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Hirano Koji

平野 康次

Graduate School of Engineering Division of Applied Chemistry, Associate Professor

Research Areas

  • Nanotechnology/Materials, Synthetic organic chemistry

Professional Memberships

  • 近畿化学会(有機金属部会)
  • 有機合成化学協会
  • 日本化学会

Papers

  • Rhodium-Catalyzed C4-Selective C–H Alkenylation of 2-Pyridones by Traceless Directing Group Strategy, Sunit Hazra,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), 2021/02/08
  • Pd-Catalyzed Regioselective C–H Alkenylation and Alkynylation of Allylic Alcohols with the Assistance of a Bidentate Phenanthroline Auxiliary, Shibo Xu,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society (ACS), 2020/11/04
  • Divergent Synthesis of Isonitriles and Nitriles by Palladium-Catalyzed Benzylic Substitution with TMSCN, Kento Asai,Koji Hirano,Masahiro Miura, The Journal of Organic Chemistry, American Chemical Society ({ACS}), 2020/09/09
  • Copper-Mediated Regioselective C–H Sulfenylation and Selenation of Phenols with Phenanthroline Bidentate Auxiliary, Rikuo Kajiwara,Kazutaka Takamatsu,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), 2020/07
  • Cu‐Catalyzed Reductive gem ‐Difunctionalization of Terminal Alkynes via Hydrosilylation/Hydroamination Cascade: Concise Synthesis of α‐Aminosilanes, Soshi Nishino,Koji Hirano,Masahiro Miura, Chemistry – A European Journal, Wiley, 2020/06
  • Synthesis of DPPP- and DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene- and Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis, Yugo Kato,Nobutaka Otomura,Koji Hirano,Masahiro Miura, The Journal of Organic Chemistry, American Chemical Society ({ACS}), 2020/04/07
  • Direct Synthesis of Dibenzophospholes from Biaryls by Double C–P Bond Formation via Phosphenium Dication Equivalents, Kazutoshi Nishimura,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), 2020/04/07
  • Highly Stereoselective Synthesis of 1,2-Disubstituted Indanes by Pd-Catalyzed Heck/Suzuki Sequence of Diarylmethyl Carbonates, Akihiro Matsude,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), 2020/04/03
  • Synthesis of gem-Difluoroalkenes by Copper-catalyzed Regioselective Hydrodefluorination of 1-Trifluoromethylalkenes, Yuki Kojima,Tatsuaki Takata,Koji Hirano,Masahiro Miura, Chemistry Letters, The Chemical Society of Japan, 2020/03
  • Pyridine-Directed Rh-Catalyzed C6-Selective C–H Acetoxylation of 2-Pyridones, Masahiro Miura,Koji Hirano,Sunit Hazra, HETEROCYCLES, Japan Institute of Heterocyclic Chemistry, Vol. 101, No. 1, 2020
  • Copper‐Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho ‐Nitrobenzoic Acids Using Phenanthroline‐Based Bidentate Auxiliary, Kazutaka Takamatsu,Yoshihiro Hayashi,Susumu Kawauchi,Koji Hirano,Masahiro Miura, ChemistrySelect, Wiley, Vol. 4, No. 40, 2019/11
  • Synthesis of α-Trifluoromethylamines by Cu-Catalyzed Regio- and Enantioselective Hydroamination of 1-Trifluoromethylalkenes, Tatsuaki Takata,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), 2019/05
  • Solvent‐Controlled Rhodium‐Catalyzed C6‐Selective C−H Alkenylation and Alkylation of 2‐Pyridones with Acrylates, Sunit Hazra,Koji Hirano,Masahiro Miura, Asian Journal of Organic Chemistry, Wiley, 2019/04
  • Synthesis of Dibenzophospholes by Tf2O-Mediated Intramolecular Phospha-Friedel–Crafts-Type Reaction, Kazutoshi Nishimura,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), Vol. 21, No. 5, 2019/02
  • Synthesis of Seven-Membered Benzolactones by Nickel-Catalyzed C−H Coupling of Benzamides with Oxetanes, Xu S,Takamatsu K,Hirano K,Miura M, Chemistry - A European Journal, 2019
  • Diphosphination of ortho-quinone methide precursors with diphosphines, Kato Y,Otomura N,Hirano K,Miura M, Tetrahedron Letters, 2019
  • Copper-Catalyzed Regioselective C-H Amination of Phenol Derivatives with Assistance of Phenanthroline-Based Bidentate Auxiliary, Takamatsu K,Hayashi Y,Kawauchi S,Hirano K,Miura M, ACS Catalysis, p. 5336-5344, 2019
  • Copper-Catalyzed Electrophilic Amination of gem-Diborylalkanes with Hydroxylamines Providing α-Aminoboronic Acid Derivatives, Nishino S,Hirano K,Miura M, Organic Letters, Vol. 21, No. 12, p. 4759-4762, 2019
  • Palladium‐Catalyzed Intramolecular Mizoroki‐Heck‐Type Reaction of Diarylmethyl Carbonates, Akihiro Matsude,Koji Hirano,Masahiro Miura, Advanced Synthesis & Catalysis, Wiley, 2019
  • Nickel-Catalyzed Stereospecific C-H Coupling of Benzamides with Epoxides, Masahiro Miura,Shibo Xu,Kazukata Takamatsu,Koji Hirano, Angewandte Chemie International Edition, Wiley, 2018/07
  • Phosphenium Cation Mediated Formal Cycloaddition Approach to Benzophospholes, Masahiro Miura,Kazutoshi Nishimura,Yuto Unoh,Koji Hirano, Chemistry - A European Journal, Wiley, 2018/07
  • Synthesis of α-Aminophosphines by Copper-Catalyzed Regioselective Hydroamination of Vinylphosphines, Tatsuaki Takata,Daiki Nishikawa,Koji Hirano,Masahiro Miura, Chemistry - A European Journal, Wiley, 2018/07
  • Diphosphination of Arynes with Diphosphines, Yuto Okugawa,Yoshihiro Hayashi,Susumu Kawauchi,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society, Vol. 20, No. 12, p. 3670-3673, 2018/06/15
  • Palladium-Catalyzed Benzylic Phosphorylation of Diarylmethyl Carbonates, Akihiro Matsude,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society, Vol. 20, No. 12, p. 3553-3556, 2018/06/15
  • Asymmetric Synthesis of Diarylmethyl Sulfones by Palladium-Catalyzed Enantioselective Benzylic Substitution: A Remarkable Effect of Water, Atifah Najib,Koji Hirano,Masahiro Miura, Chemistry - A European Journal, Wiley-VCH Verlag, Vol. 24, No. 25, p. 6525-6529, 2018/05/02
  • Copper-Catalyzed Regio- and Enantioselective Aminoboration of Unactivated Terminal Alkenes, Kodai Kato,Koji Hirano,Masahiro Miura, Chemistry - A European Journal, Wiley-VCH Verlag, Vol. 24, No. 22, p. 5775-5778, 2018/04/17
  • Bromine Cation Initiated vic-Diphosphination of Styrenes with Diphosphines under Photoredox Catalysis, Koji Hirano,Masahiro Miura,Nobutaka Otomura,Yuto Okugawa, Synthesis, Georg Thieme Verlag {KG}, 2018/04
  • Oxidative Rearrangement of Benzylamines To 4H-3,1-Benzoxazines via Cu/Mn-Promoted Intramolecular C–H Amination/Electrocyclic Reaction Cascade, Masahiro Miura,Koji Hirano,Chiaki Yamamoto,Kazutaka Takamatsu, HETEROCYCLES, Japan Institute of Heterocyclic Chemistry, Vol. 97, No. 0, 2018
  • Copper-mediated decarboxylative coupling of benzamides with potassium malonate monoesters via directed CH cleavage, Kazutaka Takamatsu,Koji Hirano,Masahiro Miura, Chemistry Letters, Chemical Society of Japan, Vol. 47, No. 4, p. 450-453, 2018
  • Diphosphination of 1,3-Dienes with Diphosphines under Visible-Light-Promoted Photoredox Catalysis, Nobutaka Otomura,Koji Hirano,Masahiro Miura, Organic Letters, American Chemical Society ({ACS}), Vol. 20, No. 24, 2018
  • Development of new C-N and C-P bond formations with alkenes and alkynes based on electrophilic amination and phosphination, Hirano K,Miura M, Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, Vol. 76, No. 11, p. 1206-1214, 2018
  • Recent advances in diphosphination of alkynes and alkenes, Koji Hirano,Masahiro Miura, TETRAHEDRON LETTERS, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 58, No. 46, p. 4317-4322, 2017/11
  • Iridium-Catalyzed Site-Selective C-H Borylation of 2-Pyridones, Wataru Miura,Koji Hirano,Masahiro Miura, SYNTHESIS-STUTTGART, GEORG THIEME VERLAG KG, Vol. 49, No. 21, p. 4745-4752, 2017/11
  • Copper/Bisphosphine Catalysts in the Internally Borylative Aminoboration of Unactivated Terminal Alkenes with Bis(pinacolato)diboron, Kodai Kato,Koji Hirano,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 82, No. 19, p. 10418-10424, 2017/10
  • vic-Diphosphination of Alkenes with Silylphosphine under Visible-Light-Promoted Photoredox Catalysis, Nobutaka Otomura,Yuto Okugawa,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 19, No. 18, p. 4802-4805, 2017/09
  • A Divergent Approach to Indoles and Oxazoles from Enamides by Directing-Group-Controlled Cu-Catalyzed Intramolecular C-H Amination and Alkoxylation, Chiaki Yamamoto,Kazutaka Takamatsu,Koji Hirano,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 82, No. 17, p. 9112-9118, 2017/09
  • Cesium Hydroxide-mediated Regio- and Stereoselective Hydroamidation of Internal Aryl Alkynes with Primary Amides, Chiaki Yamamoto,Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 46, No. 7, p. 1048-1050, 2017/07
  • Bronsted Base Mediated Stereoselective Diphosphination of Terminal Alkynes with Diphosphanes, Yuto Okugawa,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 19, No. 11, p. 2973-2976, 2017/06
  • Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary Benzyl Carbonates with Nitrogen and Oxygen Nucleophiles, Atifah Najib,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 19, No. 9, p. 2438-2441, 2017/05
  • Nickel-Catalyzed Directed C6-Selective C-H Alkylation of 2-Pyridones with Dienes and Activated Alkenes, Wataru Miura,Koji Hirano,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 82, No. 10, p. 5337-5344, 2017/05
  • Metal-Free Electrophilic Phosphination/Cyclization of Alkynes, Yuto Unoh,Koji Hirano,Masahiro Miura, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 139, No. 17, p. 6106-6109, 2017/05
  • Copper-Mediated Decarboxylative Coupling of Benzamides with ortho-Nitrobenzoic Acids by Directed C-H Cleavage, Kazutaka Takamatsu,Koji Hirano,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 56, No. 19, p. 5353-5357, 2017/05
  • Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines, Tomohiro Yasuhisa,Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 46, No. 4, p. 463-465, 2017/04
  • Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines, Tomohiro Yasuhisa,Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 46, No. 4, p. 463-465, 2017/04
  • Construction of Bisbenzofuro[2,3-b:3',2'-e]pyridines by Palladium-Catalyzed Double Intramolecular Oxidative C-H/C-H Coupling, Hiroyuki Kaida,Tsuyoshi Goya,Yuji Nishi,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 19, No. 5, p. 1236-1239, 2017/03
  • A lesson for site-selective C-H functionalization on 2-pyridones: Radical, organometallic, directing group and steric controls, Koji Hirano,Masahiro Miura, Chemical Science, Royal Society of Chemistry, Vol. 9, No. 1, p. 22-32, 2017
  • Copper-Catalyzed Regioselective Ring-Opening Hydroamination of Methylenecyclopropanes, Daiki Nishikawa,Ryosuke Sakae,Yuya Miki,Koji Hirano,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 81, No. 24, p. 12128-12134, 2016/12
  • Synthesis of beta-Boryl-alpha-Aminosilanes by Copper-Catalyzed Aminoboration of Vinylsilanes, Kodai Kato,Koji Hirano,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 55, No. 46, p. 14398-14402, 2016/11
  • Regioselective Synthesis of Benzo[b]phosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides, Yuto Unoh,Yuki Yokoyama,Tetsuya Satoh,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 18, No. 20, p. 5436-5439, 2016/10
  • Copper-Catalyzed Vicinal Diphosphination of Styrenes: Access to 1,2-Bis(diphenylphosphino)ethane-Type Bidentate Ligands from Olefins, Yuto Okugawa,Koji Hirano,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 55, No. 43, p. 13558-13561, 2016/10
  • Copper-Catalyzed Regio- and Stereoselective Aminoboration of Alkenylboronates, Daiki Nishikawa,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 18, No. 19, p. 4856-4859, 2016/10
  • Synthesis of Benzobis- and Benzotrisbenzofurans by Palladium-Catalyzed Multiple Intramolecular C-H/C-H Coupling, Hiroyuki Kaida,Tetsuya Satoh,Yuji Nishii,Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 45, No. 9, p. 1069-1071, 2016/09
  • Copper-Catalyzed Intramolecular Benzylic C-H Amination for the Synthesis of Isoindolinones, Chiaki Yamamoto,Kazutaka Takamatsu,Koji Hirano,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 81, No. 17, p. 7675-7684, 2016/09
  • Rhodium-Catalyzed C6-Selective C-H Borylation of 2-Pyridones, Wataru Miura,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 18, No. 15, p. 3742-3745, 2016/08
  • HIGHLY C3-SELECTIVE DIRECT ALKYLATION AND ARYLATION OF 2-PYRIDONES UNDER VISIBLE-LIGHT-PROMOTED PHOTOREDOX CATALYSIS, Atifah Najib,Sho Tabuchi,Koji Hirano,Masahiro Miura, HETEROCYCLES, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 92, No. 7, p. 1187-1203, 2016/07
  • Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with alpha-Naphthylbenzyl Carbonates and Pivalates, Sho Tabuchi,Koji Hirano,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 55, No. 24, p. 6973-6977, 2016/06
  • Synthesis of Benzo[c]thiophenes by Rhodium(III)-Catalyzed Dehydrogenative Annulation, Keita Fukuzumi,Yuto Unoh,Yuji Nishii,Tetsuya Satoh,Koji Hirano,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 81, No. 6, p. 2474-2481, 2016/03
  • Copper-Mediated Intermolecular C-H/C-H and C-H/N-H Couplings via Aromatic C-H Cleavage, Koji Hirano,Masahiro Miura, C-H BOND ACTIVATION AND CATALYTIC FUNCTIONALIZATION II, SPRINGER-VERLAG BERLIN, Vol. 56, p. 47-65, 2016
  • Asymmetric Synthesis of alpha-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination, Daiki Nishikawa,Koji Hirano,Masahiro Miura, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 137, No. 50, p. 15620-15623, 2015/12
  • Stereospecific Pd-Catalyzed Intermolecular C(sp(3))-C(sp) Cross-Coupling of Diarylmethyl Carbonates and Terminal Alkynes Under Base-Free Conditions, Sho Tabuchi,Koji Hirano,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 21, No. 47, p. 16823-16827, 2015/11
  • Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives, Yuto Unoh,Tetsuya Satoh,Koji Hirano,Masahiro Miura, ACS CATALYSIS, AMER CHEMICAL SOC, Vol. 5, No. 11, p. 6634-6639, 2015/11
  • Rhodium-catalyzed direct ortho-alkenylation of phenyl sulfones with alkynes utilizing sulfonyl function as modifiable directing group, Kazunori Nobushige,Koji Hirano,Tetsuya Satoh,Masahiro Miura, TETRAHEDRON, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 71, No. 37, p. 6506-6512, 2015/09
  • Synthesis of Thieno[3,2-b]benzofurans by Palladium-catalyzed Intramolecular C-H/C-H Coupling, Hiroyuki Kaida,Tetsuya Satoh,Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 44, No. 8, p. 1125-1127, 2015/08
  • Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C-H Bond Cleavage, Yuki Yokoyama,Yuto Unoh,Rebekka Anna Bohmann,Tetsuya Satoh,Koji Hirano,Carsten Bolm,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 44, No. 8, p. 1104-1106, 2015/08
  • Copper-Catalyzed Formal [4+1] Cycloaddition of Benzamides and Isonitriles via Directed C-H Cleavage, Kazutaka Takamatsu,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 17, No. 16, p. 4066-4069, 2015/08
  • Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed C-H Cleavage, Wataru Miura,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 17, No. 16, p. 4034-4037, 2015/08
  • Recent Advances in Copper-mediated Direct Biaryl Coupling, Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 44, No. 7, p. 868-873, 2015/07
  • Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation, Ryosuke Morioka,Kazunori Nobushige,Tetsuya Satoh,Koji Hirano,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 17, No. 12, p. 3130-3133, 2015/06
  • Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes, Ryosuke Sakae,Koji Hirano,Masahiro Miura, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 137, No. 20, p. 6460-6463, 2015/05
  • Evaluation of the intrinsic charge carrier transporting properties of linear- and bent-shaped π-extended benzo-fused thieno[3,2-b]thiophenes, Yusuke Tsutsui,Tsuneaki Sakurai,Sojiro Minami,Koji Hirano,Tetsuya Satoh,Wakana Matsuda,Kenichi Kato,Masaki Takata,Masahiro Miura,Shu Seki, Physical Chemistry Chemical Physics, Vol. 17, No. 15, p. 9624-9628, 2015/04
  • Rhodium-Catalyzed Dehydrogenative Coupling of Phenylheteroarenes with Alkynes or Alkenes, Tomonori Iitsuka,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 80, No. 5, p. 2804-2814, 2015/03
  • Synthesis of Indolines by Copper-Mediated Intramolecular Aromatic C-H Amination, Kazutaka Takamatsu,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 80, No. 6, p. 3242-3249, 2015/03
  • Direct Synthesis of N-H Carbazoles via Iridium(III)-Catalyzed Intramolecular C-H Amination, Chiharu Suzuki,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 17, No. 6, p. 1597-1600, 2015/03
  • Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C-H Bond Cleavage, Yuto Unoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 17, No. 3, p. 704-707, 2015/02
  • Copper-Mediated Formally Dehydrative Biaryl Coupling of Azine N-Oxides and Oxazoles, Riko Odani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 80, No. 4, p. 2384-2391, 2015/02
  • COD ID: 4101101, Hayashi Sayuri,Hirano Koji,Yorimitsu Hideki,Oshima Koichiro, Crystallography Open Database, 2015
  • Copper-Catalyzed Stereoselective Aminoboration of Bicyclic Alkenes, Ryosuke Sakae,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 54, No. 2, p. 613-617, 2015/01
  • Rhodium-catalyzed Intramolecular Dehydrogenatiye Aryl-Aryl Coupling Using Air as Terminal Oxidant, Hannah Baars,Yuto Unoh,Takeshi Okada,Koji Hirano,Tetsuya Satoh,Ken Tanaka,Carsten Bolm,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 43, No. 11, p. 1782-1784, 2014/11
