EN

基本情報

研究

社会活動

その他の活動

生越 專介

Ogoshi Sensuke

工学研究科 応用化学専攻,教授

keyword 有機金属化学

学歴

  • ~ 1993年,大阪大学,工学研究科,応用精密化学
  • ~ 1993年,大阪大学
  • ~ 1988年,大阪大学,工学部,応用精密化学
  • ~ 1988年,大阪大学

研究内容・専門分野

  • ナノテク・材料,無機・錯体化学

所属学会

  • 有機合成化学協会
  • 近畿化学協会
  • 日本化学会
  • Kinki Chemical Society, Japan
  • Chemical Society of Japan

論文

  • Triarylborane-Catalyzed Reductive N-Alkylation of Amines: A Perspective,Yoichi Hoshimoto,Sensuke Ogoshi,ACS Catalysis,American Chemical Society ({ACS}),Vol. 9,No. 6,p. 5439-5444,2019年06月
  • Complexation between MOTf (M = Li and Na) and N-Phosphine Oxide-substituted Imidazolylidenes via Coordination of the N-Phosphoryl Groups,Kinoshita Takuya,Sakuraba Mahiro,Hoshimoto Yoichi,Ogoshi Sensuke,CHEMISTRY LETTERS,Vol. 48,No. 3,p. 230-233,2019年03月
  • Nickel-catalyzed decarbonylation of: N -acylated N-heteroarenes,Vol. 10,No. 27,p. 6666-6671,2019年,研究論文(学術雑誌)
  • Main-Group-Catalyzed Reductive Alkylation of Multiply Substituted Amines with Aldehydes Using H2,Vol. 140,No. 23,p. 7292-7300,2018年06月13日,研究論文(学術雑誌)
  • Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks,Vol. 57,No. 1,p. 328-332,2018年01月02日,研究論文(学術雑誌)
  • Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate,Vol. 56,No. 51,p. 16191-16196,2017年12月18日,研究論文(学術雑誌)
  • Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene,Vol. 139,No. 49,p. 17795-17798,2017年12月,研究論文(学術雑誌)
  • Highly Atom Economical Molecular Transformation via Hetero-Nickelacycle,Vol. 90,No. 12,p. 1401-1406,2017年12月,研究論文(学術雑誌)
  • N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes,Vol. 23,No. 61,p. 15238-15243,2017年11月,研究論文(学術雑誌)
  • Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene,Vol. 56,No. 39,p. 11911-11915,2017年09月,研究論文(学術雑誌)
  • Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes,Vol. 139,No. 36,p. 12855-12862,2017年09月,研究論文(学術雑誌)
  • Nickel(0)-catalyzed Coupling Reactions of Carbonyls and Alkenes with Reducing Reagents Giving Six- and Seven-membered Benzocycloalkanols,Vol. 46,No. 8,p. 1096-1098,2017年08月,研究論文(学術雑誌)
  • Phosphorylation of Isocyanates and Aldehydes Mediated by Multifunctional N-Phosphine Oxide-substituted Imidazolylidenes,Vol. 46,No. 8,p. 1211-1213,2017年08月,研究論文(学術雑誌)
  • Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates,Yoichi Hoshimoto,Keita Ashida,Yukari Sasaoka,Ravindra Kumar,Ken Kamikawa,Xavier Verdaguer,Antoni Riera,Masato Ohashi,Sensuke Ogoshi,Angewandte Chemie International Edition,Wiley-Blackwell,Vol. 56,No. 28,p. 8206-8210,2017年07月,研究論文(学術雑誌)
  • Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates,Yoichi Hoshimoto,Keita Ashida,Yukari Sasaoka,Ravindra Kumar,Ken Kamikawa,Xavier Verdaguer,Antoni Riera,Masato Ohashi,Sensuke Ogoshi,Angewandte Chemie,Wiley-Blackwell,Vol. 129,No. 28,2017年07月
  • Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel,Vol. 8,2017年06月,研究論文(学術雑誌)
  • Nickel(0)-Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds,Vol. 56,No. 9,p. 2435-2439,2017年02月,研究論文(学術雑誌)
  • Kinetic and Theoretical Studies on Ni-0/N-Heterocyclic Carbene-Catalyzed Intramolecular Alkene Hydroacylation,Vol. 12,No. 3,p. 278-282,2017年02月,研究論文(学術雑誌)
  • Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand,Vol. 53,No. 17,p. 2630-2633,2017年,研究論文(学術雑誌)
  • Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic-Phosphinic Mixed Anhydride from CO2,Vol. 55,No. 52,p. 16075-16079,2016年12月,研究論文(学術雑誌)
  • Transition-Metal Mediated Transformations of Tetrafluoroethylene into Various Polyfluorinated Organic Compounds,Vol. 74,No. 11,p. 1047-1057,2016年11月,研究論文(学術雑誌)
  • Nickel-Catalyzed Enantioselective Synthesis of Cyclobutenes via [2+2] Cycloaddition of alpha,beta-Unsaturated Carbonyls with 1,3-Enynes,Vol. 48,No. 17,p. 2789-2794,2016年09月,研究論文(学術雑誌)
  • Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate,Vol. 55,No. 1,p. 341-344,2016年01月,研究論文(学術雑誌)
  • Nickel(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilanes,Vol. 52,No. 37,p. 6237-6240,2016年,研究論文(学術雑誌)
  • Nickel(0)/N-Heterocyclic Carbene-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Two Enones and an Alkyne: Access to Cyclohexenes with Four ContiguMccarrenous Stereogenic Centers,Vol. 17,No. 24,p. 6018-6021,2015年11月30日,研究論文(学術雑誌)
  • Pentacoordinated Carboxylate π-Allyl Nickel Complexes as Key Intermediates for the Ni-Catalyzed Direct Amination of Allylic Alcohols,Yusuke Kita,Hironobu Sakaguchi,Yoichi Hoshimoto,Daisuke Nakauchi,Yasuhito Nakahara,Jean François Carpentier,Sensuke Ogoshi,Kazushi Mashima,Chemistry - A European Journal,Vol. 21,No. 41,p. 14571-14578,2015年10月01日,研究論文(学術雑誌)
  • Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process,Vol. 137,No. 36,p. 11838-11845,2015年09月16日,研究論文(学術雑誌)
  • A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes,Vol. 54,No. 40,p. 11666-11671,2015年09月,研究論文(学術雑誌)
  • Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions,Vol. 44,No. 27,p. 12060-12073,2015年07月21日
  • Copper-mediated One-pot Synthesis of Trifluorostyrene Derivatives from Tetrafluoroethylene and Arylboronate,Vol. 44,No. 7,p. 1019-1021,2015年07月,研究論文(学術雑誌)
  • Catalytic Transformation of Aldehydes with Nickel Complexes through eta(2) Coordination and Oxidative Cyclization,Vol. 48,No. 6,p. 1746-1755,2015年06月
  • 2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C-C Bond-Forming Reactions,Vol. 34,No. 9,p. 1604-1607,2015年05月,研究論文(学術雑誌)
  • Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes,Vol. 137,No. 20,p. 6496-6499,2015年05月,研究論文(学術雑誌)
  • Synthesis, Characterization, and Unique Catalytic Activities of a Fluorinated Nickel Enolate,Vol. 137,No. 9,p. 3276-3282,2015年03月,研究論文(学術雑誌)
  • Catalytic Transformations of Fluorinated Olefins,Vol. 52,p. 197-215,2015年,研究論文(学術雑誌)
  • Regioselective C-F Bond Activation of Hexafluoropropylene on Palladium(0): Formation of a Cationic eta(2)-Perfluoroallylpalladium Complex,Vol. 53,No. 49,p. 13578-13582,2014年12月,研究論文(学術雑誌)
  • Highly Efficient Activation of Organosilanes with eta(2)-Aldehyde Nickel Complexes: Key for Catalytic Syntheses of Aryl-, Vinyl-, and Alkynyl-Benzoxasiloles,Vol. 136,No. 48,p. 16752-16755,2014年12月,研究論文(学術雑誌)
  • Nickel(0)-Catalyzed [2+2+1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to gamma-Lactams,Vol. 136,No. 45,p. 15877-15880,2014年11月,研究論文(学術雑誌)
