Synthesis of highly condensed phospholes by the Lewis acid-assisted dehydrogenative Mallory reaction under visible light irradiation

Ikki Kamiyoshi, Yuki Kojima, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano

Chemical Science　2024/11　Research paper (scientific journal)

Organic Mechanochromic Luminescent Materials with Self-Recovering Characters.

Shotaro Nakamura, Koji Hirano, Norimitsu Tohnai

ChemPlusChem　2024/07/30　Research paper (scientific journal)

Organophotoredox-Catalyzed C–H Functionalizations of Benzophospholes

Yu Tokura, Shibo Xu, Ikki Kamiyoshi, Koji Hirano

Organic Letters　2024/06/18　Research paper (scientific journal)

Nickel-Catalyzed Electrophilic Amination of the Biphenylene C–C σ-Bond

Takeru Inoue, Soshi Nishino, Kosuke Yasui, Koji Hirano

Organic Letters　2024/05/14　Research paper (scientific journal)

Facile Preparation of SeCF3-substituted Alkenes from Alkenyl Iodides and Selenium Powder

Haruka Matsui, Yuki Kojima, Koji Hirano

Chemistry Letters　2024/04/20　Research paper (scientific journal)

Asymmetric Synthesis of SCF3‐Substituted Alkylboronates by Copper‐Catalyzed Hydroboration of 1‐Trifluoromethylthioalkenes

Yuki Kojima, Yuji Nishii, Koji Hirano

Angewandte Chemie International Edition　2024/03/12　Research paper (scientific journal)

Pd-catalysed C–H alkynylation of benzophospholes

Yu Tokura, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano

Chemical Communications　2024/02　Research paper (scientific journal)

Direct Synthesis of Benzoselenophene and Benzothiophene Derivatives from 1,1-Diarylethenes and Biaryls by Chalcogen Cation-Mediated Successive Bond Formation

Hiroki Iwamoto, Yuki Kojima, Kazutoshi Nishimura, Kosuke Yasui, Koji Hirano

Organic Letters　2024/01/26　Research paper (scientific journal)

Tunable Mechanochromic Luminescence of Benzofuran-Fused Pyrazine: Effects of Alkyl Chain Length and Branching Pattern

Shotaro Nakamura, Kohei Okubo, Yuji Nishii, Koji Hirano, Norimitsu Tonai, Masahiro Miura

Journal of Materials Chemistry C　2024　Research paper (scientific journal)

Direct synthesis of spirobifluorenes by formal dehydrative coupling of biaryls and fluorenones

Yugo Kato, Kazutoshi Nishimura, Yuji Nishii, Koji Hirano

Chemical Science　2024　Research paper (scientific journal)

Palladium‐Catalyzed α‐Selective Halogenation of Triptycene Using Sulfur Directing Group

Keisuke Ueno, Yuji Nishii, Koji Hirano, Masahiro Miura

Asian Journal of Organic Chemistry　2023/12/11　Research paper (scientific journal)

Rhodium-Catalyzed Direct Vinylene Annulation of 2-Aryloxazolines and Cascade Ring-Opening Using a Vinyl Selenone

Yuji Nishii, Masahiro Miura, Junya Kitano, Koji Hirano

Synlett　2023/11/20　Research paper (scientific journal)

Aromatic halogenation using carborane catalyst

Chandrababu Naidu Kona, Rikuto Oku, Shotaro Nakamura, Masahiro Miura, Koji Hirano, Yuji Nishii

Chem　2023/11　Research paper (scientific journal)

Stimuli‐Responsive Properties on a Bisbenzofuropyrazine Core: Mechanochromism and Concentration‐Controlled Vapochromism

Shotaro Nakamura, Kohei Okubo, Yuji Nishii, Koji Hirano, Norimitsu Tohnai, Masahiro Miura

Chemistry – A European Journal　2023/09/11　Research paper (scientific journal)

Copper-mediated Trifluoromethylthiolation of Alkenyl Iodides with AgSCF₃

Yuki Kojima, Koji Hirano

Chemistry Letters　2023/09/09　Research paper (scientific journal)

Preparation and Use of (γ,γ-Dioxyallyl)boronates

Soshi Nishino, Yuji Nishii, Koji Hirano

Synlett　2023/03/09　Research paper (scientific journal)

One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C–P/C–C Bond Forming Reaction

Kazutoshi Nishimura, Shibo Xu, Yuji Nishii, Koji Hirano

Organic Letters　Vol. 25　No. 9　p. 1503-1508　2023/02/23　Research paper (scientific journal)

Copper-catalyzed Electrophilic Amination: An Umpolung Strategy for New C–N Bond Formations

Koji Hirano

Bulletin of the Chemical Society of Japan　Vol. 96　No. 3　p. 198-207　2023/01/27　Research paper (scientific journal)

Synthesis of α-Aminophosphonates by Umpolung-Enabled Cu-Catalyzed Regioselective Hydroamination

Nakamura, S., Nishino, S., Hirano, K.

Journal of Organic Chemistry　Vol. 88　No. 2　p. 1270-1281　2023/01/11　Research paper (scientific journal)

Rhodium-Catalyzed Isoquinoline Synthesis Using Vinyl Selenone as Oxidizing Acetylene Surrogate

Inami, A., Nishii, Y., Hirano, K., Miura, M.

Organic Letters　2023　Research paper (scientific journal)

Copper-Catalyzed Regio- and Diastereoselective Borylacylation of α,β-Unsaturated Esters

Nishino, S., Hirano, K.

Asian Journal of Organic Chemistry　Vol. 12　No. 2　2023　Research paper (scientific journal)

anti-Selective synthesis of β-boryl-α-amino acid derivatives by Cu-catalysed borylamination of α,β-unsaturated esters

Nishino, S., Nishii, Y., Hirano, K.

Chemical Science　Vol. 13　No. 48　p. 14387-14394　2022/11　Research paper (scientific journal)

Ligand-Enabled Copper-Catalyzed Regio- and Stereoselective Allylboration of 1-Trifluoromethylalkenes

Kojima, Y., Nishii, Y., Hirano, K.

Organic Letters　Vol. 24　No. 40　p. 7450-7454　2022/10/02　Research paper (scientific journal)

Pd-catalysed, Ag-assisted C2–H alkenylation of benzophospholes

Yu Tokura, Shibo Xu, Yuki Kojima, Masahiro Miura, Koji Hirano

Chemical Communications　Vol. 58　No. 87　p. 12208-12211　2022/10　Research paper (scientific journal)

Palladium-catalysed C–H arylation of benzophospholes with aryl halides

Shibo Xu, Kazutoshi Nishimura, Kosuke Saito, Koji Hirano, Masahiro Miura

Chemical Science　Vol. 13　No. 36　p. 10950-10960　2022/08　Research paper (scientific journal)

Palladium-Catalyzed Cross-Coupling Reaction of Diarylmethanol Derivatives with Diborylmethane

Kento Asai, Masahiro Miura, Koji Hirano

The Journal of Organic Chemistry　Vol. 87　No. 11　p. 7436-7445　2022/05/24　Research paper (scientific journal)

Catalytic Asymmetric Construction of CF3-Substituted Chiral sp3 Carbon Centers

Koji Hirano

Synthesis　Vol. 54　No. 17　p. 3708-3718　2022/04/25　Research paper (scientific journal)

Synthesis of β-Silyl-α-amino Acid Derivatives by Cu-Catalyzed Regio- and Enantioselective Silylamination of α,β-Unsaturated Esters

Kobayashi, T., Nishino, S., Miura, M., Hirano, K.

Organic Letters　Vol. 24　No. 6　p. 1418-1422　2022/02/03　Research paper (scientific journal)

Palladium-Catalyzed Benzylic Silylation of Diarylmethyl Carbonates with Silylboranes under Base-Free Conditions

Asai, K., Hirano, K., Miura, M.

European Journal of Organic Chemistry　Vol. 2022　No. 17　2022/01/19　Research paper (scientific journal)

Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

Koji Hirano, Masahiro Miura

Journal of the American Chemical Society　Vol. 144　No. 2　p. 648-661　2022/01/05　Research paper (scientific journal)

Copper-Catalyzed Regio- and Enantioselective Hydroallylation of 1-Trifluoromethylalkenes: Effect of Crown Ether

Yuki Kojima, Masahiro Miura, Koji Hirano

ACS Catalysis　Vol. 11　No. 18　p. 11663-11670　2021/09/07　Research paper (scientific journal)

Copper-mediated Regioselective C–H Cyanation of Phenols with Assistance of Bipyridine-type Bidentate Auxiliary

Rikuo Kajiwara, Koji Hirano, Masahiro Miura

Chemistry Letters　Vol. 50　No. 10　p. 1814-1817　2021/08/18　Research paper (scientific journal)

Bipyridine-Type Bidentate Auxiliary-Enabled Copper-Mediated C–H/C–H Biaryl Coupling of Phenols and 1,3-Azoles

Rikuo Kajiwara, Shibo Xu, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 23　No. 14　p. 5405-5409　2021/07/02　Research paper (scientific journal)

Nickel-Catalyzed Regio- and Stereospecific C–H Coupling of Benzamides with Aziridines

Shibo Xu, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 23　No. 14　p. 5471-5475　2021/07/01　Research paper (scientific journal)

Rhodium-Catalyzed C4-Selective C–H Alkenylation of 2-Pyridones by Traceless Directing Group Strategy

Sunit Hazra, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 23　No. 4　p. 1388-1393　2021/02/08　Research paper (scientific journal)

Regioselective C-H Functionalization of Heteroaromatics at Unusual Positions

Hirano, K., Miura, M.