  • Iridium-Catalyzed Annulative Coupling of 2-Arylbenzoyl Chlorides with Alkynes: Selective Formation of Phenanthrene Derivatives, Tomoya Nagata,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 79, No. 19, p. 8960-8967, 2014/10
  • Unexpected Cyclization of Tritylamines Promoted by Copper Salt through C-H and C-N Bond Cleavages to Produce Acridine Derivatives, Ryosuke Morioka,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 20, No. 40, p. 12720-12724, 2014/09
  • Copper-Mediated C6-Selective Dehydrogenative Heteroarylation of 2-Pyridones with 1,3-Azoles, Riko Odani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 53, No. 40, p. 10784-10788, 2014/09
  • 2,6-Diphenyl- and -distyryl-capped 3,7-dialkoxybenzo[1,2-b:4,5-b′]dithiophenes and their dithieno-annulated higher homologs: Structural phase transition with enhanced charge carrier mobility, Sojiro Minami,Marina Ide,Koji Hirano,Tetsuya Satoh,Tsuneaki Sakurai,Kenichi Kato,Masaki Takata,Shu Seki,Masahiro Miura, Physical Chemistry Chemical Physics, Vol. 16, No. 35, p. 18805-18812, 2014/08/13
  • Rhodium(III)-Catalyzed Regioselective C-H Alkenylation of Phenylphosphine Sulfides, Yuki Yokoyama,Yuto Unoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 79, No. 16, p. 7649-7655, 2014/08
  • Development of Direct Aromatic Coupling Reactions by Transition-Metal Catalysis, Masahiro Miura,Tetsuya Satoh,Koji Hirano, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, CHEMICAL SOC JAPAN, Vol. 87, No. 7, p. 751-764, 2014/07
  • Synthesis of [1]benzothieno[3,2-b][1]benzothiophene (BTBT) and its higher homologs through palladium-catalyzed intramolecular decarboxylative arylation, Sojiro Minami,Koji Hirano,Tetsuya Satoh,Masahiro Miura, TETRAHEDRON LETTERS, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 55, No. 30, p. 4175-4177, 2014/07
  • Synthesis of [1]benzothieno[3,2-b][1]benzothiophene (BTBT) and its higher homologs through palladium-catalyzed intramolecular decarboxylative arylation, Sojiro Minami,Koji Hirano,Tetsuya Satoh,Masahiro Miura, TETRAHEDRON LETTERS, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 55, No. 30, p. 4175-4177, 2014/07
  • Synthesis of Triarylmethanes by Palladium-Catalyzed C-H/C-O Coupling of Oxazoles and Diarylmethanol Derivatives, Sho Tabuchi,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 79, No. 12, p. 5401-5411, 2014/06
  • Synthesis of Carbazoles by Copper-Catalyzed Intramolecular C-H/N-H Coupling, Kazutaka Takamatsu,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 16, No. 11, p. 2892-2895, 2014/06
  • Copper-Mediated Direct Arylation of Azole Compounds, Koji Hirano,Masahiro Miura, TOPICS IN CATALYSIS, SPRINGER/PLENUM PUBLISHERS, Vol. 57, No. 10-13, p. 878-889, 2014/06
  • Ruthenium- and Rhodium-Catalyzed Dehydrogenative ortho-Alkenylation of Benzylamines via Free Amino Group Directed C-H Bond Cleavage, Chiharu Suzuki,Keisuke Morimoto,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ADVANCED SYNTHESIS & CATALYSIS, WILEY-V C H VERLAG GMBH, Vol. 356, No. 7, p. 1521-1526, 2014/05
  • Copper-Catalyzed alpha-Methylenation of Benzylpyridines Using Dimethylacetamide as One-Carbon Source, Masaki Itoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 16, No. 7, p. 2050-2053, 2014/04
  • Copper-Catalyzed Enantioselective Formal Hydroamination of Oxa-and Azabicyclic Alkenes with Hydrosilanes and Hydroxylamines, Yuya Miki,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 16, No. 5, p. 1498-1501, 2014/03
  • Copper-catalyzed aminoboration and hydroamination of alkenes with electrophilic amination reagents, Koji Hirano,Masahiro Miura, PURE AND APPLIED CHEMISTRY, WALTER DE GRUYTER GMBH, Vol. 86, No. 3, p. 291-297, 2014/03
  • Manganese-Mediated C3-Selective Direct Alkylation and Arylation of 2-Pyridones with Diethyl Malonates and Arylboronic Acids, Akihiro Nakatani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 79, No. 3, p. 1377-1385, 2014/02
  • Highly Stereoselective Synthesis of (Borylmethyl)cyclopropylamines by Copper-Catalyzed Aminoboration of Methylenecyclopropanes, Ryosuke Sakae,Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 16, No. 4, p. 1228-1231, 2014/02
  • Rhodium(III)-Catalyzed Ortho-Alkenylation through C-H Bond Cleavage Directed by Sulfoxide Groups, Kazunori Nobushige,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 16, No. 4, p. 1188-1191, 2014/02
  • PALLADIUM-CATALYZED DIRECT ARYLATION AND ALKENYLATION OF 3-(INDOL-3-YL)PROPIONIC ACIDS THROUGH C-H BOND CLEAVAGE, Daisuke Takeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, HETEROCYCLES, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 88, No. 1, p. 275-286, 2014/01
  • Erratum: Iridium-catalyzed annulative coupling of 2-arylbenzoyl chlorides with alkynes: Selective formation of phenanthrene derivatives (Journal of Organic Chemistry (2014) 79 (8960-8967) DOI:10.1021/jo501835u), Nagata T,Hirano K,Satoh T,Miura M, Journal of Organic Chemistry, Vol. 79, No. 24, 2014
  • Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages, Tomonori Iitsuka,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 20, No. 2, p. 385-389, 2014/01
  • COPPER-MEDIATED REGIOSELECTIVE HOMOCOUPLING OF THIOPHENES AND INDOLES VIA DIRECTED C-H CLEAVAGE, Riko Odani,Mayuko Nishino,Koji Hirano,Tetsuya Satoh,Masahiro Miura, HETEROCYCLES, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 88, No. 1, p. 595-602, 2014/01
  • An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving C-C and C-P Bond Formation, Yuto Unoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 52, No. 49, p. 12975-12979, 2013/12
  • Rhodium-Catalyzed Decarboxylative and Dehydrogenative Coupling of Maleic Acids with Alkynes and Alkenes, Masaki Itoh,Masaki Shimizu,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 78, No. 22, p. 11427-11432, 2013/11
  • Copper-Mediated Dehydrogenative Biaryl Coupling of Naphthylarnines and 1,3-Azoles, Riko Odani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 78, No. 21, p. 11045-11052, 2013/11
  • Koji Hirano, Angewandte Chemie International Edition, Wiley-Blackwell, Vol. 53, No. 9, 2013/11
  • Copper-catalyzed intermolecular regioselective hydroamination of styrenes with polymethylhydrosiloxane and hydroxylamines, Yuya Miki,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Angewandte Chemie - International Edition, Vol. 52, No. 41, p. 10830-10834, 2013/10/04
  • Ruthenium-catalyzed regioselective C-H alkenylation directed by a free amino group, Chiharu Suzuki,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Organic Letters, Vol. 15, No. 15, p. 3990-3993, 2013/08/02
  • Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C-H Bonds, Masaki Itoh,Yuto Hashimoto,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 78, No. 16, p. 8098-8104, 2013/08
  • Rhodium-catalyzed C3-selective alkenylation of substituted thiophene-2-carboxylic acids and related compounds, Tomonori Iitsuka,Petra Schaal,Koji Hirano,Tetsuya Satoh,Carsten Bolm,Masahiro Miura, Journal of Organic Chemistry, Vol. 78, No. 14, p. 7216-7222, 2013/07/19
  • Rhodium(III)-catalyzed Oxidative Coupling through C-H Bond Cleavage Directed by Phosphinoxy Groups, Yuto Unoh,Yuto Hashimoto,Daisuke Takeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 15, No. 13, p. 3258-3261, 2013/07
  • Nickel-catalyzed direct alkylation of heterocycles with α-bromo carbonyl compounds: C3-selective functionalization of 2-pyridones, Akihiro Nakatani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Chemistry - A European Journal, Vol. 19, No. 24, p. 7691-7695, 2013/06/10
  • Synthesis of highly substituted isocoumarins by rhodium-catalyzed annulation of readily available benzoic acids, Yuto Unoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Tetrahedron, Vol. 69, No. 22, p. 4454-4458, 2013/06/03
  • Synthesis of highly substituted isocoumarins by rhodium-catalyzed annulation of readily available benzoic acids, Yuto Unoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Tetrahedron, Elsevier {BV}, Vol. 69, No. 22, p. 4454-4458, 2013/06/03
  • C-H Activation of Heteroaromatics, Koji Hirano,Masahiro Miura, Sustainable Catalysis: Challenges and Practices for the Pharmaceutical and Fine Chemical Industries, John Wiley and Sons, p. 233-267, 2013/05/23
  • Palladium-Catalyzed Decarboxylative Arylation of Benzoylacrylic Acids toward the Synthesis of Chalcones, Yuto Unoh,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 78, No. 10, p. 5096-5102, 2013/05
  • Copper-mediated C-H/C-H biaryl coupling of benzoic acid derivatives and 1,3-azoles, Mayuko Nishino,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Angewandte Chemie - International Edition, Vol. 52, No. 16, p. 4457-4461, 2013/04/15
