research paper (scientific journal)

  96. gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones

    Ryo Shintani, Masataka Murakami, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 41　p. 12356-+　2007/10　Research paper (scientific journal)

  97. Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes

    Ryo Shintani, Yoshitaka Ichikawa, Tamio Hayashi, Jinshui Chen, Yoshiaki Nakao, Tamejiro Hiyama

    ORGANIC LETTERS　Vol. 9　No. 22　p. 4643-4645　2007/10　Research paper (scientific journal)

  98. Asymmetric construction of chiral C-N axes through rhodium-catalyzed 1,4-addition

    Wei-Liang Duan, Yusuke Imazaki, Ryo Shintani, Tamio Hayashi

    TETRAHEDRON　Vol. 63　No. 35　p. 8529-8536　2007/08　Research paper (scientific journal)

  99. Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as mild and reproducible agents for rhodium-catalyzed 1,4-addition reactions

    Yoshiaki Nakao, Jinshui Chen, Hidekazu Imanaka, Tamejiro Hiyama, Yoshitaka Ichikawa, Wei-Liang Duan, Ryo Shintani, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 29　p. 9137-9143　2007/07

  100. Iron-catalyzed arylmagnesiation of aryl(alkyl)acetylenes in the presence of an N-heterocyclic carbene ligand

    Takafumi Yamagami, Ryo Shintani, Eiji Shirakawa, Tamio Hayashi

    ORGANIC LETTERS　Vol. 9　No. 6　p. 1045-1048　2007/03　Research paper (scientific journal)

  101. Chiral phosphine-olefin ligands in the rhodium-catalyzed asymmetric 1,4-addition reactions

    Wei-Liang Duan, Hiroshi Iwamura, Ryo Shintani, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 7　p. 2130-2138　2007/02　Research paper (scientific journal)

  102. Rhodium-catalyzed asymmetric synthesis of 3,3-disubstituted 1-indanones

    Ryo Shintani, Keishi Takatsu, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 46　No. 20　p. 3735-3737　2007　Research paper (scientific journal)

  103. Palladium-catalyzed asymmetric [3+3] cycloaddition of trimethylenemethane derivatives with nitrones

    Ryo Shintani, Soyoung Park, Wei-Liang Duan, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 46　No. 31　p. 5901-5903　2007　Research paper (scientific journal)

  104. A cationic rhodium-chiral diene complex as a high-performance catalyst for the intramolecular asymmetric [4+2] cycloaddition of alkyne-1,3-dienes

    Ryo Shintani, Yuta Sannohe, Takaoki Tsuji, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 46　No. 38　p. 7277-7280　2007　Research paper (scientific journal)

  105. Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones

    Ryo Shintani, Tamio Hayashi

    NATURE PROTOCOLS　Vol. 2　No. 11　p. 2903-2909　2007　Research paper (scientific journal)

  106. Rhodium-catalyzed multicomponent-coupling reactions involving a carborhodation-cross-coupling sequence

    Ryo Shintani, Takafumi Yamagami, Tamio Hayashi

    ORGANIC LETTERS　Vol. 8　No. 21　p. 4799-4801　2006/10　Research paper (scientific journal)

  107. Ligand Design for C-C Bond Formation

    Ryo Shintani, Tamio Hayashi

    New Frontiers in Asymmetric Catalysis　p. 59-100　2006/06/14　Part of collection (book)

    Publisher: John Wiley & Sons, Inc.