Remote C-H Bond Functionalizations: Methods and Strategies in Organic Synthesis　2021　Research paper (scientific journal)

An umpolung-enabled copper-catalysed regioselective hydroamination approach to α-amino acids

Soshi Nishino, Masahiro Miura, Koji Hirano

Chemical Science　Vol. 12　No. 34　p. 11525-11537　2021　Research paper (scientific journal)

Pd-Catalyzed Regioselective C–H Alkenylation and Alkynylation of Allylic Alcohols with the Assistance of a Bidentate Phenanthroline Auxiliary

Shibo Xu, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 22　No. 22　p. 9059-9064　2020/11/04　Research paper (scientific journal)

Divergent Synthesis of Isonitriles and Nitriles by Palladium-Catalyzed Benzylic Substitution with TMSCN

Kento Asai, Koji Hirano, Masahiro Miura

The Journal of Organic Chemistry　Vol. 85　No. 19　p. 12703-12714　2020/09/09　Research paper (scientific journal)

Copper-Mediated Regioselective C–H Sulfenylation and Selenation of Phenols with Phenanthroline Bidentate Auxiliary

Rikuo Kajiwara, Kazutaka Takamatsu, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 22　No. 15　p. 5915-5919　2020/07　Research paper (scientific journal)

Cu-Catalyzed Reductive gem-Difunctionalization of Terminal Alkynes via Hydrosilylation/Hydroamination Cascade: Concise Synthesis of α-Aminosilanes

Nishino, S., Hirano, K., Miura, M.

Chemistry - A European Journal　Vol. 26　No. 40　2020/06　Research paper (scientific journal)

Synthesis of DPPP- and DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene- and Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis

Yugo Kato, Nobutaka Otomura, Koji Hirano, Masahiro Miura

The Journal of Organic Chemistry　2020/04/07　Research paper (scientific journal)

Direct Synthesis of Dibenzophospholes from Biaryls by Double C–P Bond Formation via Phosphenium Dication Equivalents

Kazutoshi Nishimura, Koji Hirano, Masahiro Miura

Organic Letters　2020/04/07　Research paper (scientific journal)

Highly Stereoselective Synthesis of 1,2-Disubstituted Indanes by Pd-Catalyzed Heck/Suzuki Sequence of Diarylmethyl Carbonates

Akihiro Matsude, Koji Hirano, Masahiro Miura

Organic Letters　2020/04/03　Research paper (scientific journal)

Synthesis of gem-Difluoroalkenes by Copper-catalyzed Regioselective Hydrodefluorination of 1-Trifluoromethylalkenes

Yuki Kojima, Tatsuaki Takata, Koji Hirano, Masahiro Miura

Chemistry Letters　2020/03　Research paper (scientific journal)

Palladium-Catalyzed Intramolecular Mizoroki-Heck-Type Reaction of Diarylmethyl Carbonates

Matsude, A., Hirano, K., Miura, M.

Advanced Synthesis and Catalysis　Vol. 362　No. 3　2020　Research paper (scientific journal)

Pyridine-directed Rh-catalyzed C6-selective C–H acetoxylation of 2-pyridones

Hazra, S., Hirano, K., Miura, M.

Heterocycles　Vol. 101　No. 1　2020　Research paper (scientific journal)

Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary

Takamatsu, K., Hayashi, Y., Kawauchi, S., Hirano, K., Miura, M.

ChemistrySelect　Vol. 4　No. 40　2019/11　Research paper (scientific journal)

Copper-Catalyzed Electrophilic Amination of gem-Diborylalkanes with Hydroxylamines Providing α-Aminoboronic Acid Derivatives

Nishino, S., Hirano, K., Miura, M.

Organic Letters　Vol. 21　No. 12　p. 4759-4762　2019/06/05　Research paper (scientific journal)

Copper-Catalyzed Regioselective C–H Amination of Phenol Derivatives with Assistance of Phenanthroline-Based Bidentate Auxiliary

Kazutaka Takamatsu, Yoshihiro Hayashi, Susumu Kawauchi, Koji Hirano, Masahiro Miura

ACS Catalysis　p. 5336-5344　2019/05/09　Research paper (scientific journal)

Synthesis of α-Trifluoromethylamines by Cu-Catalyzed Regio- and Enantioselective Hydroamination of 1-Trifluoromethylalkenes

Takata, T., Hirano, K., Miura, M.

Organic Letters　2019/05　Research paper (scientific journal)

Solvent-Controlled Rhodium-Catalyzed C6-Selective C−H Alkenylation and Alkylation of 2-Pyridones with Acrylates

Hazra, S., Hirano, K., Miura, M.

Asian Journal of Organic Chemistry　2019/04　Research paper (scientific journal)

Synthesis of Dibenzophospholes by Tf <inf>2</inf> O-Mediated Intramolecular Phospha-Friedel-Crafts-Type Reaction

Nishimura, K., Hirano, K., Miura, M.

Organic Letters　Vol. 21　No. 5　p. 1467-1470　2019/02　Research paper (scientific journal)

Synthesis of Seven-Membered Benzolactones by Nickel-Catalyzed C−H Coupling of Benzamides with Oxetanes

Xu S, Takamatsu K, Hirano K, Miura M

Chemistry - A European Journal　Vol. 25　No. 40　p. 9400-9404　2019　Research paper (scientific journal)

Diphosphination of ortho-quinone methide precursors with diphosphines

Kato, Y., Otomura, N., Hirano, K., Miura, M.

Tetrahedron Letters　2019　Research paper (scientific journal)

Synthesis of α-Aminophosphines by Copper-Catalyzed Regioselective Hydroamination of Vinylphosphines

Tatsuaki Takata, Daiki Nishikawa, Koji Hirano, Masahiro Miura

Chemistry - A European Journal　Vol. 24　No. 43　2018/07/05　Research paper (scientific journal)

Nickel-Catalyzed Stereospecific C-H Coupling of Benzamides with Epoxides

Masahiro Miura, Shibo Xu, Kazukata Takamatsu, Koji Hirano

Angewandte Chemie International Edition　Vol. 57　No. 36　p. 11797-11801　2018/07　Research paper (scientific journal)

Phosphenium-Cation-Mediated Formal Cycloaddition Approach to Benzophospholes

Nishimura, K., Unoh, Y., Hirano, K., Miura, M.

Chemistry - A European Journal　Vol. 24　No. 50　2018/07　Research paper (scientific journal)

Diphosphination of Arynes with Diphosphines

Yuto Okugawa, Yoshihiro Hayashi, Susumu Kawauchi, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 20　No. 12　p. 3670-3673　2018/06/15　Research paper (scientific journal)

Palladium-Catalyzed Benzylic Phosphorylation of Diarylmethyl Carbonates

Akihiro Matsude, Koji Hirano, Masahiro Miura

Organic Letters　Vol. 20　No. 12　p. 3553-3556　2018/06/15　Research paper (scientific journal)

Asymmetric Synthesis of Diarylmethyl Sulfones by Palladium-Catalyzed Enantioselective Benzylic Substitution: A Remarkable Effect of Water

Atifah Najib, Koji Hirano, Masahiro Miura

Chemistry - A European Journal　Vol. 24　No. 25　p. 6525-6529　2018/05/02　Research paper (scientific journal)

Copper-Catalyzed Regio- and Enantioselective Aminoboration of Unactivated Terminal Alkenes

Kodai Kato, Koji Hirano, Masahiro Miura

Chemistry - A European Journal　Vol. 24　No. 22　p. 5775-5778　2018/04/17　Research paper (scientific journal)

Bromine Cation Initiated vic -Diphosphination of Styrenes with Diphosphines under Photoredox Catalysis

Otomura, N., Okugawa, Y., Hirano, K., Miura, M.

Synthesis (Germany)　Vol. 50　No. 17　2018/04/04　Research paper (scientific journal)

Oxidative rearrangement of benzylamines to 4H-3,1-benzoxazines via Cu/Mn-promoted intramolecular C–H amination/electrocyclic reaction cascade

Yamamoto, C., Takamatsu, K., Hirano, K., Miura, M.