  • Regioselective and Stereospecific Copper-Catalyzed Aminoboration of Styrenes with Bis(pinacolato)diboron and O-Benzoyl-N,N-dialkylhydroxylamines, Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 135, No. 13, p. 4934-4937, 2013/04
  • Synthesis of N-vinylcarbazoles via dehydrogenative coupling of N-H carbazoles with alkenes under palladium catalysis, Daisuke Takeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Organic Letters, Vol. 15, No. 6, p. 1242-1245, 2013/03/15
  • Rhodium- and iridium-catalyzed dehydrogenative cyclization through double C-H bond cleavages to produce fluorene derivatives, Masaki Itoh,Koji Hirano,Tetsuya Satoh,Yu Shibata,Ken Tanaka,Masahiro Miura, Journal of Organic Chemistry, Vol. 78, No. 4, p. 1365-1370, 2013/02/15
  • Synthesis and properties of a benzo[1,2-b:4,5-b ']dithiophene core pi-system that bears alkyl, alkylthio and alkoxy groups at 3,7-positions, Shinya Ota,Sojiro Minami,Koji Hirano,Tetsuya Satoh,Yutaka Ie,Shu Seki,Yoshio Aso,Masahiro Miura, RSC ADVANCES, ROYAL SOC CHEMISTRY, Vol. 3, No. 30, p. 12356-12365, 2013
  • Regioselective C-H Bond Cleavage/Alkyne Insertion under Ruthenium Catalysis, Yuto Hashimoto,Koji Hirano,Tetsuya Satoh,Fumitoshi Kakiuchi,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 78, No. 2, p. 638-646, 2013/01
  • Formal anti-markovnikov hydroamination of terminal aryl alkynes with pinacolborane and hydroxylamines via Zr/Cu sequential catalysis, Ryosuke Sakae,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Chemistry Letters, Vol. 42, No. 10, p. 1128-1130, 2013
  • Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines, Yuya Miki,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 15, No. 1, p. 172-175, 2013/01
  • SYNTHESIS OF PHENANTHRIDINES AND RELATED COMPOUNDS BY PALLADIUM-CATALYZED DIRECT COUPLING VIA C-H AND N-H BOND CLEAVAGES, Daisuke Takeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, HETEROCYCLES, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 86, No. 1, p. 487-496, 2012/12
  • Copper-Catalyzed Direct Amination of Polyfluoroarenes and Azoles with Hydroxylamines and Its Application to the Synthesis of 3-Aminobenzoheteroles, Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, SYNTHESIS-STUTTGART, GEORG THIEME VERLAG KG, Vol. 44, No. 12, p. 1792-1797, 2012/06
  • A Concise Access to (Polyfluoroaryl)allenes by Cu-Catalyzed Direct Coupling with Propargyl Phosphates, Akihiro Nakatani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 14, No. 10, p. 2586-2589, 2012/05
  • Dehydrogenative Synthesis of C3-Azolylindoles via Copper-Promoted Annulative Direct Coupling of o-Alkynylanilines, Yoshiro Oda,Naoto Matsuyama,Koji Hirano,Tetsuya Satoh,Masahiro Miura, SYNTHESIS-STUTTGART, GEORG THIEME VERLAG KG, Vol. 44, No. 10, p. 1515-1520, 2012/05
  • Effect of the Substitution Pattern of Alkyl Side Chain in a Benzodithiophene Core pi-System on Intra and Inter-Molecular Charge Carrier Mobility (vol 115, pg 8446, 2011), Jun Kumagai,Koji Hirano,Tetsuya Satoh,Shu Seki,Masahiro Miura, JOURNAL OF PHYSICAL CHEMISTRY B, AMER CHEMICAL SOC, Vol. 116, No. 13, p. 4115-4115, 2012/04
  • Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C-H Functionalization, Yuto Hashimoto,Koji Hirano,Tetsuya Satoh,Fumitoshi Kakiuchi,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 14, No. 8, p. 2058-2061, 2012/04
  • Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C-H Bond Cleavage, Yuto Hashimoto,Timon Ortloff,Koji Hirano,Tetsuya Satoh,Carsten Bolm,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 41, No. 2, p. 151-153, 2012/02
  • Synthesis of Fluorene Derivatives through Rhodium-Catalyzed Dehydrogenative Cyclization, Keisuke Morimoto,Masaki Itoh,Koji Hirano,Tetsuya Satoh,Yu Shibata,Ken Tanaka,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 51, No. 22, p. 5359-5362, 2012
  • Synthesis of N-Azolylindoles by Copper-Catalyzed C-H/N-H Coupling-Annulation Sequence of o-Alkynylanilines, Yoshiro Oda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 14, No. 2, p. 664-667, 2012/01
  • Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups, Tomoyuki Yao,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 51, No. 3, p. 775-779, 2012
  • Erratum: Effect of the substitution pattern of alkyl side chain in a benzodithiophene core π-system on intra and inter-molecular charge carrier mobility (The Journal of Physical Chemistry B (2011) 115:26 (8446-8452)), Kumagai J,Hirano K,Satoh T,Seki S,Miura M, Journal of Physical Chemistry B, Vol. 116, No. 13, 2012
  • Copper-mediated oxidative direct C-C (hetero)aromatic cross-coupling, Koji Hirano,Masahiro Miura, CHEMICAL COMMUNICATIONS, ROYAL SOC CHEMISTRY, Vol. 48, No. 87, p. 10704-10714, 2012
  • Copper-Catalyzed Amination of Ketene Silyl Acetals with Hydroxylamines: Electrophilic Amination Approach to alpha-Amino Acids, Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 51, No. 47, p. 11827-11831, 2012
  • An Annulative Electrophilic Amination Approach to 3-Aminobenzoheteroles, Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 77, No. 1, p. 617-625, 2012/01
  • Copper-Catalyzed Amination of Arylboronates with N,N-Dialkylhydroxylamines, Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 51, No. 15, p. 3642-3645, 2012
  • Copper-Mediated and Copper-Catalyzed Cross-Coupling of Indoles and 1,3-Azoles: Double C-H Activation, Mayuko Nishino,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 51, No. 28, p. 6993-6997, 2012
  • Synthesis of Isochromene and Related Derivatives by Rhodium-Catalyzed Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes, Keisuke Morimoto,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 76, No. 22, p. 9548-9551, 2011/11
  • Ruthenium-catalyzed Oxidative Alkenylation of Arenes via Regioselective C-H Bond Cleavage Directed by a Nitrogen-containing Group, Yuto Hashimoto,Takumi Ueyama,Tatsuya Fukutani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 40, No. 10, p. 1165-1166, 2011/10
  • A remarkable effect of ionic liquids in transition-metal-free aerobic oxidation of benzylic alcohols, Yoshiro Oda,Koji Hirano,Tetsuya Satoh,Susumu Kuwabata,Masahiro Miura, TETRAHEDRON LETTERS, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 52, No. 41, p. 5392-5394, 2011/10
  • Palladium-catalyzed Direct Monoarylation of Thiophene-, Benzothiophene-, and Indoleacetic Acids through Regioselective C-H Bond Cleavage, Daisuke Takeda,Mana Yamashita,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 40, No. 9, p. 1015-1017, 2011/09
  • Copper-Catalyzed Oxidative Direct Cyclization of N-Methylanilines with Electron-Deficient Alkenes Using Molecular Oxygen, Mayuko Nishino,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 76, No. 15, p. 6447-6451, 2011/08
  • Effect of the Substitution Pattern of Alkyl Side Chain in a Benzodithiophene Core pi-System on Intra and Inter-Molecular Charge Carrier Mobility, Jun Kumagai,Koji Hirano,Tetsuya Satoh,Shu Seki,Masahiro Miura, JOURNAL OF PHYSICAL CHEMISTRY B, AMER CHEMICAL SOC, Vol. 115, No. 26, p. 8446-8452, 2011/07
  • Rhodium-catalyzed Oxidative Coupling of Benzylamines with Alkynes through Dehydrogenation and Dehydrogenative Cyclization, Keisuke Morimoto,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 40, No. 6, p. 600-602, 2011/06
  • Copper-Mediated Annulative Direct Coupling of o-Alkynylphenols with Oxadiazoles: A Dehydrogenative Cascade Construction of Biheteroaryls, Hitoshi Hachiya,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 13, No. 12, p. 3076-3079, 2011/06
  • Copper-Catalyzed Direct Amination of Electron-Deficient Arenes with Hydroxylamines, Naoki Matsuda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 13, No. 11, p. 2860-2863, 2011/06
  • Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group, Satoshi Mochida,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 76, No. 9, p. 3024-3033, 2011/05
  • Copper-Catalyzed Annulative Amination of ortho-Alkynylphenols with Hydroxylamines: Synthesis of 3-Aminobenzofurans by Umpolung Amination Strategy, Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 13, No. 9, p. 2395-2397, 2011/05
  • Synthesis of Highly Substituted Acenes through Rhodium-Catalyzed Oxidative Coupling of Arylboron Reagents with Alkynes, Tatsuya Fukutani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 76, No. 8, p. 2867-2874, 2011/04
  • Synthesis of Enantiomerically Pure P-Stereogenic Diphosphacrowns and Their Palladium Complexes, Yasuhiro Morisaki,Hiroaki Imoto,Koji Hirano,Tamio Hayashi,Yoshiki Chujo, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 76, No. 6, p. 1795-1803, 2011/03