  108. Rhodium-catalyzed asymmetric construction of quaternary carbon stereocenters: Ligand-dependent regiocontrol in the 1,4-addition to substituted maleimides

    R Shintani, WL Duan, T Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 128　No. 17　p. 5628-5629　2006/05　Research paper (scientific journal)

  109. Palladium-catalyzed [3+3] cycloaddition of trimethylenemethane with azomethine imines

    Ryo Shintani, Tamio Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 128　No. 19　p. 6330-6331　2006/05　Research paper (scientific journal)

  110. Rhodium-catalyzed asymmetric synthesis of indanones: Development of a new "axially chiral" bisphosphine ligand

    R Shintani, K Yashio, T Nakamura, K Okamoto, T Shimada, T Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 128　No. 9　p. 2772-2773　2006/03　Research paper (scientific journal)

  111. Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins

    Ryo Shintani, Mitsunori Inoue, Tamio Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 45　No. 20　p. 3353-3356　2006　Research paper (scientific journal)

  112. Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes

    Ryo Shintani, Wei-Liang Duan, Soyoung Park, Tamio Hayashi

    CHEMICAL COMMUNICATIONS　No. 34　p. 3646-3647　2006　Research paper (scientific journal)

  113. Asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones by rhodium-catalyzed 1,4-addition of arylzinc reagents in the presence of chlorotrimethylsilane

    R Shintani, T Yamagami, T Kimura, T Hayashi

    ORGANIC LETTERS　Vol. 7　No. 23　p. 5317-5319　2005/11　Research paper (scientific journal)

  114. Carbon-carbon bond-forming enantioselective synthesis of chiral organosilicon compounds by rhodium/chiral diene-catalyzed asymmetric 1,4-addition reaction

    R Shintani, K Okamoto, T Hayashi

    ORGANIC LETTERS　Vol. 7　No. 21　p. 4757-4759　2005/10　Research paper (scientific journal)

  115. Asymmetric Synthesis

    Ryo Shintani, Tamio Hayashi

    Modern Organonickel Chemistry　p. 240-272　2005/08/19　Part of collection (book)

    Publisher: John Wiley and Sons

  116. Rhodium-catalyzed addition of arylzinc reagents to aryl alkynyl ketones: Synthesis of beta,beta-disubstituted indanones

    R Shintani, T Hayashi

    ORGANIC LETTERS　Vol. 7　No. 10　p. 2071-2073　2005/05　Research paper (scientific journal)

  117. Preparation of C-2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids

    Y Otomaru, K Okamoto, R Shintani, T Hayashi

    JOURNAL OF ORGANIC CHEMISTRY　Vol. 70　No. 7　p. 2503-2508　2005/04　Research paper (scientific journal)

  118. Rhodium-catalyzed isomerization of alpha-arylpropargyl alcohols to indanones: Involvement of an unexpected reaction cascade

    R Shintani, K Okamoto, T Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 127　No. 9　p. 2872-2873　2005/03　Research paper (scientific journal)

  119. Catalytic asymmetric arylative cyclization of alkynals: Phosphine-free rhodium/diene complexes as efficient catalysts

    R Shintani, K Okamoto, Y Otomaru, K Ueyama, T Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 127　No. 1　p. 54-55　2005/01　Research paper (scientific journal)

  120. C-2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines

    Y Otomaru, N Tokunaga, R Shintani, T Hayashi

    ORGANIC LETTERS　Vol. 7　No. 2　p. 307-310　2005/01　Research paper (scientific journal)

  121. Highly chemo- and enantioselective arylative cyclization of alkyne-tethered electron-deficient olefins catalyzed by rhodium complexes with chiral dienes

    R Shintani, A Tsurusaki, K Okamoto, T Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 44　No. 25　p. 3909-3912　2005　Research paper (scientific journal)

  122. Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides

    R Shintani, T Kimura, T Hayashi

    CHEMICAL COMMUNICATIONS　No. 25　p. 3213-3214　2005　Research paper (scientific journal)

  123. Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: Rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides

    R Shintani, WL Duan, T Nagano, A Okada, T Hayashi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 44　No. 29　p. 4611-4614　2005　Research paper (scientific journal)

  124. C-2-symmetric bicyclo[2.2.2]octadienes as chiral ligands: Their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines

    N Tokunaga, Y Otomaru, K Okamoto, K Ueyama, R Shintani, T Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 126　No. 42　p. 13584-13585　2004/10　Research paper (scientific journal)