Heterocycles　Vol. 97　No. 1　2018　Research paper (scientific journal)

Copper-mediated decarboxylative coupling of benzamides with potassium malonate monoesters via directed CH cleavage

Kazutaka Takamatsu, Koji Hirano, Masahiro Miura

Chemistry Letters　Vol. 47　No. 4　p. 450-453　2018　Research paper (scientific journal)

Diphosphination of 1,3-Dienes with Diphosphines under Visible-Light-Promoted Photoredox Catalysis

Otomura, N., Hirano, K., Miura, M.

Organic Letters　Vol. 20　No. 24　p. 7965-7968　2018　Research paper (scientific journal)

Development of new C-N and C-P bond formations with alkenes and alkynes based on electrophilic amination and phosphination

Hirano, K., Miura, M.

Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry　Vol. 76　No. 11　p. 1206-1214　2018　Research paper (scientific journal)

Recent advances in diphosphination of alkynes and alkenes

Koji Hirano, Masahiro Miura

TETRAHEDRON LETTERS　Vol. 58　No. 46　p. 4317-4322　2017/11　Research paper (scientific journal)

Iridium-Catalyzed Site-Selective C-H Borylation of 2-Pyridones

Wataru Miura, Koji Hirano, Masahiro Miura

SYNTHESIS-STUTTGART　Vol. 49　No. 21　p. 4745-4752　2017/11　Research paper (scientific journal)

Copper/Bisphosphine Catalysts in the Internally Borylative Aminoboration of Unactivated Terminal Alkenes with Bis(pinacolato)diboron

Kodai Kato, Koji Hirano, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 82　No. 19　p. 10418-10424　2017/10　Research paper (scientific journal)

vic-Diphosphination of Alkenes with Silylphosphine under Visible-Light-Promoted Photoredox Catalysis

Nobutaka Otomura, Yuto Okugawa, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 19　No. 18　p. 4802-4805　2017/09　Research paper (scientific journal)

A Divergent Approach to Indoles and Oxazoles from Enamides by Directing-Group-Controlled Cu-Catalyzed Intramolecular C-H Amination and Alkoxylation

Chiaki Yamamoto, Kazutaka Takamatsu, Koji Hirano, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 82　No. 17　p. 9112-9118　2017/09　Research paper (scientific journal)

Cesium Hydroxide-mediated Regio- and Stereoselective Hydroamidation of Internal Aryl Alkynes with Primary Amides

Chiaki Yamamoto, Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 46　No. 7　p. 1048-1050　2017/07　Research paper (scientific journal)

Bronsted Base Mediated Stereoselective Diphosphination of Terminal Alkynes with Diphosphanes

Yuto Okugawa, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 19　No. 11　p. 2973-2976　2017/06　Research paper (scientific journal)

Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary Benzyl Carbonates with Nitrogen and Oxygen Nucleophiles

Atifah Najib, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 19　No. 9　p. 2438-2441　2017/05　Research paper (scientific journal)

Nickel-Catalyzed Directed C6-Selective C-H Alkylation of 2-Pyridones with Dienes and Activated Alkenes

Wataru Miura, Koji Hirano, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 82　No. 10　p. 5337-5344　2017/05　Research paper (scientific journal)

Metal-Free Electrophilic Phosphination/Cyclization of Alkynes

Yuto Unoh, Koji Hirano, Masahiro Miura

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 139　No. 17　p. 6106-6109　2017/05　Research paper (scientific journal)

Copper-Mediated Decarboxylative Coupling of Benzamides with ortho-Nitrobenzoic Acids by Directed C-H Cleavage

Kazutaka Takamatsu, Koji Hirano, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 56　No. 19　p. 5353-5357　2017/05　Research paper (scientific journal)

Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines

Tomohiro Yasuhisa, Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 46　No. 4　p. 463-465　2017/04　Research paper (scientific journal)

Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines

Tomohiro Yasuhisa, Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 46　No. 4　p. 463-465　2017/04　Research paper (scientific journal)

Construction of Bisbenzofuro[2,3-b:3',2'-e]pyridines by Palladium-Catalyzed Double Intramolecular Oxidative C-H/C-H Coupling

Hiroyuki Kaida, Tsuyoshi Goya, Yuji Nishi, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 19　No. 5　p. 1236-1239　2017/03　Research paper (scientific journal)

A lesson for site-selective C-H functionalization on 2-pyridones: Radical, organometallic, directing group and steric controls

Koji Hirano, Masahiro Miura

Chemical Science　Vol. 9　No. 1　p. 22-32　2017

Copper-Catalyzed Regioselective Ring-Opening Hydroamination of Methylenecyclopropanes

Daiki Nishikawa, Ryosuke Sakae, Yuya Miki, Koji Hirano, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 81　No. 24　p. 12128-12134　2016/12　Research paper (scientific journal)

Synthesis of beta-Boryl-alpha-Aminosilanes by Copper-Catalyzed Aminoboration of Vinylsilanes

Kodai Kato, Koji Hirano, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 55　No. 46　p. 14398-14402　2016/11　Research paper (scientific journal)

Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides

Yuto Unoh, Yuki Yokoyama, Tetsuya Satoh, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 18　No. 20　p. 5436-5439　2016/10　Research paper (scientific journal)

Copper-Catalyzed Vicinal Diphosphination of Styrenes: Access to 1,2-Bis(diphenylphosphino)ethane-Type Bidentate Ligands from Olefins

Yuto Okugawa, Koji Hirano, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 55　No. 43　p. 13558-13561　2016/10　Research paper (scientific journal)

Copper-Catalyzed Regio- and Stereoselective Aminoboration of Alkenylboronates

Daiki Nishikawa, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 18　No. 19　p. 4856-4859　2016/10　Research paper (scientific journal)

Synthesis of Benzobis- and Benzotrisbenzofurans by Palladium-Catalyzed Multiple Intramolecular C-H/C-H Coupling

Hiroyuki Kaida, Tetsuya Satoh, Yuji Nishii, Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 45　No. 9　p. 1069-1071　2016/09　Research paper (scientific journal)

Copper-Catalyzed Intramolecular Benzylic C-H Amination for the Synthesis of Isoindolinones

Chiaki Yamamoto, Kazutaka Takamatsu, Koji Hirano, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 81　No. 17　p. 7675-7684　2016/09　Research paper (scientific journal)

Rhodium-Catalyzed C6-Selective C-H Borylation of 2-Pyridones

Wataru Miura, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 18　No. 15　p. 3742-3745　2016/08　Research paper (scientific journal)

HIGHLY C3-SELECTIVE DIRECT ALKYLATION AND ARYLATION OF 2-PYRIDONES UNDER VISIBLE-LIGHT-PROMOTED PHOTOREDOX CATALYSIS

Atifah Najib, Sho Tabuchi, Koji Hirano, Masahiro Miura

HETEROCYCLES　Vol. 92　No. 7　p. 1187-1203　2016/07　Research paper (scientific journal)

Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with alpha-Naphthylbenzyl Carbonates and Pivalates

Sho Tabuchi, Koji Hirano, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 55　No. 24　p. 6973-6977　2016/06　Research paper (scientific journal)

Synthesis of Benzo[c]thiophenes by Rhodium(III)-Catalyzed Dehydrogenative Annulation

Keita Fukuzumi, Yuto Unoh, Yuji Nishii, Tetsuya Satoh, Koji Hirano, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 81　No. 6　p. 2474-2481　2016/03　Research paper (scientific journal)

Highly C3-Selective Direct Alkylation and Arylation of 2-Pyridones under Visible-Light-Promoted Photoredox Catalysis

Atifah Najib, Tabuchi Sho, Hirano Koji, Miura Masahiro

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute　Vol. 2016　p. 156-156　2016

Copper-catalyzed intramolecular benzylic C-H amination for the synthesis of isoindolinones

Yamamoto Chiaki, Takamatsu Kazutaka, Hirano Koji, Miura Masahiro

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute　Vol. 2016　p. 157-157　2016

Copper-Mediated Intermolecular C-H/C-H and C-H/N-H Couplings via Aromatic C-H Cleavage

Koji Hirano, Masahiro Miura

C-H BOND ACTIVATION AND CATALYTIC FUNCTIONALIZATION II　Vol. 56　p. 47-65　2016　Research paper (scientific journal)

Asymmetric Synthesis of alpha-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

Daiki Nishikawa, Koji Hirano, Masahiro Miura

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 137　No. 50　p. 15620-15623　2015/12　Research paper (scientific journal)

Stereospecific Pd-Catalyzed Intermolecular C(sp(3))-C(sp) Cross-Coupling of Diarylmethyl Carbonates and Terminal Alkynes Under Base-Free Conditions

Sho Tabuchi, Koji Hirano, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 21　No. 47　p. 16823-16827　2015/11　Research paper (scientific journal)

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

Yuto Unoh, Tetsuya Satoh, Koji Hirano, Masahiro Miura

ACS CATALYSIS　Vol. 5　No. 11　p. 6634-6639　2015/11　Research paper (scientific journal)

Rhodium-catalyzed direct ortho-alkenylation of phenyl sulfones with alkynes utilizing sulfonyl function as modifiable directing group

Kazunori Nobushige, Koji Hirano, Tetsuya Satoh, Masahiro Miura

TETRAHEDRON　Vol. 71　No. 37　p. 6506-6512　2015/09　Research paper (scientific journal)

Synthesis of Thieno[3,2-b]benzofurans by Palladium-catalyzed Intramolecular C-H/C-H Coupling

Hiroyuki Kaida, Tetsuya Satoh, Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 44　No. 8　p. 1125-1127　2015/08　Research paper (scientific journal)

Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C-H Bond Cleavage

Yuki Yokoyama, Yuto Unoh, Rebekka Anna Bohmann, Tetsuya Satoh, Koji Hirano, Carsten Bolm, Masahiro Miura

CHEMISTRY LETTERS　Vol. 44　No. 8　p. 1104-1106　2015/08　Research paper (scientific journal)

Copper-Catalyzed Formal [4+1] Cycloaddition of Benzamides and Isonitriles via Directed C-H Cleavage

Kazutaka Takamatsu, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 17　No. 16　p. 4066-4069　2015/08　Research paper (scientific journal)

Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed C-H Cleavage

Wataru Miura, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 17　No. 16　p. 4034-4037　2015/08　Research paper (scientific journal)

ChemInform Abstract: Rhodium-Catalyzed Dehydrogenative Coupling of Phenylheteroarenes with Alkynes or Alkenes.