  • C-H Functionalization of Heteroarenes Using First-Row Transition Metals: Copper and Nickel Catalyses, Koji Hirano,Masahiro Miura, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, SOC SYNTHETIC ORGANIC CHEM JPN, Vol. 69, No. 3, p. 252-265, 2011/03
  • Synthesis of 1,4-Diarylbuta-1,3-dienes through Palladium-Catalyzed Decarboxylative Coupling of Unsaturated Carboxylic Acids, Mana Yamashita,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ADVANCED SYNTHESIS & CATALYSIS, WILEY-BLACKWELL, Vol. 353, No. 4, p. 631-636, 2011/03
  • Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C-H Bond Cleavage, Takumi Ueyama,Satoshi Mochida,Tatsuya Fukutani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 13, No. 4, p. 706-708, 2011/02
  • Copper-Mediated Intermolecular Direct Biaryl Coupling, Masanori Kitahara,Nobuyoshi Umeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 133, No. 7, p. 2160-2162, 2011/02
  • Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions, Mitsuru Miyasaka,Koji Hirano,Tetsuya Satoh,Rafal Kowalczyk,Carsten Bolm,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 13, No. 3, p. 359-361, 2011/02
  • Direct Carbon-Hydrogen Bond Functionalization of Heterocyclic Compounds, Koji Hirano,Masahiro Miura, SYNLETT, GEORG THIEME VERLAG KG, No. 3, p. 294-307, 2011/02
  • Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C-H Bonds, Nobuyoshi Umeda,Koji Hirano,Tetsuya Satoh,Naoto Shibata,Hirofumi Sato,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 76, No. 1, p. 13-24, 2011/01
  • Stereospecific Copper-Catalyzed C-H Allylation of Electron-Deficient Arenes with Allyl Phosphates, Tomoyuki Yao,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 50, No. 13, p. 2990-2994, 2011
  • Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups, Tomoyuki Yao,Koji Hirano,Tetsuya Satoh,Masahiro Miura, Angewandte Chemie International Edition, Wiley-Blackwell, Vol. 51, No. 3, 2011
  • Synthesis of Stilbene and Distyrylbenzene Derivatives through Rhodium-Catalyzed Ortho-Olefination and Decarboxylation of Benzoic Acids, Satoshi Mochida,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 12, No. 24, p. 5776-5779, 2010/12
  • Oxidative Nickel-Air Catalysis in C-H Arylation: Direct Cross-Coupling of Azoles with Arylboronic Acids using Air as Sole Oxidant, Hitoshi Hachiya,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMCATCHEM, WILEY-V C H VERLAG GMBH, Vol. 2, No. 11, p. 1403-1406, 2010/11
  • Palladium Nanoparticles in Ionic Liquid by Sputter Deposition as Catalysts for Suzuki-Miyaura Coupling in Water, Yoshiro Oda,Koji Hirano,Kazuki Yoshii,Susumu Kuwabata,Tsukasa Torimoto,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 39, No. 10, p. 1069-1071, 2010/10
  • Palladium-Catalyzed Direct Oxidative Alkenylation of Azoles, Mitsuru Miyasaka,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 75, No. 15, p. 5421-5424, 2010/08
  • Rhodium-catalyzed Oxidative Coupling/Cyclization of Benzamides with Alkynes via C-H Bond Cleavage, Satoshi Mochida,Nobuyoshi Umeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 39, No. 7, p. 744-746, 2010/07
  • Rhodium-Catalyzed Oxidative Coupling/Cyclization of 2-Phenylindoles with Alkynes via C-H and N-H Bond Cleavages with Air as the Oxidant, Keisuke Morimoto,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 12, No. 9, p. 2068-2071, 2010/05
  • A New Entry of Amination Reagents for Heteroaromatic C-H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature, Tsuyoshi Kawano,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 132, No. 20, p. 6900-+, 2010/05
  • Nickel- and Copper-Catalyzed Direct Alkynylation of Azoles and Polyfluoroarenes with Terminal Alkynes under O-2 or Atmospheric Conditions, Naoto Matsuyama,Masanori Kitahara,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 12, No. 10, p. 2358-2361, 2010/05
  • Room Temperature Direct Alkynylation of 1,3,4-Oxadiazoles with Alkynyl Bromides under Copper Catalysis, Tsuyoshi Kawano,Naoto Matsuyama,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 75, No. 5, p. 1764-1766, 2010/03
  • Palladium-Catalyzed Direct Benzylation of Azoles with Benzyl Carbonates, Tomoya Mukai,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 12, No. 6, p. 1360-1363, 2010/03
  • Synthesis of alpha,omega-Diarylbutadienes and -Hexatrienes via Decarboxylative Coupling of Cinnamic Acids with Vinyl Bromides under Palladium Catalysis, Mana Yamashita,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 12, No. 3, p. 592-595, 2010/02
  • Synthesis of Naphtho[1,8-bc]pyran Derivatives and Related Compounds through Hydroxy Group Directed C-H Bond Cleavage under Rhodium Catalysis, Satoshi Mochida,Masaki Shimizu,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY-AN ASIAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 5, No. 4, p. 847-851, 2010
  • Rhodium/Phosphine/Amine center dot HBr Catalyst System for Highly Selective Cross-Cyclodimerization of Aryl- and Alkylalkynes: Efficient Access to Multisubstituted Naphthalene Derivatives, Koichi Sakabe,Hayato Tsurugi,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 16, No. 2, p. 445-449, 2010
  • Synthesis of Substituted Stilbenes via Direct Decarboxylative Coupling of Cinnamic Acids with Arylboronic Acids under Palladium Catalysis, Mana Yamashita,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 39, No. 1, p. 68-69, 2010/01
  • Copper-Mediated Direct Cross-Coupling of 1,3,4-Oxadiazoles and Oxazoles with Terminal Alkynes, Masanori Kitahara,Koji Hirano,Hayato Tsurugi,Tetsuya Satoh,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 16, No. 6, p. 1772-1775, 2010
  • Nickel-Catalyzed Direct C-H Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents, Hitoshi Hachiya,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-BLACKWELL, Vol. 49, No. 12, p. 2202-2205, 2010
  • Palladium- and Nickel-Catalyzed Direct Alkylation of Azoles with Unactivated Alkyl Bromides and Chlorides, Tomoyuki Yao,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 16, No. 41, p. 12307-12311, 2010
  • Synthesis of Highly Substituted Naphthalene and Anthracene Derivatives by Rhodium-Catalyzed Oxidative Coupling of Arylboronic Acids with Alkynes, Tatsuya Fukutani,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 11, No. 22, p. 5198-5201, 2009/11
  • Synthesis of 2,3-Diarylbenzo[b]thiophenes via Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling and Palladium-Catalyzed Decarboxylative Arylation, Mitsuru Miyasaka,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ADVANCED SYNTHESIS & CATALYSIS, WILEY-V C H VERLAG GMBH, Vol. 351, No. 16, p. 2683-2688, 2009/11
  • Fused Ring Construction around Pyrrole, Indole, and Related Compounds via Palladium-Catalyzed Oxidative Coupling with Alkynes, Maria Yamashita,Hakaru Horiguchi,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 74, No. 19, p. 7481-7488, 2009/10
  • Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C-H Bond Cleavage, Nobuyoshi Umeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 74, No. 18, p. 7094-7099, 2009/09
  • Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides, Naoto Matsuyama,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 11, No. 18, p. 4156-4159, 2009/09
  • Synthesis of Functionalized alpha-Pyrone and Butenolide Derivatives by Rhodium-Catalyzed Oxidative Coupling of Substituted Acrylic Acids with Alkynes and Alkenes, Satoshi Mochida,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 74, No. 16, p. 6295-6298, 2009/08
  • Nickel-Catalyzed C-H Alkenylation and Alkylation of 1,3,4-Oxadiazoles with Alkynes and Styrenes, Tomoya Mukai,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 74, No. 16, p. 6410-6413, 2009/08
  • Copper-Catalyzed Arylation of Chlorosilanes with Grignard Reagents, Eiji Morita,Kei Murakami,Masayuki Iwasaki,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, CHEMICAL SOC JAPAN, Vol. 82, No. 8, p. 1012-1014, 2009/08
  • Copper-Mediated Direct Arylation of 1,3,4-Oxadiazoles and 1,2,4-Triazoles with Aryl Iodides, Tsuyoshi Kawano,Tomoki Yoshizumi,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 11, No. 14, p. 3072-3075, 2009/07
  • Synthesis of 2,5-diaryloxazoles through van Leusen reaction and copper-mediated direct arylation, Tomoki Yoshizumi,Tetsuya Satoh,Koji Hirano,Daisuke Matsuo,Akihiro Orita,Junzo Otera,Masahiro Miura, TETRAHEDRON LETTERS, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 50, No. 26, p. 3273-3276, 2009/07
  • Palladium-Catalyzed Three-Component 1:2:1 Coupling of Aryl Iodides, Alkynes, and Alkenes to Produce 1,3,5-Hexatriene Derivatives, Hakaru Horiguchi,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ADVANCED SYNTHESIS & CATALYSIS, WILEY-V C H VERLAG GMBH, Vol. 351, No. 9, p. 1431-1436, 2009/06