  • Fluoroalkylcopper(I) Complexes Generated by the Carbocupration of Tetrafluoroethylene: Construction of a Tetrafluoroethylene-Bridging Structure,Vol. 136,No. 43,p. 15158-15161,2014年10月,研究論文(学術雑誌)
  • Base-Free Hiyama Coupling Reaction via a Group 10 Metal Fluoride Intermediate Generated by C-F Bond Activation,Vol. 33,No. 14,p. 3669-3672,2014年07月,研究論文(学術雑誌)
  • Synthesis of Cyclobutenes and Allenes by Cobalt-Catalyzed Cross-Dimerization of Simple Alkenes with 1,3-Enynes,Vol. 20,No. 22,p. 6613-6617,2014年05月,研究論文(学術雑誌)
  • Nickel-catalyzed synthesis of N-aryl-1,2-dihydropyridines by [2+2+2] cycloaddition of imines with alkynes through T-shaped 14-electron aza-nickelacycle key intermediates,Vol. 20,No. 14,p. 4105-4110,2014年04月01日,研究論文(学術雑誌)
  • One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(eta(6)-arene)Ni(N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni-0-NHC Unit,Vol. 33,No. 5,p. 1276-1282,2014年03月,研究論文(学術雑誌)
  • Palladium-Catalyzed Coupling Reaction of Perfluoroarenes with Diarylzinc Compounds,Vol. 20,No. 7,p. 2040-2048,2014年02月,研究論文(学術雑誌)
  • Bis-cyclooctatetraene tripalladium sandwich complexes,Vol. 50,No. 7,p. 820-822,2014年,研究論文(学術雑誌)
  • Nickel-catalyzed [2+2] Cycloaddition Reaction of Bulky Enones with Simple Alkynes. The Effect of Bulkiness of Substituent Attached at beta-Carbon,Vol. 42,No. 8,p. 904-905,2013年08月,研究論文(学術雑誌)
  • Preparation of Trifluorovinyl Compounds by Lithium Salt-promoted Monoalkylation of Tetrafluoroethene,Vol. 42,No. 8,p. 933-935,2013年08月,研究論文(学術雑誌)
  • Carbon-Fluorine Bond Activation of Tetrafluoroethylene on Palladium(0) and Nickel(0): Heat or Lewis Acidic Additive Promoted Oxidative Addition,Vol. 32,No. 13,p. 3631-3639,2013年07月,研究論文(学術雑誌)
  • Bridging π-coordination of pyrrole and indole over a Pd I-PdI bond,Vol. 49,No. 39,p. 4310-4312,2013年05月14日,研究論文(学術雑誌)
  • Ni-Catalyzed [4+3+2] Cycloaddition of Ethyl Cyclopropylideneacetate and Dienynes: Scope and Mechanistic Insights,Vol. 19,No. 10,p. 3415-3425,2013年03月,研究論文(学術雑誌)
  • Trinuclear palladium addition to unsaturated carbocycles,Vol. 42,No. 29,p. 10626-10632,2013年,研究論文(学術雑誌)
  • Palladium-Catalyzed Base-Free Suzuki-Miyaura Coupling Reactions of Fluorinated Alkenes and Arenes via a Palladium Fluoride Key Intermediate,No. 3,p. 443-447,2013年01月,研究論文(学術雑誌)
  • Nickel-Catalyzed Intermolecular [2+2] Cycloaddition of Conjugated Enynes with Alkenes,Vol. 134,No. 38,p. 15692-15695,2012年09月,研究論文(学術雑誌)
  • Selective Construction of Pd2Pt and PdPt2 Triangles in a Sandwich Framework: Carbocyclic Ligands as Scaffolds for a Mixed-Metal System,Vol. 18,No. 29,p. 8886-8890,2012年07月,研究論文(学術雑誌)
  • Synthesis of Five- and Six-Membered Benzocyclic Ketones through Intramolecular Alkene Hydroacylation Catalyzed by Nickel(0)/N-Heterocyclic Carbenes,Vol. 51,No. 43,p. 10812-10815,2012年,研究論文(学術雑誌)
  • Redox-induced reversible metal assembly through translocation and reversible ligand coupling in tetranuclear metal sandwich frameworks,Vol. 4,No. 1,p. 52-58,2012年01月,研究論文(学術雑誌)
  • Nickel-Catalyzed Dehydrogenative [4+2] Cycloaddition of 1,3-Dienes with Nitriles,Vol. 133,No. 45,p. 18018-18021,2011年11月,研究論文(学術雑誌)
