顔写真

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Yuya Kakiuchi
垣内 勇哉
Yuya Kakiuchi
垣内 勇哉
Graduate School of Engineering　Center for Future Innovation，Assistant Professor

keyword Coordination Chemistry，Computational Chemisitry，Surface Chemistry，Catalysis，Solid-state NMR，Spectroscopy，Organometallic chemistry

Research History 1

  1. 2025/07 - Present
    The University of Osaka　Graduate School of Engineering　Assistant Professor

Education 4

  1. ETH Zurich　Department of Chemistry and Applied Biosciences

    2021/02 - 2025/06

  2. The University of Osaka　Graduate School of Engineering Science

    2020/10 - 2021/01

  3. The University of Osaka　Graduate School of Engineering Science

    2019/04 - 2020/09

  4. The University of Osaka　School of Engineering Science

    2015/04 - 2019/03

Research Areas 3

  1. Nanotechnology/Materials / Analytical chemistry /

  2. Nanotechnology/Materials / Synthetic organic chemistry /

  3. Nanotechnology/Materials / Inorganic and coordination chemistry /

Papers 19

  1. NMR Signatures of Transition-Metal Nuclei: From Local Environments and Electronic Structures to Reactivity Descriptors in Molecular and Heterogeneous Catalysis

    Zachariah J. Berkson, Weicheng Cao, Domenico Gioffrè, Christoph J. Kaul, Lukas Lätsch, Yuya Kakiuchi, Alexander Yakimov, Christophe Copéret

    JACS Au　2025/07/28　Research paper (scientific journal)

  2. 13C Chemical Shift of N-Heterocyclic Carbenes in Coinage Metal(I) Complexes and Clusters: trans-Influence and Spin–Orbit Coupling

    Shahar Dery, Christian Ehinger, Jeremy Roudin, Yuya Kakiuchi, Domenico Gioffrè, Christophe Copéret

    Journal of the American Chemical Society　2025/05/28　Research paper (scientific journal)

  3. Branch-Selective Olefin Hydroaminoalkylation from Ti(III)–Al Bimetallic Intermediates Evidenced by EPR Hyperfine Spectroscopy and DFT Calculations

    Mariko Inoue, Julian Stropp, Anton Ashuiev, Yuya Kakiuchi, Pierre-Adrien Payard, Tokiya Teraishi, Mai Mizukami, Hayato Tsurugi, Daniel Klose, Christophe Copéret, Kazushi Mashima

    Journal of the American Chemical Society　2025/05/14　Research paper (scientific journal)

  4. Correction to “Fingerprint Analysis of X-ray Absorption Spectra with the Machine-Learning Method Trained on the Multielement Experimental Library”

    B. O. Protsenko, Y. Kakiuchi, S. A. Guda, D. Trummer, A. Zabilska, S. Shapovalova, A. V. Soldatov, O. V. Safonova, C. Copéret, A. A. Guda

    The Journal of Physical Chemistry C　2025/04/03　Research paper (scientific journal)

  5. Ti-catalyzed 1,2-Diamination of Alkynes Using 1,1-Disubstituted Hydrazines

    Partha Sarathi Karmakar, Yuya Kakiuchi, Jaekwan Kim, Michael R. Harris, Daniel N. Huh, Alexander G. Sell, Christophe Copéret, Ian A. Tonks

    Journal of the American Chemical Society　2025/04/02　Research paper (scientific journal)

  6. Fingerprint Analysis of X-ray Absorption Spectra with the Machine-Learning Method Trained on the Multielement Experimental Library

    B. O. Protsenko, Y. Kakiuchi, S. A. Guda, D. Trummer, A. Zabilska, S. Shapovalova, A. V. Soldatov, O. V. Safonova, C. Copéret, A. A. Guda

    The Journal of Physical Chemistry C　2025/02/06　Research paper (scientific journal)