  • Synthesis of Condensed Heteroaromatic Compounds by Palladium-Catalyzed Oxidative Coupling of Heteroarene Carboxylic Acids with Alkynes, Mana Yamashita,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 11, No. 11, p. 2337-2340, 2009/06
  • Waste-Free Synthesis of Condensed Heterocyclic Compounds by Rhodium-Catalyzed Oxidative Coupling of Substituted Arene or Heteroarene Carboxylic Acids with Alkynes, Masaki Shimizu,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 74, No. 9, p. 3478-3483, 2009/05
  • Nickel- and Rhodium-Catalyzed Addition of Terminal Silylacetylenes to Propargyl Amines: Catalyst-Dependent Complementary Regioselectivity, Naoto Matsuyama,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 74, No. 9, p. 3576-3578, 2009/05
  • Nickel-Catalyzed Direct Arylation of Azoles with Aryl Bromides, Hitoshi Hachiya,Koji Hirano,Tetsuya Satoh,Masahiro Miura, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 11, No. 8, p. 1737-1740, 2009/04
  • Palladium-Catalyzed 1-Methylene-2-propenylation Reactions of Aryl Bromides with 3,4-Alkadien-1-ols via Carbon-Carbon Bond Cleavage for the Synthesis of 2-Aryl-1,3-butadiene Derivatives, Junichi Imoto,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, CHEMICAL SOC JAPAN, Vol. 82, No. 3, p. 393-400, 2009/03
  • Rhodium-catalyzed and Coordination-assisted Regioselective Alkenylation of Aromatic C-H Bonds with Terminal Silylacetylenes, Takashi Katagiri,Tomoya Mukai,Tetsuya Satoh,Koji Hirano,Masahiro Miura, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 38, No. 2, p. 118-119, 2009/02
  • Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage, Tatsuya Fukutani,Nobuyoshi Umeda,Koji Hirano,Tetsuya Satoh,Masahiro Miura, CHEMICAL COMMUNICATIONS, ROYAL SOC CHEMISTRY, No. 34, p. 5141-5143, 2009
  • Fluorescent Diarylindoles by Palladium-Catalyzed Direct and Decarboxylative Arylations of Carboxyindoles, Mitsuru Miyasaka,Azusa Fukushima,Tetsuya Satoh,Koji Hirano,Masahiro Miura, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 15, No. 15, p. 3674-3677, 2009
  • Nickel-catalyzed carboxylation of organozinc reagent with CO(2), Hidenori Ochiai,Minsul Jang,Koji Hirano,Hideki Yorimitsu,Koichiro Shima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 10, No. 13, p. 2681-2683, 2008/07
  • Palladium-catalyzed formal cycloaddition of silacyclobutanes with enones: Synthesis of eight-membered cyclic silyl enolates, Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 10, No. 11, p. 2199-2201, 2008/06
  • Synthesis of arylallenes by palladium-catalyzed retro-propargylation of homopropargyl alcohols, Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Shima, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 130, No. 15, p. 5048-+, 2008/04
  • Nickel-catalyzed allylation of allyl carbonates with homoallyl alcohols via retro-allylation providing 1,5-hexadienes, Yuto Sumida,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 10, No. 8, p. 1629-1632, 2008/04
  • 1,1-Dimethylsilacyclobutane, Encyclopedia of Reagents for Organic Synthesis, 2008/03
  • Silver-catalyzed transmetalation between chlorosilanes and aryl and alkenyl Grignard reagents for the synthesis of tetraorganosilanes, Kei Murakami,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-BLACKWELL, Vol. 47, No. 31, p. 5833-5835, 2008
  • Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols by retroallylation and isomerization to saturated ketones with conventional or microwave heating, Yuto Sumida,Yuko Takada,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, CHEMISTRY-AN ASIAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 3, No. 1, p. 119-125, 2008
  • Nickel-catalysed reactions with trialkylboranes and silacyclobutanes, Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, CHEMICAL COMMUNICATIONS, ROYAL SOC CHEMISTRY, No. 28, p. 3234-3241, 2008
  • Nickel-catalyzed beta-boration of alpha,beta-unsaturated esters and amides with bis(pinacolato)diboron, Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 9, No. 24, p. 5031-5033, 2007/11
  • Synthesis of (Arylal kenyl)si lanes by palladium-catalyzed regiospecific and stereoselective allyl transfer from silyl-substituted homoallyl alcohols to aryl halides, Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 129, No. 42, p. 12650-+, 2007/10
  • Microwave-assisted palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation, Masayuki Iwasaki,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, TETRAHEDRON, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 63, No. 24, p. 5200-5203, 2007/06
  • Rhodium-catalyzed allyl transfer from homoallyl alcohols to acrylate esters via retro-allylation, Minsul Jang,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, TETRAHEDRON LETTERS, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 48, No. 23, p. 4003-4005, 2007/06
  • Nickel-catalyzed regio- and stereoselective silylation of terminal alkenes with silacyclobutanes: Facile access to vinylsilanes from alkenes, Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 129, No. 19, p. 6094-+, 2007/05
  • Pd(OAc)(2)/P((C6H11)-C-c)(3)-Catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation, Masayuki Iwasaki,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 129, No. 14, p. 4463-4469, 2007/04
  • Nickel-catalyzed 1,4-addition of trialkylboranes to alpha,beta-unsaturated esters: Dramatic enhancement by addition of methanol, Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 9, No. 8, p. 1541-1544, 2007/04
  • CCDC 265711: Experimental Crystal Structure Determination, Hayashi S,Hirano K,Yorimitsu H,Oshima K, Cambridge Structural Database, 2007
  • Gallium-mediated allyl transfer from bulky homoallyl alcohol to aldehydes or alkynes: Control of dynamic sigma-allylgalliums based on retro-allylation reaction, Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER SCIENCE SA, Vol. 692, No. 1-3, p. 505-513, 2007/01
  • Alkylation of aldehydes with trialkylboranes in water, Koji Hirano,Hideki Yorimitsu,Koichiro Shima, ADVANCED SYNTHESIS & CATALYSIS, WILEY-V C H VERLAG GMBH, Vol. 348, No. 12-13, p. 1543-1546, 2006/08
  • Rhodium-catalyzed allyl transfer from homoallyl alcohols to aldehydes via retro-allylation followed by isomerization into ketones, Yuko Takada,Sayuri Hayashi,Koji Hirano,Hideki Yorimitsu,Koichiro Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 8, No. 12, p. 2515-2517, 2006/06
  • Current topics on synthetic reactions with azido compounds, K Hirano, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, SOC SYNTHETIC ORGANIC CHEM JPN, Vol. 64, No. 4, p. 416-417, 2006/04
  • Palladium-catalyzed stereo- and regiospecific allylation of aryl halides with homoallyl alcohols via retro-allylation: Selective generation and use of sigma-allylpalladium, S Hayashi,K Hirano,H Yorimitsu,K Oshima, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 128, No. 7, p. 2210-2211, 2006/02
  • Nickel-catalyzed reactions of silacyclobutanes with aldehydes: Ring opening and ring expansion reaction, K Hirano,H Yorimitsu,K Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 8, No. 3, p. 483-485, 2006/02
  • Nickel-catalyzed alkylation of aldehydes with trialkylboranes, K Hirano,H Yorimitsu,K Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 7, No. 21, p. 4689-4691, 2005/10
  • Gallium-mediated allyl transfer from bulky homoallylic alcohol to aldehydes via retro-allylation: Stereoselective synthesis of both erythro- and threo-homoallylic alcohols, S Hayashi,K Hirano,H Yorimitsu,K Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 7, No. 16, p. 3577-3579, 2005/08
  • Nickel-catalyzed cross-coupling reaction of aryl halides with allylic zirconium reagents generated in situ from zirconocene(alkene) complexes, K Hirano,K Fujita,H Yorimitsu,K Oshima, SYNLETT, GEORG THIEME VERLAG KG, No. 11, p. 1787-1788, 2005/07
  • Boron trifluoride-mediated alkylation of diphenylphosphine with tert-alkyl fluoride, K Hirano,H Yorimitsu,K Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 6, No. 26, p. 4873-4875, 2004/12
  • Boron trifluoride-catalyzed reaction of alkyl fluoride with silyl enolate, allylsilane, and hydrosilane, Koji Hirano,Kazuya Fujita,Hideki Yorimitsu,Hiroshi Shinokubo,Koichiro Oshima, Tetrahedron Letters, Elsevier {BV}, Vol. 45, No. 12, p. 2555-2557, 2004/03/15
  • Triethylborane-induced radical allylation reaction with zirconocene-olefin complex, K Hirano,K Fujita,H Shinokubo,K Oshima, ORGANIC LETTERS, AMER CHEMICAL SOC, Vol. 6, No. 4, p. 593-595, 2004/02