Tomonori Iitsuka, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ChemInform　Vol. 46　No. 29　2015/07

Recent Advances in Copper-mediated Direct Biaryl Coupling

Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 44　No. 7　p. 868-873　2015/07

Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation

Ryosuke Morioka, Kazunori Nobushige, Tetsuya Satoh, Koji Hirano, Masahiro Miura

ORGANIC LETTERS　Vol. 17　No. 12　p. 3130-3133　2015/06　Research paper (scientific journal)

ChemInform Abstract: Copper-Catalyzed Stereoselective Aminoboration of Bicyclic Alkenes.

Ryosuke Sakae, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ChemInform　Vol. 46　No. 22　2015/05

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

Ryosuke Sakae, Koji Hirano, Masahiro Miura

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 137　No. 20　p. 6460-6463　2015/05　Research paper (scientific journal)

Evaluation of the intrinsic charge carrier transporting properties of linear- and bent-shaped π-extended benzo-fused thieno[3,2-b]thiophenes

Yusuke Tsutsui, Tsuneaki Sakurai, Sojiro Minami, Koji Hirano, Tetsuya Satoh, Wakana Matsuda, Kenichi Kato, Masaki Takata, Masahiro Miura, Shu Seki

Physical Chemistry Chemical Physics　Vol. 17　No. 15　p. 9624-9628　2015/04　Research paper (scientific journal)

Rhodium-Catalyzed Dehydrogenative Coupling of Phenylheteroarenes with Alkynes or Alkenes

Tomonori Iitsuka, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 80　No. 5　p. 2804-2814　2015/03　Research paper (scientific journal)

Synthesis of Indolines by Copper-Mediated Intramolecular Aromatic C-H Amination

Kazutaka Takamatsu, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 80　No. 6　p. 3242-3249　2015/03　Research paper (scientific journal)

Direct Synthesis of N-H Carbazoles via Iridium(III)-Catalyzed Intramolecular C-H Amination

Chiharu Suzuki, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 17　No. 6　p. 1597-1600　2015/03　Research paper (scientific journal)

Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C-H Bond Cleavage

Yuto Unoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 17　No. 3　p. 704-707　2015/02　Research paper (scientific journal)

Copper-Mediated Formally Dehydrative Biaryl Coupling of Azine N-Oxides and Oxazoles

Riko Odani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 80　No. 4　p. 2384-2391　2015/02　Research paper (scientific journal)

COD ID: 4101101

Hayashi Sayuri, Hirano Koji, Yorimitsu Hideki, Oshima Koichiro

Crystallography Open Database　2015

Copper-Catalyzed Stereoselective Aminoboration of Bicyclic Alkenes

Ryosuke Sakae, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 54　No. 2　p. 613-617　2015/01　Research paper (scientific journal)

Rhodium-catalyzed Intramolecular Dehydrogenatiye Aryl-Aryl Coupling Using Air as Terminal Oxidant

Hannah Baars, Yuto Unoh, Takeshi Okada, Koji Hirano, Tetsuya Satoh, Ken Tanaka, Carsten Bolm, Masahiro Miura

CHEMISTRY LETTERS　Vol. 43　No. 11　p. 1782-1784　2014/11　Research paper (scientific journal)

Iridium-Catalyzed Annulative Coupling of 2-Arylbenzoyl Chlorides with Alkynes: Selective Formation of Phenanthrene Derivatives

Tomoya Nagata, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 79　No. 19　p. 8960-8967　2014/10　Research paper (scientific journal)

Unexpected Cyclization of Tritylamines Promoted by Copper Salt through C-H and C-N Bond Cleavages to Produce Acridine Derivatives

Ryosuke Morioka, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 20　No. 40　p. 12720-12724　2014/09　Research paper (scientific journal)

Copper-Mediated C6-Selective Dehydrogenative Heteroarylation of 2-Pyridones with 1,3-Azoles

Riko Odani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 53　No. 40　p. 10784-10788　2014/09　Research paper (scientific journal)

2,6-Diphenyl- and -distyryl-capped 3,7-dialkoxybenzo[1,2-b:4,5-b′]dithiophenes and their dithieno-annulated higher homologs: Structural phase transition with enhanced charge carrier mobility

Sojiro Minami, Marina Ide, Koji Hirano, Tetsuya Satoh, Tsuneaki Sakurai, Kenichi Kato, Masaki Takata, Shu Seki, Masahiro Miura

Physical Chemistry Chemical Physics　Vol. 16　No. 35　p. 18805-18812　2014/08/13　Research paper (scientific journal)

Rhodium(III)-Catalyzed Regioselective C-H Alkenylation of Phenylphosphine Sulfides

Yuki Yokoyama, Yuto Unoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 79　No. 16　p. 7649-7655　2014/08　Research paper (scientific journal)

Development of Direct Aromatic Coupling Reactions by Transition-Metal Catalysis

Masahiro Miura, Tetsuya Satoh, Koji Hirano

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN　Vol. 87　No. 7　p. 751-764　2014/07

Synthesis of [1]benzothieno[3,2-b][1]benzothiophene (BTBT) and its higher homologs through palladium-catalyzed intramolecular decarboxylative arylation

Sojiro Minami, Koji Hirano, Tetsuya Satoh, Masahiro Miura

TETRAHEDRON LETTERS　Vol. 55　No. 30　p. 4175-4177　2014/07　Research paper (scientific journal)

Synthesis of Triarylmethanes by Palladium-Catalyzed C-H/C-O Coupling of Oxazoles and Diarylmethanol Derivatives

Sho Tabuchi, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 79　No. 12　p. 5401-5411　2014/06　Research paper (scientific journal)

Synthesis of Carbazoles by Copper-Catalyzed Intramolecular C-H/N-H Coupling

Kazutaka Takamatsu, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 16　No. 11　p. 2892-2895　2014/06　Research paper (scientific journal)

Copper-Mediated Direct Arylation of Azole Compounds

Koji Hirano, Masahiro Miura

TOPICS IN CATALYSIS　Vol. 57　No. 10-13　p. 878-889　2014/06　Research paper (scientific journal)

Ruthenium- and Rhodium-Catalyzed Dehydrogenative ortho-Alkenylation of Benzylamines via Free Amino Group Directed C-H Bond Cleavage

Chiharu Suzuki, Keisuke Morimoto, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ADVANCED SYNTHESIS & CATALYSIS　Vol. 356　No. 7　p. 1521-1526　2014/05　Research paper (scientific journal)

Copper-Catalyzed alpha-Methylenation of Benzylpyridines Using Dimethylacetamide as One-Carbon Source

Masaki Itoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 16　No. 7　p. 2050-2053　2014/04　Research paper (scientific journal)

ChemInform Abstract: Copper-Mediated Dehydrogenative Biaryl Coupling of Naphthylamines and 1,3-Azoles.