  125. Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds

    R Shintani, K Ueyama, Yamada, I, T Hayashi

    ORGANIC LETTERS　Vol. 6　No. 19　p. 3425-3427　2004/09　Research paper (scientific journal)

  126. A new entry of nucleophiles in rhodium-catalyzed asymmetric 1,4-addition reactions: Addition of organozinc reagents for the synthesis of 2-aryl-4-piperidones

    R Shintani, N Tokunaga, H Doi, T Hayashi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 126　No. 20　p. 6240-6241　2004/05　Research paper (scientific journal)

  127. A new copper-catalyzed [3+2] cycloaddition: Enantioselective coupling of terminal alkynes with azomethine imines to generate five-membered nitrogen heterocycles

    R Shintani, GC Fu

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 125　No. 36　p. 10778-10779　2003/09　Research paper (scientific journal)

  128. Catalytic enantioselective synthesis of beta-lactams: Intramolecular Kinugasa reactions and interception of an intermediate in the reaction cascade

    R Shintani, GC Fu

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 42　No. 34　p. 4082-4085　2003　Research paper (scientific journal)

  129. Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones in the presence of planar-chiral phosphaferrocene-oxazoline ligands

    R Shintani, GC Fu

    ORGANIC LETTERS　Vol. 4　No. 21　p. 3699-3702　2002/10　Research paper (scientific journal)

  130. Highly enantioselective desymmetrization of anhydrides by carbon nucleophiles: Reactions of grignard reagents in the presence of (-)-sparteine

    R Shintani, GC Fu

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 41　No. 6　p. 1057-+　2002　Research paper (scientific journal)

  131. Synthesis and application of planar-chiral phosphaferrocene-oxazolines, a new class of P,N-ligands

    R Shintani, MMC Lo, GC Fu

    ORGANIC LETTERS　Vol. 2　No. 23　p. 3695-3697　2000/11　Research paper (scientific journal)

  132. Asymmetric conjugate reduction of alpha,beta-unsaturated esters using a chiral phosphine-copper catalyst

    DH Appella, Y Moritani, R Shintani, EM Ferreira, SL Buchwald

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 121　No. 40　p. 9473-9474　1999/10　Research paper (scientific journal)

Misc. 73

  1. キノイド型縮環オリゴシロールの化学還元およびその構造と物性

    高野遼, 新谷亮, 深澤愛子, 山口茂弘, 山口茂弘, 中林耕二, 大越慎一, 野崎京子

    日本化学会春季年会講演予稿集(CD-ROM)　Vol. 97th　2017/03/03

  2. Recent Progress in Copper-Catalyzed Asymmetric Allylic Substitution Reactions Using Organoboron Nucleophiles

    Ryo Shintani

    SYNTHESIS-STUTTGART　Vol. 48　No. 8　p. 1087-1100　2016/04　Book review, literature introduction, etc.

  3. Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

    Ryo Shintani

    ASIAN JOURNAL OF ORGANIC CHEMISTRY　Vol. 4　No. 6　p. 510-514　2015/06　Book review, literature introduction, etc.

