EN

基本情報

研究

社会活動

その他の活動

福本 能也

Fukumoto Yoshiya

工学研究科 応用化学専攻,准教授

keyword 均一系触媒反応

学歴

  • ~ 1995年,大阪大学,工学研究科,応用精密化学
  • ~ 1990年,大阪大学,工学部,応用精密化学

経歴

  • 1995年 ~ 2004年,大阪大学 大学院工学研究科 助手
  • 2004年 ~ ,- 大阪大学 大学院工学研究科 講師

研究内容・専門分野

  • ナノテク・材料,有機合成化学

所属学会

  • 近畿化学協会
  • 有機合成化学協会
  • 日本化学会

論文

  • Co<sub>2</sub>(CO)<sub>8</sub>-Catalyzed Reactions of Acetals or Lactones with Hydrosilanes and Carbon Monoxide. A New Access to the Preparation of 1,2-Diol Derivatives through Siloxymethylation,Vol. 94,No. 1,p. 81-90,2021年01月,研究論文(学術雑誌)
  • Ru<sub>3</sub>(CO)<sub>12</sub>-Catalyzed Reaction of 1,6-Diynes, Carbon Monoxide, and Water via the Reductive Coupling of Carbon Monoxide,Vol. 22,No. 22,p. 8747-8751,2020年11月,研究論文(学術雑誌)
  • Rhodium-catalyzed Reaction of Alkynes with Hydrosilanes and <i>n</i>-Octyl Isocyanide: A Silylimination/1,4-Hydrosilylation Sequence Leading to β-Silylmethyl-<i>N</i>-silylenamines,Yoshiya Fukumoto,Yuta Seo,Hiroto Shimizu,Hiroki Enomoto,Naoto Chatani,Chemistry Letters,Vol. 49,No. 3,p. 357-360,2020年04月
  • Chapter 6: Transition‐Metal‐Catalyzed C-H Bond Silylation,Yoshiya Fukumoto,Naoto Chatani,Organosilicon Chemistry: Novel Approaches and Reactions,p. 171-212,2019年12月
  • A New Class of Redox Isomerization of <i>N</i>-Alkylpropargylamines into <i>N</i>-Alkylideneallylamines Catalyzed by a ReBr(CO)<sub>5</sub>/Amine <i>N</i>-oxide System,Yoshiya Fukumoto,Natsuki Okazaki,Naoto Chatani,Organic Letters,Vol. 21,No. 6,p. 1760-1765,2019年03月
  • A Cationic Iridium-Catalyzed C(sp<sup>3</sup>)-H Silylation of 2-Alkyl-1,3-azoles at the α-Position in the 2-Alkyl Group Leading to 2-(1-Silylalkyl)-1,3-azoles,Masaya Hirano,Yoshiya Fukumoto,Nao Matsubara,Naoto Chatani,Chemistry Letters,Vol. 47,No. 3,p. 385-388,2018年03月,研究論文(学術雑誌)
  • Ir<sub>4</sub>(CO)<sub>12</sub>-Catalyzed Benzylic C(sp<sup>3</sup>)-H Silylation of 2-Alkylpyridines with Hydrosilanes Leading to 2-(1-Silylalkyl)pyridines,Vol. 82,No. 24,p. 13649-13655,2017年12月15日,研究論文(学術雑誌)
  • An unusual endo-selective C-H hydroarylation of norbornene by the Rh(I)-catalyzed reaction of benzamides,Vol. 8,No. 1,p. 1448-1455,2017年11月,研究論文(学術雑誌)
  • Iridium-Catalyzed Regioselective C(sp<sup>3</sup>)-H Silylation of 4-Alkylpyridines at the Benzylic Position with Hydrosilanes Leading to 4-(1-Silylalkyl)pyridines,Vol. 7,No. 5,p. 3152-3156,2017年05月05日,研究論文(学術雑誌)
  • Direct and Regioselective Introduction of Acetals into Imidazoles at the 2-Position by an Iridium-Catalyzed Reaction with Formates in the Presence of Hydrosilanes,Vol. 2017,No. 12,p. 1662-1665,2017年,研究論文(学術雑誌)
  • Conversion of 3,3,3-Trisubstituted Prop-1-ynes with <i>tert</i>-Butylhydrazine into 3,3,3-Trisubstituted Propionitriles Catalyzed by TpRh(C<sub>2</sub>H<sub>4</sub>)<sub>2</sub>/P(2-furyl)<sub>3</sub>,Vol. 81,No. 8,p. 3161-3167,2016年04月,研究論文(学術雑誌)
  • Ni(II)-Catalyzed Oxidative Coupling between C(sp(2))-H in Benzamides and C(sp(3))-H in Toluene Derivatives,Vol. 136,No. 44,p. 15509-15512,2014年11月,研究論文(学術雑誌)