  7. Electronic Structures of Late versus Early Transition Metal Imido Complexes from 15N NMR Signatures

    Yuya Kakiuchi, Christophe Copéret

    2024/10/24

  8. Electronic Structures of Late versus Early Transition Metal Imido Complexes from 15N NMR Signatures

    Yuya Kakiuchi, Christophe Copéret

    2024/09/25

  9. Origin of Reactivity Trends of an Elusive Metathesis Intermediate from NMR Chemical Shift Analysis of Surrogate Analogs

    Yuya Kakiuchi, Scott R. Docherty, Zachariah J. Berkson, Alexander V. Yakimov, Michael Wörle, Christophe Copéret, Sadig Aghazada

    Journal of the American Chemical Society　2024/04/15　Research paper (scientific journal)

  10. Bonding and Reactivity of d0 Transition Metal Imido Complexes Encoded in Their 15N NMR Signatures

    Yuya Kakiuchi, Partha Sarathi Karmakar, Jérémy Roudin, Ian A. Tonks, Christophe Copéret

    Journal of the American Chemical Society　2024/04/10　Research paper (scientific journal)

  11. Well-Defined Ti Surface Sites in Ziegler–Natta Pre-Catalysts from 47/49Ti Solid-State Nuclear Magnetic Resonance Spectroscopy

    Alexander V. Yakimov, Christoph J. Kaul, Yuya Kakiuchi, Sebastian Sabisch, Felipe Morais Bolner, Jean Raynaud, Vincent Monteil, Pierrick Berruyer, Christophe Copéret

    The Journal of Physical Chemistry Letters　2024/03/21　Research paper (scientific journal)

  12. Bonding and Reactivity of d0 Transition Metal Imido Complexes Encoded in their 15N NMR Signatures

    Yuya Kakiuchi, Partha S. Karmakar, Jérémy Roudin, Ian A. Tonks, Christophe Copéret

    2024/03/04

  13. Evaluation of Tungsten Catalysis among Early Transition Metals for N-Aryl-2,3,4,5-tetraarylpyrrole Synthesis: Modular Access to N-Doped π-Conjugated Material Precursors

    Hayato Tsurugi, Takuya Akiyama, Connor W. Frye, Yuya Kakiuchi, Kazushi Mashima, Ian A. Tonks

    Inorganic Chemistry　2024/02/12　Research paper (scientific journal)

  14. Reactivity of Transition Metal Imido Complexes Encoded in their 15N NMR Signatures

    Yuya Kakiuchi, Partha S. Karmakar, Jérémy Roudin, Ian A. Tonks, Christophe Copéret

    2023/12/27

  15. Geometry and Local Environment of Surface Sites in Vanadium-Based Ziegler–Natta Catalysts from 51V Solid-State NMR Spectroscopy

    Sebastian Sabisch, Yuya Kakiuchi, Scott R. Docherty, Alexander V. Yakimov, Christophe Copéret

    Journal of the American Chemical Society　2023/11/29　Research paper (scientific journal)

  16. Influence of Strong pi-Acceptor Ligands on Cr-K-edge X-Ray Absorption Spectral Signatures and Consequences on Interpretation of Surface Sites in the Phillips Catalyst

    Yuya Kakiuchi, Svetlana Shapovalova, Bogdan Protsenko, Sergey Guda, Olga V. Safonova, Alexander Guda, Christophe Copéret

    2023/08/08

  17. Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules

    Kawakita, K., Parker, B.F., Kakiuchi, Y., Tsurugi, H., Mashima, K., Arnold, J., Tonks, I.A.

    Coordination Chemistry Reviews　Vol. 407　2020　Research paper (scientific journal)

  18. Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the N-N Bond of 2,2′-Azopyridine: Precursors for Early-Late Heterobimetallic Complexes

    Kawakita, K., Kakiuchi, Y., Beaumier, E.P., Tonks, I.A., Tsurugi, H., Mashima, K.

    Inorganic Chemistry　Vol. 58　No. 22　2019　Research paper (scientific journal)

  19. Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles

    Kawakita, K., Beaumier, E.P., Kakiuchi, Y., Tsurugi, H., Tonks, I.A., Mashima, K.

    Journal of the American Chemical Society　Vol. 141　No. 10　2019　Research paper (scientific journal)