Misc.

  • Correction to Iridium-Catalyzed Annulative Coupling of 2-Arylbenzoyl Chlorides with Alkynes: Selective Formation of Phenanthrene Derivatives (vol 79, 8960, 2014), Tomoya Nagata,Koji Hirano,Tetsuya Satoh,Masahiro Miura, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 79, No. 24, p. 12205-12205, 2014/12
  • パラジウム触媒による3,4‐アルカジエノールとハロゲン化アリールの反応, IMOTO JUN'ICHI,HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 88th, No. 2, 2008/03/12
  • ニッケル触媒によるレトロアリル化を利用した1,5‐ヘキサジエンの合成, SUMIDA YUTO,HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 88th, No. 2, 2008/03/12
  • ニッケル触媒による有機亜鉛反応剤と二酸化炭素の反応, OCHIAI HIDENORI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 88th, No. 2, 2008/03/12
  • 銀触媒によるクロロシランとグリニャール反応剤の交差カップリング反応, MURAKAMI KEI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 88th, No. 2, 2008/03/12
  • パラジウム触媒による第三級ホモプロパルギルアルコールのレトロプロパルギル化を利用したアリールアレンの合成, HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 88th, No. 2, 2008/03/12
  • ロジウム触媒によるレトロアリル化を利用したホモアリルアルコールから活性オレフィンへのアリル基移動反応, JANG MINSUL,HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 87th, No. 2, 2007/03/12
  • パラジウム触媒による第三級ホモアリルアルコールのレトロアリル化を利用したアリルシランおよびビニルシランの合成, HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 87th, No. 2, 2007/03/12
  • マイクロ波照射下パラジウム触媒によるホモアリルアルコールのレトロアリル化を利用したハロゲン化アリールのアリル化反応, IWASAKI MASAYUKI,HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 87th, No. 2, 2007/03/12
  • ニッケル触媒を用いたアルケンとトリアルキルボランならびにシラシクロブタンの反応, HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 87th, No. 2, 2007/03/12
  • Nickel-catalyzed reactions of aldehydes with trialkylboranes or silacyclobutanes, HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 86th, No. 2, 2006/03/13
  • Rhodium-catalyzed retro-allylation of homoallylic alcohols and its application to organic synthesis, TAKADA YUKO,HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 86th, No. 2, 2006/03/13
  • Palladium-Catalyzed Stereo- and Regioselective Allylation of Aryl Halides with Homoallyl Alcohols via Retro-Allylation, HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 86th, No. 2, 2006/03/13
  • Boron Trifluoride-mediated Alkylation of Diphenylphosphine with tert-Alkyl Fluoride, HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 85th, No. 2, 2005/03/11
  • Preparation of allylic gallium reagents via carbon-carbon bond cleavage and its application to organic synthesis, HAYASHI SAYURI,HIRANO KOJI,YORIMITSU HIDEKI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 85th, No. 2, 2005/03/11
  • Lewis Acid-Promoted C-F Bond Activation and Its Application to C-C Bond Formation Reaction, HIRANO KOJI,FUJITA KAZUYA,YORIMITSU HIDEKI,SHINOBUKUBO HIROSHI,OSHIMA KOICHIRO, 日本化学会講演予稿集, Vol. 84th, No. 2, 2004/03/11