  4. 新規触媒的不斉合成によるケイ素不斉中心の構築

    新谷亮

    旭硝子財団研究助成成果発表会　Vol. 2014　p. 32-33　2014/07

  5. ロジウム触媒による不斉ケイ素中心を持つ光学活性ジベンゾシロールの合成

    高木智博, 伊藤智章, 新谷亮, 野崎京子

    日本化学会講演予稿集　Vol. 94th　No. 4　2014/03/12

  6. 銅触媒によるγ位二置換リン酸アリル類のアリールおよびシリルボロン酸エステルを用いた不斉アリル位置換反応

    竹田桃太郎, 高津慶士, 新谷亮, 林民生

    日本化学会講演予稿集　Vol. 94th　No. 4　2014/03/12

  7. ロジウム触媒を用いた3‐アリールシクロプロペンの重合反応

    飯野亮, 新谷亮, 野崎京子

    日本化学会講演予稿集　Vol. 94th　No. 4　2014/03/12

  8. 銅/NHC触媒を用いた新しい不斉合成反応

    新谷亮

    日本薬学会年会要旨集(CD-ROM)　Vol. 134th　2014

  9. Enantioselective Construction of Silicon Stereocenters by New Asymmetric Catalysis

    p. 1-5　2014

    Publisher: 旭硝子財団

  10. Lecture Tour upon Receiving the 8th Lectureship Award MBLA

    Vol. 71　No. 4　p. 357-364　2013/04

    Publisher: 有機合成化学協会

  11. Lecture Tour upon Receiving the 8th Lectureship Award MBLA

    SHINTANI Ryo

    Vol. 71　No. 4　p. 357-364　2013/04/01

  12. 銅触媒を用いたリン酸アリル類のシリルボロン酸エステルによる不斉アリル位置換反応

    竹田桃太郎, 新谷亮, 林民生

    日本化学会講演予稿集　Vol. 93rd　No. 4　2013/03/08

  13. 不斉ケイ素中心を持つ架橋ビアリール化合物の触媒的不斉合成

    新谷亮, MACIVER Eleanor E, 玉國史子, 大伴晴香, 大田健介, 林民生

    日本化学会講演予稿集　Vol. 93rd　No. 4　2013/03/08

  14. エポキシド‐二酸化炭素交互共重合における触媒の回収および再利用

    藤江竜平, 中野幸司, 新谷亮, 野崎京子

    日本化学会講演予稿集　Vol. 93rd　No. 4　2013/03/08

  15. Lectureship Award MBLA: Lecture Tour upon Receiving the 8th Lectureship Award MBLA

    Ryo Shintani

    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry　Vol. 71　No. 4　p. 357-364　2013

    Publisher: The Society of Synthetic Organic Chemistry, Japan

  16. gamma-Methylidene-delta-valerolactones: New Reagents for Palladium-Catalyzed Intermolecular Cyclization Reactions

    Ryo Shintani

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN　Vol. 85　No. 9　p. 931-939　2012/09　Book review, literature introduction, etc.