Riko Odani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Wiley-Blackwell ChemInform　Vol. 45　No. 14　2014/03　Research paper (scientific journal)

Copper-Catalyzed Enantioselective Formal Hydroamination of Oxa-and Azabicyclic Alkenes with Hydrosilanes and Hydroxylamines

Yuya Miki, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 16　No. 5　p. 1498-1501　2014/03　Research paper (scientific journal)

Copper-catalyzed aminoboration and hydroamination of alkenes with electrophilic amination reagents

Koji Hirano, Masahiro Miura

PURE AND APPLIED CHEMISTRY　Vol. 86　No. 3　p. 291-297　2014/03　Research paper (scientific journal)

Manganese-Mediated C3-Selective Direct Alkylation and Arylation of 2-Pyridones with Diethyl Malonates and Arylboronic Acids

Akihiro Nakatani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 79　No. 3　p. 1377-1385　2014/02　Research paper (scientific journal)

Highly Stereoselective Synthesis of (Borylmethyl)cyclopropylamines by Copper-Catalyzed Aminoboration of Methylenecyclopropanes

Ryosuke Sakae, Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 16　No. 4　p. 1228-1231　2014/02　Research paper (scientific journal)

Rhodium(III)-Catalyzed Ortho-Alkenylation through C-H Bond Cleavage Directed by Sulfoxide Groups

Kazunori Nobushige, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 16　No. 4　p. 1188-1191　2014/02　Research paper (scientific journal)

PALLADIUM-CATALYZED DIRECT ARYLATION AND ALKENYLATION OF 3-(INDOL-3-YL)PROPIONIC ACIDS THROUGH C-H BOND CLEAVAGE

Daisuke Takeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

HETEROCYCLES　Vol. 88　No. 1　p. 275-286　2014/01　Research paper (scientific journal)

Erratum: Iridium-catalyzed annulative coupling of 2-arylbenzoyl chlorides with alkynes: Selective formation of phenanthrene derivatives (Journal of Organic Chemistry (2014) 79 (8960-8967) DOI:10.1021/jo501835u)

Nagata, T., Hirano, K., Satoh, T., Miura, M.

Journal of Organic Chemistry　Vol. 79　No. 24　2014　Research paper (scientific journal)

Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages

Tomonori Iitsuka, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 20　No. 2　p. 385-389　2014/01　Research paper (scientific journal)

COPPER-MEDIATED REGIOSELECTIVE HOMOCOUPLING OF THIOPHENES AND INDOLES VIA DIRECTED C-H CLEAVAGE

Riko Odani, Mayuko Nishino, Koji Hirano, Tetsuya Satoh, Masahiro Miura

HETEROCYCLES　Vol. 88　No. 1　p. 595-602　2014/01　Research paper (scientific journal)

An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving C-C and C-P Bond Formation

Yuto Unoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 52　No. 49　p. 12975-12979　2013/12　Research paper (scientific journal)

Koji Hirano

Koji Hirano

Angewandte Chemie International Edition　Vol. 53　No. 9　p. 2276-2276　2013/11/07　Research paper (scientific journal)

Rhodium-Catalyzed Decarboxylative and Dehydrogenative Coupling of Maleic Acids with Alkynes and Alkenes

Masaki Itoh, Masaki Shimizu, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 78　No. 22　p. 11427-11432　2013/11　Research paper (scientific journal)

Copper-Mediated Dehydrogenative Biaryl Coupling of Naphthylarnines and 1,3-Azoles

Riko Odani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 78　No. 21　p. 11045-11052　2013/11　Research paper (scientific journal)

Copper-catalyzed intermolecular regioselective hydroamination of styrenes with polymethylhydrosiloxane and hydroxylamines

Yuya Miki, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Angewandte Chemie - International Edition　Vol. 52　No. 41　p. 10830-10834　2013/10/04　Research paper (scientific journal)

Ruthenium-catalyzed regioselective C-H alkenylation directed by a free amino group

Chiharu Suzuki, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Organic Letters　Vol. 15　No. 15　p. 3990-3993　2013/08/02　Research paper (scientific journal)

Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C-H Bonds

Masaki Itoh, Yuto Hashimoto, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 78　No. 16　p. 8098-8104　2013/08　Research paper (scientific journal)

Rhodium-catalyzed C3-selective alkenylation of substituted thiophene-2-carboxylic acids and related compounds

Tomonori Iitsuka, Petra Schaal, Koji Hirano, Tetsuya Satoh, Carsten Bolm, Masahiro Miura

Journal of Organic Chemistry　Vol. 78　No. 14　p. 7216-7222　2013/07/19　Research paper (scientific journal)

Rhodium(III)-catalyzed Oxidative Coupling through C-H Bond Cleavage Directed by Phosphinoxy Groups

Yuto Unoh, Yuto Hashimoto, Daisuke Takeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 15　No. 13　p. 3258-3261　2013/07　Research paper (scientific journal)

Nickel-catalyzed direct alkylation of heterocycles with α-bromo carbonyl compounds: C3-selective functionalization of 2-pyridones

Akihiro Nakatani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Chemistry - A European Journal　Vol. 19　No. 24　p. 7691-7695　2013/06/10　Research paper (scientific journal)

Synthesis of highly substituted isocoumarins by rhodium-catalyzed annulation of readily available benzoic acids

Yuto Unoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Tetrahedron　Vol. 69　No. 22　p. 4454-4458　2013/06/03　Research paper (scientific journal)

Synthesis of highly substituted isocoumarins by rhodium-catalyzed annulation of readily available benzoic acids

Yuto Unoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Tetrahedron　Vol. 69　No. 22　p. 4454-4458　2013/06/03　Research paper (scientific journal)

C-H Activation of Heteroaromatics

Koji Hirano, Masahiro Miura

Sustainable Catalysis: Challenges and Practices for the Pharmaceutical and Fine Chemical Industries　p. 233-267　2013/05/23　Part of collection (book)

ChemInform Abstract: Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines.

Yuya Miki, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ChemInform　Vol. 44　No. 21　2013/05

Palladium-Catalyzed Decarboxylative Arylation of Benzoylacrylic Acids toward the Synthesis of Chalcones

Yuto Unoh, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 78　No. 10　p. 5096-5102　2013/05　Research paper (scientific journal)

Copper-mediated C-H/C-H biaryl coupling of benzoic acid derivatives and 1,3-azoles

Mayuko Nishino, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Angewandte Chemie - International Edition　Vol. 52　No. 16　p. 4457-4461　2013/04/15　Research paper (scientific journal)

Regioselective and Stereospecific Copper-Catalyzed Aminoboration of Styrenes with Bis(pinacolato)diboron and O-Benzoyl-N,N-dialkylhydroxylamines

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 135　No. 13　p. 4934-4937　2013/04　Research paper (scientific journal)

Synthesis of N-vinylcarbazoles via dehydrogenative coupling of N-H carbazoles with alkenes under palladium catalysis

Daisuke Takeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Organic Letters　Vol. 15　No. 6　p. 1242-1245　2013/03/15　Research paper (scientific journal)

Rhodium- and iridium-catalyzed dehydrogenative cyclization through double C-H bond cleavages to produce fluorene derivatives

Masaki Itoh, Koji Hirano, Tetsuya Satoh, Yu Shibata, Ken Tanaka, Masahiro Miura

Journal of Organic Chemistry　Vol. 78　No. 4　p. 1365-1370　2013/02/15　Research paper (scientific journal)

Synthesis and properties of a benzo[1,2-b:4,5-b ']dithiophene core pi-system that bears alkyl, alkylthio and alkoxy groups at 3,7-positions

Shinya Ota, Sojiro Minami, Koji Hirano, Tetsuya Satoh, Yutaka Ie, Shu Seki, Yoshio Aso, Masahiro Miura

RSC ADVANCES　Vol. 3　No. 30　p. 12356-12365　2013　Research paper (scientific journal)

Regioselective C-H Bond Cleavage/Alkyne Insertion under Ruthenium Catalysis

Yuto Hashimoto, Koji Hirano, Tetsuya Satoh, Fumitoshi Kakiuchi, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 78　No. 2　p. 638-646　2013/01　Research paper (scientific journal)

Formal anti-markovnikov hydroamination of terminal aryl alkynes with pinacolborane and hydroxylamines via Zr/Cu sequential catalysis

Ryosuke Sakae, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Chemistry Letters　Vol. 42　No. 10　p. 1128-1130　2013　Research paper (scientific journal)

Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines

Yuya Miki, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 15　No. 1　p. 172-175　2013/01　Research paper (scientific journal)

SYNTHESIS OF PHENANTHRIDINES AND RELATED COMPOUNDS BY PALLADIUM-CATALYZED DIRECT COUPLING VIA C-H AND N-H BOND CLEAVAGES

Daisuke Takeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

HETEROCYCLES　Vol. 86　No. 1　p. 487-496　2012/12　Research paper (scientific journal)

Copper-Catalyzed Direct Amination of Polyfluoroarenes and Azoles with Hydroxylamines and Its Application to the Synthesis of 3-Aminobenzoheteroles

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

SYNTHESIS-STUTTGART　Vol. 44　No. 12　p. 1792-1797　2012/06　Research paper (scientific journal)

A Concise Access to (Polyfluoroaryl)allenes by Cu-Catalyzed Direct Coupling with Propargyl Phosphates

Akihiro Nakatani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 14　No. 10　p. 2586-2589　2012/05　Research paper (scientific journal)

Dehydrogenative Synthesis of C3-Azolylindoles via Copper-Promoted Annulative Direct Coupling of o-Alkynylanilines

Yoshiro Oda, Naoto Matsuyama, Koji Hirano, Tetsuya Satoh, Masahiro Miura

SYNTHESIS-STUTTGART　Vol. 44　No. 10　p. 1515-1520　2012/05　Research paper (scientific journal)