Publications

  • Remote C-H Bond Functionalizations. Methods and Strategies in Organic Synthesis, Maiti, Debabrata,Guin, Srimanta, Wiley-VCH, Weinheim, 2021/02
  • 直接的芳香族カップリング反応の設計と応用, シーエムシー出版, ISBN:9784781314211, 2019/05
  • Sustainable catalysis : challenges and practices for the pharmaceutical and fine chemical industries, Dunn, Peter J. (Peter James),Hii, K. K.,Krische, Michael J.,Williams, Michael T. (Michael Trevelyan), John Wiley & Sons, ISBN:9781118155424

Awards

  • Merck Banyu Lectureship Award (MBLA) 2019, Hirano Koji, MSD Life Science Foundation, Public Interest Incorporated Foundation, 2020/02
  • Thieme Chemistry Journals Award 2020, Hirano Koji, Georg Thieme Verlag KG, 2020/01
  • 大阪大学賞, 2019/11
  • Chemist Award BCA 2019, Hirano Koji, MSD Life Science Foundation, Public Interest Incorporated Foundation, 2019/10
  • The Commendation for Science and Technology by MEXT, The Young Scientists' Prize, Hirano Koji, The Minister of Education, Culture, Sports, Science and Technology, 2017/04
  • 文部科学大臣表彰 若手科学者賞, 2017/04
  • 2016 The Chemical Society of Japan Award For Young Chemists, Hirano Koji, The Chemical Society of Japan, 2016/03
  • 日本化学会 第65回進歩賞, 2016/03
  • 大阪大学総長奨励賞(研究部門), 2014/07
  • 13th GSC Award by the Minister of Education, Culture, Sports, Science and Technology, Hirano Koji, The Japan Association for Chemical Innovation (JACI), 2014/05
  • グリーン・サステイナブル ケミストリー賞 文部科学大臣賞, 2014/05
  • 若い世代の特別講演会, 2013/03
  • 有機合成化学協会研究企画賞, 2012/02

Presentations

  • 有機合成化学研究の醍醐味, 2020/10
  • 極性転換の拡張に基づく新規結合形成手法の開拓(MBLA受賞講演), 2020/10
  • Synthesis of Benzophospholes with Phosphenium Cations of Unique Reactivity, Koji Hirano, 27th International Society of Heterocyclic Chemistry Congress (27th ISHC), 2019/09
  • Copper-Catalyzed Regioselective C-H Amination of Phenol Derivatives with Assistance of Phenanthroline-Based Bidentate Auxiliary, Koji Hirano, 20th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS20), 2019/07
  • 極性転換が拓く新規炭素ーヘテロ元素結合形成, 2019/03
  • Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary Benzyl Carbonates, Koji Hirano, The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14), 2018/11
  • Phosphination of Alkenes and Alkynes with Phosphinyl Radicals and Phosphenium Cations of Unique Reactivity, Koji Hirano, International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS), 2018/08
  • Phosphination of Alkenes and Alkynes with Phosphinyl Radicals and Phosphenium Cations of Unique Reactivity, Koji Hirano, Biotechnology and Chemistry for Green Growth, 2018/03
  • 極性転換が拓く新規触媒的炭素−窒素結合形成, 2017/10
  • Catalytic vic-Diphosphination of Terminal Alkenes with Silylphosphine, Koji Hirano, INTERNATIONAL SYMPOSIUM ON PURE & APPLIED CHEMISTRY (ISPAC) 2017, 2017/06
  • 銅触媒を用いた窒素およびリン元素導入を伴うアルケンの新規二官能基化反応の開発, 2016/11
  • 銅触媒を用いた求電子的アミノ化:”マイナス”を”プラス”にしたら何ができるのか?, 2016/08
  • 求電子的アミノ化を鍵とする新規触媒的炭素-窒素結合形成反応の開発, 2016/03
  • Metal-Promoted Site-Selective C–H Functionalization of 2-Pyridones, Koji Hirano, The 13th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-13), 2015/11
  • Development of New C-N Bond Formations via Copper-Catalyzed Electrophilic Amination, 2015/10
  • Regiodivergent Copper-Catalzyed Aminoboration of Unactivated Terminal Alkenes, Koji Hirano, Organic Chemistry Symposium, Royal Society of Chemistry Roadshow, 2015/06
  • Copper-Catalyzed Regio- and Stereoselective Aminoboration and Hydroamination of Alkenes with Electrophilic Amination Reagents, Koji Hirano, International Conference on Organometallic Chemistry (ICOMC) 2014 Post-Symposium in Osaka, 2014/07
  • 求電子的アミノ化を鍵とする新規触媒的炭素―窒素結合形成反応の開発, 2013/12
  • Copper-Catalyzed Aminoboration of Alkenes with Bis(pinacolato)diboron and Hydroxylamines, Koji Hirano, 10th International Symposium on Carbanion Chemistry (ISCC10), 2013/09
  • Copper-Catalyzed Aminoboration of Alkenes with Bis(pinacolato)diboron and Hydroxylamines, Koji Hirano, 17th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS17), 2013/07
  • 求電子的アミノ化試薬を活用する新規触媒的炭素―窒素結合形成反応の開発, 2013/03
  • Copper-catalyzed electrophilic amination: an umpolung strategy for C-N bond formations, Koji Hirano, Biotechnology & Chemistry for Green Growth, 2013/03
  • 第一遷移元素を活用する直接的ヘテロビアリールカップリング法の開発, 2013/03
  • 求電子的アミノ化試薬を活用する新規触媒的炭素̶―窒素結合形成反応の開発, 2013/03
  • 第一遷移元素を活用するヘテロアレーン類の炭素̶―水素結合直接変換反応の開発, 2010/03