  17. パラジウム触媒による環状有機化合物の高選択的合成法

    新谷亮

    万有生命科学振興国際交流財団仙台シンポジウム　Vol. 23rd　p. 4-9　2012/06/02

  18. パラジウム触媒を用いたシラシクロブタンのエナンチオ選択的非対称化による不斉四級ケイ素中心の構築

    新谷亮, 守屋孝平, 林民生

    日本化学会講演予稿集　Vol. 92nd　No. 4　2012/03/09

  19. 遷移金属触媒による環状有機化合物の高選択的合成法の開発

    新谷亮

    日本化学会講演予稿集　Vol. 92nd　No. 4　2012/03/09

  20. 銅触媒によるリン酸アリル類の有機ボロン酸エステルを用いた不斉アリル位置換反応

    新谷亮, 竹田桃太郎, 高津慶士, 林民生

    日本化学会講演予稿集　Vol. 92nd　No. 4　2012/03/09

  21. パラジウム触媒を用いたγ‐メチリデン‐δ‐バレロラクトンとアルデヒドによる4‐オキサスピロ[2.4]へプタンの合成

    新谷亮, 伊藤智章, 林民生

    日本化学会講演予稿集　Vol. 92nd　No. 4　2012/03/09

  22. 銅触媒による有機ボロン酸エステルのアルキリデンシアノ酢酸エステルへの不斉1,4‐付加反応

    新谷亮, 高津慶士, 林民生

    日本化学会講演予稿集　Vol. 91st　No. 4　2011/03/11

  23. 新規光学活性ホスフィン‐オレフィン配位子の合成とロジウム触媒による不斉1,4‐付加への利用

    新谷亮, 成井倫太郎, 林沙悠梨, 堤洋介, 林民生

    日本化学会講演予稿集　Vol. 91st　No. 4　2011/03/11

  24. パラジウム触媒によるγ‐メチリデン‐δ‐バレロラクトンとイソシアネートとの脱炭酸を伴う環化反応の機構に関する研究

    新谷亮, 辻孝宙, PARK Soyoung, 林民生

    日本化学会講演予稿集　Vol. 91st　No. 4　2011/03/11

  25. パラジウム触媒を用いた脱炭酸を伴う2‐アルキリデントリメチレンカーボネートとイソシアネートによるシクロプロパン化反応

    新谷亮, 守屋孝平, 林民生

    日本化学会講演予稿集　Vol. 91st　No. 4　2011/03/11

  26. ロジウム触媒によるN‐トシルケトイミンの不斉アリール化反応

    新谷亮, 竹田桃太郎, 辻孝宙, 林民生

    日本化学会講演予稿集　Vol. 91st　No. 4　2011/03/11

  27. gamma-Methylidene-delta-valerolactones: New Reagents for Palladium-catalyzed Intermolecular Cyclization Reactions

    Ryo Shintani

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN　Vol. 68　No. 8　p. 834-844　2010/08

  28. γ-methylidene-δ-valerolactones: New reagents for palladium-catalyzed intermodular cyclization reactions

    Ryo Shintani

    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry　Vol. 68　No. 8　p. 834-844　2010/08

    Publisher: The Society of Synthetic Organic Chemistry, Japan

  29. ロジウム/キラルジエン触媒によるアリールボロキシンのβ位二置換α,β‐不飽和ケトンへの不斉1,4‐付加反応

    新谷亮, 竹田桃太郎, 西村貴洋, 林民生

    日本化学会講演予稿集　Vol. 90th　No. 4　2010/03/12

  30. ロジウム/キラルジエン触媒によるスピロ型炭素環状化合物の不斉合成

    新谷亮, 磯部真吾, 竹田桃太郎, 林民生

    日本化学会講演予稿集　Vol. 90th　No. 4　2010/03/12

  31. テトラアリールホウ酸ナトリウムを用いたロジウム/ジエン触媒によるβ位二置換α,β‐不飽和ケトンへの1,4‐付加反応

    新谷亮, 堤洋介, 永長誠, 西村貴洋, 林民生

    日本化学会講演予稿集　Vol. 90th　No. 4　2010/03/12

  32. 銅触媒によるアリールボロン酸エステルのイサチンへの不斉付加反応

    新谷亮, 高津慶士, 林民生

    日本化学会講演予稿集　Vol. 90th　No. 4　2010/03/12

  33. β‐アミノ酸の合成を指向したロジウム触媒によるアリールボロン酸の不斉1,4‐付加反応

    西村貴洋, WANG Jun, 永長誠, 岡本和紘, 新谷亮, CHAN Albert S. C, 林民生

    日本化学会講演予稿集　Vol. 90th　No. 4　2010/03/12

  34. パラジウム触媒によるγ‐メチリデン‐δ‐バレロラクトンと1,1‐ジシアノシクロプロパンとの脱炭酸を伴う[4+3]環化反応

    新谷亮, 村上正鷹, 辻孝宙, 淡野秀行, 林民生

    日本化学会講演予稿集　Vol. 90th　No. 4　2010/03/12

  35. Palladium-Catalyzed Decarboxylative Intramolecular Cyclization of .ALPHA.-Aryl-.GAMMA.-methylidene-.DELTA.-valerolactones

    SHINTANI RYO, TSUJI TAKAOKI, PARK SOYOUNG, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 89th　No. 2　2009/03/13

  36. Rhodium-Catalyzed Kinetic Resolution of Tertiary Homoallyl Alcohols via Stereoselective Carbon-Carbon Bond Cleavage

    SHINTANI RYO, TAKATSU KEISHI, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 89th　No. 2　2009/03/13