Effect of the Substitution Pattern of Alkyl Side Chain in a Benzodithiophene Core pi-System on Intra and Inter-Molecular Charge Carrier Mobility (vol 115, pg 8446, 2011)

Jun Kumagai, Koji Hirano, Tetsuya Satoh, Shu Seki, Masahiro Miura

JOURNAL OF PHYSICAL CHEMISTRY B　Vol. 116　No. 13　p. 4115-4115　2012/04

Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C-H Functionalization

Yuto Hashimoto, Koji Hirano, Tetsuya Satoh, Fumitoshi Kakiuchi, Masahiro Miura

ORGANIC LETTERS　Vol. 14　No. 8　p. 2058-2061　2012/04　Research paper (scientific journal)

Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C-H Bond Cleavage

Yuto Hashimoto, Timon Ortloff, Koji Hirano, Tetsuya Satoh, Carsten Bolm, Masahiro Miura

CHEMISTRY LETTERS　Vol. 41　No. 2　p. 151-153　2012/02　Research paper (scientific journal)

Synthesis of Fluorene Derivatives through Rhodium-Catalyzed Dehydrogenative Cyclization

Keisuke Morimoto, Masaki Itoh, Koji Hirano, Tetsuya Satoh, Yu Shibata, Ken Tanaka, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 51　No. 22　p. 5359-5362　2012　Research paper (scientific journal)

Synthesis of N-Azolylindoles by Copper-Catalyzed C-H/N-H Coupling-Annulation Sequence of o-Alkynylanilines

Yoshiro Oda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 14　No. 2　p. 664-667　2012/01　Research paper (scientific journal)

Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups

Tomoyuki Yao, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 51　No. 3　p. 775-779　2012　Research paper (scientific journal)

Erratum: Effect of the substitution pattern of alkyl side chain in a benzodithiophene core π-system on intra and inter-molecular charge carrier mobility (The Journal of Physical Chemistry B (2011) 115:26 (8446-8452))

Kumagai, J., Hirano, K., Satoh, T., Seki, S., Miura, M.

Journal of Physical Chemistry B　Vol. 116　No. 13　2012　Research paper (scientific journal)

Copper-mediated oxidative direct C-C (hetero)aromatic cross-coupling

Koji Hirano, Masahiro Miura

CHEMICAL COMMUNICATIONS　Vol. 48　No. 87　p. 10704-10714　2012　Research paper (scientific journal)

Copper-Catalyzed Amination of Ketene Silyl Acetals with Hydroxylamines: Electrophilic Amination Approach to alpha-Amino Acids

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 51　No. 47　p. 11827-11831　2012　Research paper (scientific journal)

An Annulative Electrophilic Amination Approach to 3-Aminobenzoheteroles

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 77　No. 1　p. 617-625　2012/01　Research paper (scientific journal)

Copper-Catalyzed Amination of Arylboronates with N,N-Dialkylhydroxylamines

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 51　No. 15　p. 3642-3645　2012　Research paper (scientific journal)

Copper-Mediated and Copper-Catalyzed Cross-Coupling of Indoles and 1,3-Azoles: Double C-H Activation

Mayuko Nishino, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 51　No. 28　p. 6993-6997　2012　Research paper (scientific journal)

Synthesis of Isochromene and Related Derivatives by Rhodium-Catalyzed Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes

Keisuke Morimoto, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 22　p. 9548-9551　2011/11　Research paper (scientific journal)

Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C-H Bond Cleavage Directed by a Nitrogen-containing Group

Yuto Hashimoto, Takumi Ueyama, Tatsuya Fukutani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY LETTERS　Vol. 40　No. 10　p. 1165-1166　2011/10　Research paper (scientific journal)

A remarkable effect of ionic liquids in transition-metal-free aerobic oxidation of benzylic alcohols

Yoshiro Oda, Koji Hirano, Tetsuya Satoh, Susumu Kuwabata, Masahiro Miura

TETRAHEDRON LETTERS　Vol. 52　No. 41　p. 5392-5394　2011/10　Research paper (scientific journal)

Palladium-catalyzed Direct Monoarylation of Thiophene-, Benzothiophene-, and Indoleacetic Acids through Regioselective C-H Bond Cleavage

Daisuke Takeda, Mana Yamashita, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY LETTERS　Vol. 40　No. 9　p. 1015-1017　2011/09　Research paper (scientific journal)

ChemInform Abstract: Copper-Catalyzed Direct Amination of Electron-Deficient Arenes with Hydroxylamines.

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ChemInform　Vol. 42　No. 38　2011/08

Copper-Catalyzed Oxidative Direct Cyclization of N-Methylanilines with Electron-Deficient Alkenes Using Molecular Oxygen

Mayuko Nishino, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 15　p. 6447-6451　2011/08　Research paper (scientific journal)

Effect of the Substitution Pattern of Alkyl Side Chain in a Benzodithiophene Core pi-System on Intra and Inter-Molecular Charge Carrier Mobility

Jun Kumagai, Koji Hirano, Tetsuya Satoh, Shu Seki, Masahiro Miura

JOURNAL OF PHYSICAL CHEMISTRY B　Vol. 115　No. 26　p. 8446-8452　2011/07　Research paper (scientific journal)

Rhodium-catalyzed Oxidative Coupling of Benzylamines with Alkynes through Dehydrogenation and Dehydrogenative Cyclization

Keisuke Morimoto, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY LETTERS　Vol. 40　No. 6　p. 600-602　2011/06　Research paper (scientific journal)

Copper-Mediated Annulative Direct Coupling of o-Alkynylphenols with Oxadiazoles: A Dehydrogenative Cascade Construction of Biheteroaryls

Hitoshi Hachiya, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 13　No. 12　p. 3076-3079　2011/06　Research paper (scientific journal)

Copper-Catalyzed Direct Amination of Electron-Deficient Arenes with Hydroxylamines

Naoki Matsuda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 13　No. 11　p. 2860-2863　2011/06　Research paper (scientific journal)

Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

Satoshi Mochida, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 9　p. 3024-3033　2011/05　Research paper (scientific journal)

Copper-Catalyzed Annulative Amination of ortho-Alkynylphenols with Hydroxylamines: Synthesis of 3-Aminobenzofurans by Umpolung Amination Strategy

Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 13　No. 9　p. 2395-2397　2011/05　Research paper (scientific journal)

Synthesis of Highly Substituted Acenes through Rhodium-Catalyzed Oxidative Coupling of Arylboron Reagents with Alkynes

Tatsuya Fukutani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 8　p. 2867-2874　2011/04　Research paper (scientific journal)

Synthesis of Enantiomerically Pure P-Stereogenic Diphosphacrowns and Their Palladium Complexes

Yasuhiro Morisaki, Hiroaki Imoto, Koji Hirano, Tamio Hayashi, Yoshiki Chujo

JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 6　p. 1795-1803　2011/03　Research paper (scientific journal)

C-H Functionalization of Heteroarenes Using First-Row Transition Metals: Copper and Nickel Catalyses

Koji Hirano, Masahiro Miura

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN　Vol. 69　No. 3　p. 252-265　2011/03　Research paper (scientific journal)

Synthesis of 1,4-Diarylbuta-1,3-dienes through Palladium-Catalyzed Decarboxylative Coupling of Unsaturated Carboxylic Acids

Mana Yamashita, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ADVANCED SYNTHESIS & CATALYSIS　Vol. 353　No. 4　p. 631-636　2011/03　Research paper (scientific journal)

Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C-H Bond Cleavage

Takumi Ueyama, Satoshi Mochida, Tatsuya Fukutani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 13　No. 4　p. 706-708　2011/02　Research paper (scientific journal)

Copper-Mediated Intermolecular Direct Biaryl Coupling

Masanori Kitahara, Nobuyoshi Umeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 133　No. 7　p. 2160-2162　2011/02　Research paper (scientific journal)

Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions

Mitsuru Miyasaka, Koji Hirano, Tetsuya Satoh, Rafal Kowalczyk, Carsten Bolm, Masahiro Miura

ORGANIC LETTERS　Vol. 13　No. 3　p. 359-361　2011/02　Research paper (scientific journal)

Direct Carbon-Hydrogen Bond Functionalization of Heterocyclic Compounds

Koji Hirano, Masahiro Miura

SYNLETT　No. 3　p. 294-307　2011/02　Research paper (scientific journal)

Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C-H Bonds

Nobuyoshi Umeda, Koji Hirano, Tetsuya Satoh, Naoto Shibata, Hirofumi Sato, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 76　No. 1　p. 13-24　2011/01　Research paper (scientific journal)

Stereospecific Copper-Catalyzed C-H Allylation of Electron-Deficient Arenes with Allyl Phosphates

Tomoyuki Yao, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 50　No. 13　p. 2990-2994　2011　Research paper (scientific journal)

Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups

Tomoyuki Yao, Koji Hirano, Tetsuya Satoh, Masahiro Miura

Angewandte Chemie International Edition　Vol. 51　No. 3　p. 775-779　2011　Research paper (scientific journal)