  • Synthesis of α-Silylmethyl-α,β-Unsaturated Imines by the Rhodium-Catalyzed Silylimination of Primary-Alkyl-Substituted Terminal Alkynes,Yoshiya Fukumoto,Hiroto Shimizu,Aya Tashiro,Naoto Chatani,Journal of Organic Chemistry,Vol. 79,No. 17,p. 8221-8227,2014年09月,研究論文(学術雑誌)
  • Rhenium(I)-catalyzed reaction of terminal alkynes with imines leading to allylamine derivatives,Vol. 86,No. 3,p. 283-289,2014年03月,研究論文(学術雑誌)
  • Ruthenium-catalyzed cyclocarbonylation of aliphatic amides through the regioselective activation of unactivated C(sp(3))-H bonds,Vol. 69,No. 22,p. 4466-4472,2013年06月,研究論文(学術雑誌)
  • Rhodium-catalyzed anti-markovnikov hydrohydrazination of terminal alkynes with n-alkyl- and N,N-dialkylhydrazines,Vol. 2,No. 12,p. 1036-1039,2013年,研究論文(学術雑誌)
  • Ruthenium Dodecacarbonyl Triangulo,Naoto Chatani,Yoshiya Fukumoto,Handbook of Reagents for Organic Synthesis: Catalytic Oxidation Reagents,p. 565-568,2013年
  • Skeletal reorganization of enynes catalyzed by a Ru(2)Ru(3) mixed-valence complex under an atmosphere of O2 or CO,Vol. 42,No. 12,p. 1565-1567,2013年,研究論文(学術雑誌)
  • Ruthenium-Catalyzed Carbonylation of ortho C-H Bonds in Arylacetamides: C-H Bond Activation Utilizing a Bidentate-Chelation System,Vol. 4,No. 11,p. 1733-1736,2012年11月,研究論文(学術雑誌)
  • Rhenium-Catalyzed Regio- and Stereoselective Addition of Imines to Terminal Alkynes Leading to N-Alkylideneallylamines,Vol. 134,No. 21,p. 8762-8765,2012年05月,研究論文(学術雑誌)
  • Nickel-Catalyzed Chelation-Assisted Transformations Involving <i>ortho</i> C-H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes,Kaname Shibata,Nao Hasegawa,Yoshiya Fukumoto,Naoto Chatani,Journal of the American Chemical Society,Vol. 133,No. 38,p. 14952-14955,2012年
  • Switch in Stereoselectivity Caused by the Isocyanide Structure in the Rhodium-Catalyzed Silylimination of Alkynes,Vol. 133,No. 26,p. 10014-10017,2011年07月,研究論文(学術雑誌)
  • Highly Regioselective Carbonylation of Unactivated C(sp(3))-H Bonds by Ruthenium Carbonyl,Vol. 133,No. 21,p. 8070-8073,2011年06月,研究論文(学術雑誌)
  • Chelation-assisted carbonylation reactions catalyzed by Rh and Ru complexes,Vol. 82,No. 7,p. 1443-1451,2010年07月,研究論文(学術雑誌)
  • Nickel-Catalyzed Cyclization of Difluoro-Substituted 1,6-Enynes with Organozinc Reagents through the Stereoselective Activation of C-F Bonds: Synthesis of Bicyclo[3.2.0]heptene Derivatives,Vol. 49,No. 46,p. 8717-8720,2010年,研究論文(学術雑誌)
  • Synthesis of [RhCl(CO)(cyclopentadienone)](2) from [RhCl(cod)](2) and a 1,6-diyne under CO: application to Rh(I)-catalyzed tandem [2+2+1] carbonylative cycloaddition of diynes and Claisen rearrangement,Vol. 46,No. 19,p. 3345-3347,2010年,研究論文(学術雑誌)
  • Synthesis of (E)-3-Alkylidene-1-pyrrolines by the Rhodium-Catalyzed Cyclization of Terminal Alkynes with Homopropargylic Amines,Vol. 351,No. 14-15,p. 2315-2318,2009年10月,研究論文(学術雑誌)
  • Catalytic Hydroamination of C-C Multiple Bonds,Vol. 67,No. 7,p. 735-750,2009年07月
  • Ruthenium-Catalyzed Carbonylation at Ortho C-H Bonds in Aromatic Amides Leading to Phthalimides: C-H Bond Activation Utilizing a Bidentate System,Vol. 131,No. 20,p. 6898-+,2009年05月,研究論文(学術雑誌)
  • Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde,Vol. 11,No. 8,p. 1777-1780,2009年04月,研究論文(学術雑誌)
  • 炭素-炭素多重結合への触媒的ヒドロアミノ化,福本能也,有機合成化学協会誌,Vol. 67,No. 7,p. 735-750,2009年
  • Anti-markovnikov addition of both primary and secondary Amines to terminal Alkynes catalyzed by the TpRh(C(2)H(4))(2)/PPh(3) system,Vol. 129,No. 45,p. 13792-+,2007年11月,研究論文(学術雑誌)
  • A chelation-assisted transformation: Synthesis of maleimides by the Rh-catalyzed carbonylation of alkynes with pyridin-2-ylmethylamine,Vol. 72,No. 17,p. 6588-6590,2007年08月,研究論文(学術雑誌)
  • Rh(I)-catalyzed carbonylative cyclization reactions of alkynes with 2-bromophenylboronic acids leading to indenones,Vol. 129,No. 17,p. 5766-5771,2007年05月,研究論文(学術雑誌)
  • Rhodium(III) Chloride,Jeffrey A. McKinney,Yoshiya Fukumoto,Naoto Chatani,Encyclopedia of Reagents for Organic Synthesis,p. 1-3,2007年
  • Rhodium-catalyzed reaction of terminal alkynes with allylamine leading to (E)-3-alkylidene N-heterocycles,Vol. 8,No. 20,p. 4641-4643,2006年09月,研究論文(学術雑誌)
  • Chelation-assisted transformation: Synthesis of 1,4-dicarboxylate esters by the Rh-catalyzed carbonylation of internal alkynes with pyridin-2-ylmethanol,Vol. 8,No. 12,p. 2519-2522,2006年06月,研究論文(学術雑誌)
  • A new synthesis of aldehydes by the palladium-catalyzed reaction of 2-pyridinyl esters with hydrosilanes,No. 6,p. 869-872,2006年04月,研究論文(学術雑誌)
  • Palladium-Catalyzed Carbonylation of Yne-Esters Leading to γ-Alkylidene α,β-Unsaturated γ-Lactones,Yasuyuki Harada,Yoshiya Fukumoto,Naoto Chatani,Organic Letters,Vol. 7,No. 20,p. 4385-4387,2005年09月,研究論文(学術雑誌)
  • Ruthenium Dodecacarbonyl Triangulo (revised),Yoshiya Fukumoto,Naoto Chatani,Encyclopedia of Reagents for Organic Synthesis,p. 1-3,2005年
  • Chelation-assisted hydroesterification of alkenes catalyzed by rhodium complex,Vol. 5,No. 23,p. 4329-4331,2003年11月,研究論文(学術雑誌)
  • Ruthenium-Catalyzed Carbonylative Cycloaddition of α-Keto Lactones with Alkenes or Alkynes: The Paticipation of an Ester-Carbonyl Group in Cycloaddition Reactions as the Two-Atom Assembling Unit,Naoto Chatani,Katsuya Amako,Mamoru Tobisu,Taku Asaumi,Yoshiya Fukumoto,Shinji Murai,The Journal of Organic Chemistry,Vol. 68,No. 4,p. 1591-1593,2003年02月,研究論文(学術雑誌)
  • Ta触媒によるエチレン三量化の理論的研究,福本能也,Organometallic News,Vol. 26,No. 2,p. 56-56,2003年
  • Reaction of terminal Alkynes with hydrazines to give nitriles, catalyzed by TpRuCl(PPh3)(2): Novel catalytic transformation involving a vinylidene ruthenium,Vol. 21,No. 19,p. 3845-3847,2002年09月,研究論文(学術雑誌)
  • [Ir-4(CO)(12)]-catalyzed coupling reaction of imidazoles with aldehydes in the presence of a hydrosilane to give 2-substituted imidazoles,Vol. 41,No. 15,p. 2779-+,2002年,研究論文(学術雑誌)
  • Catalytic carbonylation reactions of benzyne derivatives,Vol. 123,No. 50,p. 12686-12687,2001年12月,研究論文(学術雑誌)
  • Ruthenium Dodecacarbonyl Triangulo,Yoshiya Fukumoto,Naoto Chatani,Encyclopedia of Reagents for Organic Synthesis,p. 1-2,2001年