  37. Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium-Catalyzed Decarboxylative Cycloaddition of .GAMMA.-Methylidene-.DELTA.-valerolactones with Imines

    SHINTANI RYO, MURAKAMI MASATAKA, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 89th　No. 2　2009/03/13

  38. Palladium-Catalyzed Decarboxylative [4+1] Cycloaddition of .GAMMA.-Methylidene-.DELTA.-valerolactones with Isocyanides

    PARK SOYOUNG, SHINTANI RYO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 89th　No. 2　2009/03/13

  39. Palladium-Catalyzed Decarboxylative [4+2] Cycloaddition of .GAMMA.-Methylidene-.DELTA.-valerolactones with Isatins

    SHINTANI RYO, HAYASHI SHIN'YA, MURAKAMI MASATAKA, TAKEDA MOMOTARO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 89th　No. 2　2009/03/13

  40. Rhodium-Catalyzed Intramolecular Asymmetric [5+2] Cycloaddition of Alkyne-Vinylcyclopropanes

    SHINTANI RYO, NAKATSU HIROKI, TAKATSU KEISHI, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 89th　No. 2　2009/03/13

  41. Palladium-catalyzed decarboxylative [4 + 1] cyclization of γ-methylidene-δ-vaierolaetones with isocyanides

    Soyoung Park, Ryo Shintani, Tamio Hayashi

    Chemistry Letters　Vol. 38　No. 3　p. 204-205　2009

  42. パラジウム触媒によるγ‐メチリデン‐δ‐バレロラクトンとイソシアネートの不斉[4+2]環化付加反応

    新谷亮, 白水文貴, PARK Soyoung, 村上正鷹, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  43. パラジウム触媒を用いたγ‐メチリデン‐δ‐バレロラクトンと電子不足オレフィンの環化付加反応によるスピロ[2.4]ヘプタン類の合成

    新谷亮, PARK Soyoung, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  44. 有機[2‐(ヒドロキシメチル)フェニル]ジメチルシランのイミンおよびアルキンへの1,2‐付加反応

    中尾佳亮, 武田聖英, CHEN Jinshui, 檜山爲次郎, 市川善隆, 新谷亮, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  45. パラジウム触媒によるγ‐メチリデン‐δ‐バレロラクトンとニトロンの[4+3]環化付加反応

    新谷亮, 村上正鷹, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  46. 新規ビシクロ[3.3.1]ノナ‐2,6‐ジエン配位子の開発とそれを用いたロジウム触媒による不斉1,4‐付加反応

    新谷亮, 市川善隆, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  47. ロジウム触媒を用いるアルキニルアルケニルカルビノール類の不斉転位反応

    西村貴洋, 加藤泰祐, 高津慶士, 新谷亮, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  48. ロジウム触媒を用いたアリールビス(アルキニル)カルビノールの3‐アルキニル‐1‐インダノンへの転位反応

    新谷亮, 高津慶士, 加藤泰祐, 西村貴洋, 林民生

    日本化学会講演予稿集　Vol. 88th　No. 2　2008/03/12

  49. パラジウム触媒によるトリメチレンメタンとアゾメチンイミンの[3+3]環化付加反応

    新谷亮, 林民生

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  50. ロジウム触媒による3,3‐二置換1‐インダノン類の不斉合成

    新谷亮, 高津慶士, 林民生

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  51. カルベン配位子存在下鉄触媒を用いたアリールアルキルアセチレンのアリールマグネシウム化反応

    山上高史, 新谷亮, 白川英二, 林民生

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  52. ロジウム/キラルジエン触媒を用いたアルケニルケイ素試薬のβ‐シリルα,β‐不飽和カルボニル化合物への1,4‐付加によるアリルシランの不斉合成