Synthesis of Stilbene and Distyrylbenzene Derivatives through Rhodium-Catalyzed Ortho-Olefination and Decarboxylation of Benzoic Acids

Satoshi Mochida, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 12　No. 24　p. 5776-5779　2010/12　Research paper (scientific journal)

Oxidative Nickel-Air Catalysis in C-H Arylation: Direct Cross-Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant

Hitoshi Hachiya, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMCATCHEM　Vol. 2　No. 11　p. 1403-1406　2010/11　Research paper (scientific journal)

Palladium Nanoparticles in Ionic Liquid by Sputter Deposition as Catalysts for Suzuki-Miyaura Coupling in Water

Yoshiro Oda, Koji Hirano, Kazuki Yoshii, Susumu Kuwabata, Tsukasa Torimoto, Masahiro Miura

CHEMISTRY LETTERS　Vol. 39　No. 10　p. 1069-1071　2010/10　Research paper (scientific journal)

Palladium-Catalyzed Direct Oxidative Alkenylation of Azoles

Mitsuru Miyasaka, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 75　No. 15　p. 5421-5424　2010/08　Research paper (scientific journal)

Rhodium-catalyzed Oxidative Coupling/Cyclization of Benzamides with Alkynes via C-H Bond Cleavage

Satoshi Mochida, Nobuyoshi Umeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY LETTERS　Vol. 39　No. 7　p. 744-746　2010/07　Research paper (scientific journal)

Rhodium-Catalyzed Oxidative Coupling/Cyclization of 2-Phenylindoles with Alkynes via C-H and N-H Bond Cleavages with Air as the Oxidant

Keisuke Morimoto, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 12　No. 9　p. 2068-2071　2010/05　Research paper (scientific journal)

A New Entry of Amination Reagents for Heteroaromatic C-H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature

Tsuyoshi Kawano, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 132　No. 20　p. 6900-+　2010/05　Research paper (scientific journal)

Nickel- and Copper-Catalyzed Direct Alkynylation of Azoles and Polyfluoroarenes with Terminal Alkynes under O-2 or Atmospheric Conditions

Naoto Matsuyama, Masanori Kitahara, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 12　No. 10　p. 2358-2361　2010/05　Research paper (scientific journal)

Room Temperature Direct Alkynylation of 1,3,4-Oxadiazoles with Alkynyl Bromides under Copper Catalysis

Tsuyoshi Kawano, Naoto Matsuyama, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 75　No. 5　p. 1764-1766　2010/03　Research paper (scientific journal)

Palladium-Catalyzed Direct Benzylation of Azoles with Benzyl Carbonates

Tomoya Mukai, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 12　No. 6　p. 1360-1363　2010/03　Research paper (scientific journal)

Synthesis of alpha,omega-Diarylbutadienes and -Hexatrienes via Decarboxylative Coupling of Cinnamic Acids with Vinyl Bromides under Palladium Catalysis

Mana Yamashita, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 12　No. 3　p. 592-595　2010/02　Research paper (scientific journal)

Nickel-catalyzed direct C-H arylation of azoles with organosilicon and organoboron reagents

Hachiya Hitoshi, Hirano Koji, Satoh Tetsuya, Miura Masahiro

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute　Vol. 2010　p. 7-7　2010

Synthesis of pi-conjugated molecules via palladium-catalyzed decarboxylative coupling

Yamashita Mana, Hirano Koji, Satoh Tetsuya, Miura Masahiro

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute　Vol. 2010　p. 3-3　2010

Rhodium catalyzed oxidative coupling of carboxylic acids with unsaturated compounds

Mochida Satoshi, Hirano Koji, Satoh Tetsuya, Miura Masahiro

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute　Vol. 2010　p. 2-2　2010

Synthesis of Naphtho[1,8-bc]pyran Derivatives and Related Compounds through Hydroxy Group Directed C-H Bond Cleavage under Rhodium Catalysis

Satoshi Mochida, Masaki Shimizu, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY-AN ASIAN JOURNAL　Vol. 5　No. 4　p. 847-851　2010　Research paper (scientific journal)

Rhodium/Phosphine/Amine center dot HBr Catalyst System for Highly Selective Cross-Cyclodimerization of Aryl- and Alkylalkynes: Efficient Access to Multisubstituted Naphthalene Derivatives

Koichi Sakabe, Hayato Tsurugi, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 16　No. 2　p. 445-449　2010　Research paper (scientific journal)

Synthesis of Substituted Stilbenes via Direct Decarboxylative Coupling of Cinnamic Acids with Arylboronic Acids under Palladium Catalysis

Mana Yamashita, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY LETTERS　Vol. 39　No. 1　p. 68-69　2010/01　Research paper (scientific journal)

Copper-Mediated Direct Cross-Coupling of 1,3,4-Oxadiazoles and Oxazoles with Terminal Alkynes

Masanori Kitahara, Koji Hirano, Hayato Tsurugi, Tetsuya Satoh, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 16　No. 6　p. 1772-1775　2010　Research paper (scientific journal)

Nickel-Catalyzed Direct C-H Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents

Hitoshi Hachiya, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 49　No. 12　p. 2202-2205　2010　Research paper (scientific journal)

Palladium- and Nickel-Catalyzed Direct Alkylation of Azoles with Unactivated Alkyl Bromides and Chlorides

Tomoyuki Yao, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 16　No. 41　p. 12307-12311　2010　Research paper (scientific journal)

Synthesis of Highly Substituted Naphthalene and Anthracene Derivatives by Rhodium-Catalyzed Oxidative Coupling of Arylboronic Acids with Alkynes

Tatsuya Fukutani, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 11　No. 22　p. 5198-5201　2009/11　Research paper (scientific journal)

Synthesis of 2,3-Diarylbenzo[b]thiophenes via Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling and Palladium-Catalyzed Decarboxylative Arylation

Mitsuru Miyasaka, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ADVANCED SYNTHESIS & CATALYSIS　Vol. 351　No. 16　p. 2683-2688　2009/11　Research paper (scientific journal)

Fused Ring Construction around Pyrrole, Indole, and Related Compounds via Palladium-Catalyzed Oxidative Coupling with Alkynes

Maria Yamashita, Hakaru Horiguchi, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 19　p. 7481-7488　2009/10　Research paper (scientific journal)

Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C-H Bond Cleavage

Nobuyoshi Umeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 18　p. 7094-7099　2009/09　Research paper (scientific journal)

Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides

Naoto Matsuyama, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 11　No. 18　p. 4156-4159　2009/09　Research paper (scientific journal)

Synthesis of Functionalized alpha-Pyrone and Butenolide Derivatives by Rhodium-Catalyzed Oxidative Coupling of Substituted Acrylic Acids with Alkynes and Alkenes

Satoshi Mochida, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 16　p. 6295-6298　2009/08　Research paper (scientific journal)

Nickel-Catalyzed C-H Alkenylation and Alkylation of 1,3,4-Oxadiazoles with Alkynes and Styrenes

Tomoya Mukai, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 16　p. 6410-6413　2009/08　Research paper (scientific journal)

Copper-Catalyzed Arylation of Chlorosilanes with Grignard Reagents

Eiji Morita, Kei Murakami, Masayuki Iwasaki, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN　Vol. 82　No. 8　p. 1012-1014　2009/08　Research paper (scientific journal)

Copper-Mediated Direct Arylation of 1,3,4-Oxadiazoles and 1,2,4-Triazoles with Aryl Iodides

Tsuyoshi Kawano, Tomoki Yoshizumi, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 11　No. 14　p. 3072-3075　2009/07　Research paper (scientific journal)

Synthesis of 2,5-diaryloxazoles through van Leusen reaction and copper-mediated direct arylation

Tomoki Yoshizumi, Tetsuya Satoh, Koji Hirano, Daisuke Matsuo, Akihiro Orita, Junzo Otera, Masahiro Miura

TETRAHEDRON LETTERS　Vol. 50　No. 26　p. 3273-3276　2009/07　Research paper (scientific journal)

Palladium-Catalyzed Three-Component 1:2:1 Coupling of Aryl Iodides, Alkynes, and Alkenes to Produce 1,3,5-Hexatriene Derivatives

Hakaru Horiguchi, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ADVANCED SYNTHESIS & CATALYSIS　Vol. 351　No. 9　p. 1431-1436　2009/06　Research paper (scientific journal)

Synthesis of Condensed Heteroaromatic Compounds by Palladium-Catalyzed Oxidative Coupling of Heteroarene Carboxylic Acids with Alkynes

Mana Yamashita, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 11　No. 11　p. 2337-2340　2009/06　Research paper (scientific journal)

Waste-Free Synthesis of Condensed Heterocyclic Compounds by Rhodium-Catalyzed Oxidative Coupling of Substituted Arene or Heteroarene Carboxylic Acids with Alkynes

Masaki Shimizu, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 9　p. 3478-3483　2009/05　Research paper (scientific journal)