  • Ru<sub>3</sub>(CO)<sub>12</sub>-Catalyzed Intermolecular Cyclocoupling of Ketones, Alkenes or Alkynes, and Carbon Monoxide. [2+2+1] Cycloaddition Strategy for the Synthesis of Functionalized γ-Butyrolactones,Mamoru Tobisu,Naoto Chatani,Taku Asaumi,Katsuya Amako,Yutaka Ie,Yoshiya Fukumoto,Shinji Murai,Journal of the American Chemical Society,Vol. 122,No. 51,p. 12663-12674,2000年12月,研究論文(学術雑誌)
  • Platinum and Palladium Complex-Catalyzed Regioselective Nucleophilic Substitutions with Two Different Nucleophiles at the Central and Terminal Carbon Atoms of the π-Allyl Ligand,Joji Kadota,Hidefusa Katsuragi,Yoshiya Fukumoto,Shinji Murai,Organometallics,Vol. 19,No. 6,p. 979-983,2000年03月,研究論文(学術雑誌)
  • A New Platinum Complex Catalyzed Reaction Involving Nucleophilic Substitution at the Central Carbon Atom of the π-Allyl Ligand,Joji Kadota,Shinji Komori,Yoshiya Fukumoto,Shinji Murai,The Journal of Organic Chemistry,Vol. 64,No. 20,p. 7523-7527,1999年10月,研究論文(学術雑誌)
  • Ruthenium Carbonyl-Catalyzed [2+2+1]-Cycloaddition of Ketones, Olefins, and Carbon Monoxide, Leading to Functionalized γ-Butyrolactones,Naoto Chatani,Mamoru Tobisu,Taku Asaumi,Yoshiya Fukumoto,Shinji Murai,Journal of the American Chemical Society,Vol. 121,No. 30,p. 7160-7161,1999年08月,研究論文(学術雑誌)
  • Ru<sub>3</sub>(CO)<sub>12</sub>-Catalyzed Reaction of Yne-Imines with Carbon Nonoxide Leading to Bicyclic α,β-Unsaturated Lactams,Naoto Chatani,Tsumoru Morimoto,Akihito Kamitani,Yoshiya Fukumoto,Shinji Murai,Journal of Organometallic Chemistry,Vol. 579,No. 1-2,p. 177-181,1999年05月,研究論文(学術雑誌)
  • Ru<sub>3</sub>(CO)<sub>12</sub>-Catalyzed Cyclocarbonylation of Yne-Aldehydes to Bicyclic α, β-Unsaturated γ-Butyrolactones,Naoto Chatani,Tsumoru Morimoto,Yoshiya Fukumoto,Shinji Murai,Journal of the American Chemical Society,Vol. 120,No. 21,p. 5335-5336,1998年06月,研究論文(学術雑誌)
  • CuまたはRu触媒を用いるアルコ ールの効率的なO<sub>2</sub>酸化,福本能也,Organometallic News,Vol. 21,No. 1,p. 21-21,1998年
  • Ru<sub>3</sub>(CO)<sub>12</sub>-Catalyzed Cyclocarbonylation of 1,6-Enynes to Bicyclo[3.3.0]octenones,Tsumoru Morimoto,Naoto Chatani,Yoshiya Fukumoto,Shinji Murai,The Journal of Organic Chemistry,Vol. 62,No. 11,p. 3762-3765,1996年
  • IRIDIUM-CATALYZED REACTION OF ACETYLENE HYDRAZONES WITH A HYDROSILANE AND CARBON-MONOXIDE - SYNTHESIS OF NITROGEN-HETEROCYCLES,Vol. 14,No. 9,p. 4418-4420,1995年09月
  • Synthesis of Dipeptides by the Photolytic Coupling of Chromium Aminocarbene Complexes with α-Amino Acid Esters. 2. Side Chain Functionalized and α,α-Disubstituted α-Amino Acid Esters and <i>N</i>-Methyl-α,α-dialkyl-α-amino Acid Esters,Catherine Dubuisson,Yoshiya Fukumoto,Louis S. Hegedus,Journal of the American Chemical Society,Vol. 117,No. 13,p. 3697-3704,1995年04月,研究論文(学術雑誌)
  • RING-OPENING SILYLFORMYLATION OF OXETANES CATALYZED BY [RHCL(CO)(2)](2)-AMINE,Vol. 489,No. 1-2,p. 215-219,1995年03月,研究論文(学術雑誌)
  • RUTHENIUM-CATALYZED REACTION OF 1,6-DIYNES WITH HYDROSILANES AND CARBON-MONOXIDE - A 3RD WAY OF INCORPORATING CO,Vol. 115,No. 24,p. 11614-11615,1993年12月
  • Rhodium-Catalyzed Ring-Opening Silylformylation of Epoxides Leading to β-Siloxy Aldehydes,Yoshiya Fukumoto,Naoto Chatani,Shinji Murai,Vol. 58,No. 16,p. 4187-4188,1993年07月