    新谷亮, 市川善隆, 林民生, CHEN Jinshui, 中尾佳亮, 檜山爲次郎

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  53. ロジウム/キラルジエン触媒による分子内[4+2]不斉環化付加反応

    新谷亮, 三戸祐太, 林民生

    日本化学会講演予稿集　Vol. 87th　No. 2　2007/03/12

  54. Asymmetric Synthesis of 2-Aryl-2,3-dihydro-4-quinolones by Rhodium-Catalyzed 1,4-Addition of Arylzinc Reagents in the Presence of Chlorotrimethylsilane

    SHINTANI RYO, YAMAGAMI TAKAFUMI, KIMURA TAKAHIRO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 86th　No. 2　2006/03/13

  55. Carbon-carbon Bond-Forming Enantioselective Synthesis of Chiral Organosilicon Compounds by Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition Reaction

    SHINTANI RYO, OKAMOTO KAZUHIRO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 86th　No. 2　2006/03/13

  56. Rhodium-Catalyzed Asymmetric Addition of Aryl- and Alkenylboronic Acids to Isatins

    SHINTANI RYO, INOUE MITSUNORI, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 86th　No. 2　2006/03/13

  57. Rhodium-Catalyzed Asymmetric Synthesis of Indanones: Development of a New Axially-Chiral Bisphosphine Ligand

    SHINTANI RYO, YASHIO KEIJI, NAKAMURA TOMOAKI, OKAMOTO KAZUHIRO, SHIMADA TOYOSHI, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 86th　No. 2　2006/03/13

  58. Asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated aldehydes catalyzed by a chiral diene-rhodium complex

    Tamio Hayashi, Norihito Tokunaga, Kazuhiro Okamoto, Ryo Shintani

    Chemistry Letters　Vol. 34　No. 11　p. 1480-1481　2005/11/05

  59. 不斉ジエン配位子を用いたロジウム触媒によるN‐スルホニルアリールイミン類の不斉アリール化反応.光学活性ジアリールメチルアミン類の触媒的不斉合成

    徳永礼仁, 乙丸裕介, 新谷亮, 林民生

    反応と合成の進歩シンポジウム講演要旨集　Vol. 31st　p. 44-45　2005/10/12

  60. Palladium/chiral phosphine-olefin complexes: X-ray crystallographic analysis and the use in catalytic asymmetric allylic alkylation

    R Shintani, WL Duan, K Okamoto, T Hayashi

    TETRAHEDRON-ASYMMETRY　Vol. 16　No. 20　p. 3400-3405　2005/10

  61. Rhodium-catalyzed synthesis of indenols by regioselective coupling of alkynes with ortho-carbonylated arylboronic acids

    Ryo Shintani, Kazuhiro Okamoto, Tamio Hayashi

    Chemistry Letters　Vol. 34　No. 9　p. 1294-1295　2005/09/05

  62. C-2-Symmetric bicyclo[3.3.1]nona-2,6-diene and bicyclo[3.3.2]deca-2,6-diene: new chiral diene ligands based on the 1,5-cyclooctadiene framework

    Y Otomaru, A Kina, R Shintani, T Hayashi

    TETRAHEDRON-ASYMMETRY　Vol. 16　No. 9　p. 1673-1679　2005/05

  63. Preparation of a C2-Symmetric Bicyclo[3.3.1]nonadiene Ligand and Its Use for Rhodium-Catalyzed Asymmetric Arylation of N-(4-Nitrobenzenesulfonyl)arylimines

    OTOMARU YUSUKE, TOKUNAGA NORIHITO, SHINTANI RYO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 85th　No. 2　2005/03/11

  64. Rhodium/Diene-Catalyzed Asymmetric Arylative Cyclization of Alkyne-Tethered Electron-Deficient Olefins

    SHINTANI RYO, TSURUSAKI AKIHIRO, OKAMOTO KAZUHIRO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 85th　No. 2　2005/03/11