Nickel- and Rhodium-Catalyzed Addition of Terminal Silylacetylenes to Propargyl Amines: Catalyst-Dependent Complementary Regioselectivity

Naoto Matsuyama, Koji Hirano, Tetsuya Satoh, Masahiro Miura

JOURNAL OF ORGANIC CHEMISTRY　Vol. 74　No. 9　p. 3576-3578　2009/05　Research paper (scientific journal)

Nickel-Catalyzed Direct Arylation of Azoles with Aryl Bromides

Hitoshi Hachiya, Koji Hirano, Tetsuya Satoh, Masahiro Miura

ORGANIC LETTERS　Vol. 11　No. 8　p. 1737-1740　2009/04　Research paper (scientific journal)

Palladium-Catalyzed 1-Methylene-2-propenylation Reactions of Aryl Bromides with 3,4-Alkadien-1-ols via Carbon-Carbon Bond Cleavage for the Synthesis of 2-Aryl-1,3-butadiene Derivatives

Junichi Imoto, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN　Vol. 82　No. 3　p. 393-400　2009/03　Research paper (scientific journal)

Rhodium-catalyzed and Coordination-assisted Regioselective Alkenylation of Aromatic C-H Bonds with Terminal Silylacetylenes

Takashi Katagiri, Tomoya Mukai, Tetsuya Satoh, Koji Hirano, Masahiro Miura

CHEMISTRY LETTERS　Vol. 38　No. 2　p. 118-119　2009/02　Research paper (scientific journal)

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage

Tatsuya Fukutani, Nobuyoshi Umeda, Koji Hirano, Tetsuya Satoh, Masahiro Miura

CHEMICAL COMMUNICATIONS　No. 34　p. 5141-5143　2009　Research paper (scientific journal)

Fluorescent Diarylindoles by Palladium-Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles

Mitsuru Miyasaka, Azusa Fukushima, Tetsuya Satoh, Koji Hirano, Masahiro Miura

CHEMISTRY-A EUROPEAN JOURNAL　Vol. 15　No. 15　p. 3674-3677　2009　Research paper (scientific journal)

Nickel-catalyzed carboxylation of organozinc reagent with CO(2)

Hidenori Ochiai, Minsul Jang, Koji Hirano, Hideki Yorimitsu, Koichiro Shima

ORGANIC LETTERS　Vol. 10　No. 13　p. 2681-2683　2008/07　Research paper (scientific journal)

Palladium-catalyzed formal cycloaddition of silacyclobutanes with enones: Synthesis of eight-membered cyclic silyl enolates

Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

ORGANIC LETTERS　Vol. 10　No. 11　p. 2199-2201　2008/06　Research paper (scientific journal)

Synthesis of arylallenes by palladium-catalyzed retro-propargylation of homopropargyl alcohols

Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Shima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 130　No. 15　p. 5048-+　2008/04　Research paper (scientific journal)

Nickel-catalyzed allylation of allyl carbonates with homoallyl alcohols via retro-allylation providing 1,5-hexadienes

Yuto Sumida, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

ORGANIC LETTERS　Vol. 10　No. 8　p. 1629-1632　2008/04　Research paper (scientific journal)

1,1-Dimethylsilacyclobutane

Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

Encyclopedia of Reagents for Organic Synthesis　2008/03/14　Research paper (scientific journal)

Silver-catalyzed transmetalation between chlorosilanes and aryl and alkenyl Grignard reagents for the synthesis of tetraorganosilanes

Kei Murakami, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION　Vol. 47　No. 31　p. 5833-5835　2008　Research paper (scientific journal)

Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols by retroallylation and isomerization to saturated ketones with conventional or microwave heating

Yuto Sumida, Yuko Takada, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

CHEMISTRY-AN ASIAN JOURNAL　Vol. 3　No. 1　p. 119-125　2008　Research paper (scientific journal)

Nickel-catalysed reactions with trialkylboranes and silacyclobutanes

Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

CHEMICAL COMMUNICATIONS　No. 28　p. 3234-3241　2008

Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron

Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

ORGANIC LETTERS　Vol. 9　No. 24　p. 5031-5033　2007/11　Research paper (scientific journal)

Synthesis of (Arylal kenyl)si lanes by palladium-catalyzed regiospecific and stereoselective allyl transfer from silyl-substituted homoallyl alcohols to aryl halides

Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 42　p. 12650-+　2007/10　Research paper (scientific journal)

Microwave-assisted palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation

Masayuki Iwasaki, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

TETRAHEDRON　Vol. 63　No. 24　p. 5200-5203　2007/06　Research paper (scientific journal)

Rhodium-catalyzed allyl transfer from homoallyl alcohols to acrylate esters via retro-allylation

Minsul Jang, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

TETRAHEDRON LETTERS　Vol. 48　No. 23　p. 4003-4005　2007/06　Research paper (scientific journal)

Nickel-catalyzed regio- and stereoselective silylation of terminal alkenes with silacyclobutanes: Facile access to vinylsilanes from alkenes

Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 19　p. 6094-+　2007/05　Research paper (scientific journal)

Pd(OAc)(2)/P((C6H11)-C-c)(3)-Catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation

Masayuki Iwasaki, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 129　No. 14　p. 4463-4469　2007/04　Research paper (scientific journal)

Nickel-catalyzed 1,4-addition of trialkylboranes to alpha,beta-unsaturated esters: Dramatic enhancement by addition of methanol

Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

ORGANIC LETTERS　Vol. 9　No. 8　p. 1541-1544　2007/04　Research paper (scientific journal)

CCDC 265711: Experimental Crystal Structure Determination

Hayashi S, Hirano K, Yorimitsu H, Oshima K

Cambridge Structural Database　2007

Gallium-mediated allyl transfer from bulky homoallyl alcohol to aldehydes or alkynes: Control of dynamic sigma-allylgalliums based on retro-allylation reaction

Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

JOURNAL OF ORGANOMETALLIC CHEMISTRY　Vol. 692　No. 1-3　p. 505-513　2007/01　Research paper (scientific journal)

Alkylation of aldehydes with trialkylboranes in water

Koji Hirano, Hideki Yorimitsu, Koichiro Shima

ADVANCED SYNTHESIS & CATALYSIS　Vol. 348　No. 12-13　p. 1543-1546　2006/08　Research paper (scientific journal)

Rhodium-catalyzed allyl transfer from homoallyl alcohols to aldehydes via retro-allylation followed by isomerization into ketones

Yuko Takada, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, Koichiro Oshima

ORGANIC LETTERS　Vol. 8　No. 12　p. 2515-2517　2006/06　Research paper (scientific journal)

Current topics on synthetic reactions with azido compounds

K Hirano

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN　Vol. 64　No. 4　p. 416-417　2006/04

Palladium-catalyzed stereo- and regiospecific allylation of aryl halides with homoallyl alcohols via retro-allylation: Selective generation and use of sigma-allylpalladium

S Hayashi, K Hirano, H Yorimitsu, K Oshima

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY　Vol. 128　No. 7　p. 2210-2211　2006/02　Research paper (scientific journal)

Nickel-catalyzed reactions of silacyclobutanes with aldehydes: Ring opening and ring expansion reaction

K Hirano, H Yorimitsu, K Oshima

ORGANIC LETTERS　Vol. 8　No. 3　p. 483-485　2006/02　Research paper (scientific journal)

Nickel-catalyzed alkylation of aldehydes with trialkylboranes

K Hirano, H Yorimitsu, K Oshima

ORGANIC LETTERS　Vol. 7　No. 21　p. 4689-4691　2005/10　Research paper (scientific journal)

Gallium-mediated allyl transfer from bulky homoallylic alcohol to aldehydes via retro-allylation: Stereoselective synthesis of both erythro- and threo-homoallylic alcohols

S Hayashi, K Hirano, H Yorimitsu, K Oshima

ORGANIC LETTERS　Vol. 7　No. 16　p. 3577-3579　2005/08　Research paper (scientific journal)

Nickel-catalyzed cross-coupling reaction of aryl halides with allylic zirconium reagents generated in situ from zirconocene(alkene) complexes

K Hirano, K Fujita, H Yorimitsu, K Oshima

SYNLETT　No. 11　p. 1787-1788　2005/07　Research paper (scientific journal)

Boron trifluoride-mediated alkylation of diphenylphosphine with tert-alkyl fluoride

K Hirano, H Yorimitsu, K Oshima

ORGANIC LETTERS　Vol. 6　No. 26　p. 4873-4875　2004/12　Research paper (scientific journal)

Boron trifluoride-catalyzed reaction of alkyl fluoride with silyl enolate, allylsilane, and hydrosilane

Koji Hirano, Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo, Koichiro Oshima

Tetrahedron Letters　Vol. 45　No. 12　p. 2555-2557　2004/03/15　Research paper (scientific journal)

Triethylborane-induced radical allylation reaction with zirconocene-olefin complex

K Hirano, K Fujita, H Shinokubo, K Oshima

ORGANIC LETTERS　Vol. 6　No. 4　p. 593-595　2004/02　Research paper (scientific journal)