  65. Rhodium/Diene-Catalyzed Asymmetric Arylative Cyclization of Alkynals

    SHINTANI RYO, OKAMOTO KAZUHIRO, OTOMARU YUSUKE, UEYAMA KAZUHITO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 85th　No. 2　2005/03/11

  66. Preparation of C2-Symmetric Chiral Bicyclo[2.2.2]octadiene Ligands and Their Use for Rhodium-Catalyzed Asymmetric Reactions

    OTOMARU YUSUKE, TOKUNAGA NORIHITO, OKAMOTO KAZUHIRO, SHINTANI RYO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 85th　No. 2　2005/03/11

  67. Rhodium-Catalyzed Isomerization of .ALPHA.-Arylpropargyl Alcohols to Indanones

    SHINTANI RYO, OKAMOTO KAZUHIRO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 85th　No. 2　2005/03/11

  68. Rhodium/Chiral Diene-Catalyzed Enantioselective Conjugate Addition of Organoboronic Acids to Maleimides

    SHINTANI RYO, YAMADA ICHIRO, UEYAMA KAZUHITO, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 84th　No. 2　2004/03/11

  69. Rhodium-Catalyzed Enantioselective Conjugate Addition to .BETA.-N-Substituted-.ALPHA.,.BETA.-enones

    SHINTANI RYO, DOI HIDENORI, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 84th　No. 2　2004/03/11

  70. Applications of Planar-Chiral Phosphaferrocene-Oxazoline Ligands in Cu-Catalyzed Asymmetric Cycloadditions

    SHINTANI RYO, FU G C

    日本化学会講演予稿集　Vol. 84th　No. 2　2004/03/11

  71. Synthesis and application of planar-chiral phosphaferroceneoxazolines, a new class of P,N-ligands.

    GC Fu, R Shintani

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　Vol. 224　p. U178-U179　2002/08　Research paper, summary (international conference)

  72. Highly enantioselective desymmetrization of anhydrides by carbon nucleophiles: Reactions of grignard reagents in the presence of (-)-sparteine.

    GC Fu, R Shintani

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY　Vol. 224　p. U202-U202　2002/08　Research paper, summary (international conference)

  73. Asymmetric synthesis of metallocenes through asymmetric addition of aryllithiums to 6-(dimethylamino)fulvenes.

    SUZUKA TOSHIMASA, SHINTANI RYO, OGASAWARA MASAMICHI, HAYASHI TAMIO

    日本化学会講演予稿集　Vol. 79th　No. 2　2001/03/15

Industrial Property Rights 1

  1. 重合生成物と金属錯体触媒の分離、回収方法

    中野 幸司, 野崎 京子, 新谷 亮, 西岡 聖司, 藤本 信貴

    出願日:2013/03/06

Institutional Repository 3

Content Published in the University of Osaka Institutional Repository (OUKA)

  1. Theoretical Investigation on the Copper‐Catalyzed anti‐Selective 1,2‐Silylboration of Internal Alkynes

    Moniwa Hirokazu, Yamanaka Masahiro, Shintani Ryo

    European Journal of Organic Chemistry　2025/01/10

  2. A Kinetically Stabilized Nitrogen-Doped Triangulene Cation: Stable and NIR Fluorescent Diradical Cation with Triplet Ground State

    Arikawa Shinobu, Shimizu Akihiro, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Sotome Hikaru, Miyasaka Hiroshi, Murai Masahito, Yamaguchi Shigehiro, Shintani Ryo

    Angewandte Chemie International Edition　Vol. 62　No. 29　2023/06/12

  3. Zwitterionic Open-Shell Singlet Diradical with Solvent-Dependent Singlet–Triplet Energy Gap

    Shimizu Akihiro, Hayashida Masaaki, Ochi Yuta, Shiomi Daisuke, Sato Kazunobu, Takui Takeji, Shintani Ryo

    Asian Journal of Organic Chemistry　Vol. 12　No. 8　2023/05/23