  • Nickel-Catalyzed Formation of Cyclopentenone Derivatives via the Unique Cycloaddition of alpha,beta-Unsaturated Phenyl Esters with Alkynes,Vol. 133,No. 38,p. 14900-14903,2011年09月,研究論文(学術雑誌)
  • Oxidative Dinuclear Addition of a Pd-I-Pd-I Moiety to Arenes: Generation of mu-eta(3):eta(3)-Arene-Pd-2(II) Species,Vol. 133,No. 38,p. 14908-14911,2011年09月,研究論文(学術雑誌)
  • Intramolecular Oxidative Cyclization of Alkenes and Nitriles with Nickel(0),Vol. 30,No. 10,p. 2765-2774,2011年05月,研究論文(学術雑誌)
  • Nickel-Catalyzed Selective Conversion of Two Different Aldehydes to Cross-Coupled Esters,Vol. 133,No. 13,p. 4668-4671,2011年04月,研究論文(学術雑誌)
  • Palladium-catalyzed coupling reactions of tetrafluoroethylene with arylzinc compounds,Vol. 133,No. 10,p. 3256-3259,2011年03月16日,研究論文(学術雑誌)
  • Formation of Six-membered Aza-nickelacycles by Oxidative Addition of Cyclopropyl Imines to Nickel(0),Vol. 40,No. 3,p. 248-249,2011年03月,研究論文(学術雑誌)
  • Metallocenoids of platinum: Syntheses and structures of triangular triplatinum sandwich complexes of cycloheptatrienyl,Vol. 2,No. 1,p. 117-122,2011年,研究論文(学術雑誌)
  • [3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride,Vol. 50,No. 50,p. 12067-12070,2011年,研究論文(学術雑誌)
  • Formation and coordination modes of the C4E4 moiety (E = COOMe) bound to two palladium(II) moieties,Vol. 40,No. 10,p. 2383-2387,2011年,研究論文(学術雑誌)
  • Nickel(0)-Catalyzed Formation of Oxaaluminacyclopentenes via an Oxanickelacyclopentene Key Intermediate: Me2AlOTf-Assisted Oxidative Cyclization of an Aldehyde and an Alkyne with Nickel(0),Vol. 29,No. 23,p. 6534-6540,2010年12月,研究論文(学術雑誌)
  • Nickel-Catalyzed [2+2+2] Cycloaddition of Two Enones and an Alkyne,Vol. 12,No. 15,p. 3450-3452,2010年08月,研究論文(学術雑誌)
  • Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes,Vol. 132,No. 29,p. 10070-10077,2010年07月,研究論文(学術雑誌)
  • [3+3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient Alkylidenecyclopropanes,Vol. 29,No. 11,p. 2386-2389,2010年06月,研究論文(学術雑誌)
  • Nickel-catalyzed reactions of enone with ethylene,Vol. 232,No. 1,2010年,研究論文(国際会議プロシーディングス)
  • Nickel(0)-catalyzed [3 + 3] cyclodimerization of methylenecyclopropanes,Vol. 232,No. 1,2010年,研究論文(国際会議プロシーディングス)
  • Hydrofluoroarylation of alkynes with fluoroarenes,Vol. 39,No. 43,p. 10483-10494,2010年,研究論文(学術雑誌)
  • Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex,Vol. 46,No. 19,p. 3354-3356,2010年,研究論文(学術雑誌)
  • Nickel-catalyzed Reactions between Enone and Two Ethylenes,Vol. 38,No. 12,p. 1166-1167,2009年12月,研究論文(学術雑誌)
  • Nickel-Catalyzed Direct Conjugate Addition of Simple Alkenes to Enones,Vol. 131,No. 30,p. 10350-+,2009年08月,研究論文(学術雑誌)
  • Square Tetrapalladium Sheet Sandwich Complexes: Cyclononatetraenyl as a Versatile Face-Capping Ligand,Vol. 131,No. 29,p. 9888-+,2009年07月,研究論文(学術雑誌)
  • Reductive coupling of metal triangles in sandwich complexes,Vol. 130,No. 27,p. 8586-+,2008年07月,研究論文(学術雑誌)
  • Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine,Vol. 80,No. 5,p. 1115-1125,2008年05月,研究論文(学術雑誌)
  • Synthesis and structure of dipalladium complexes containing cyclooctatetraene and bicyclooctatrienyl ligands,Vol. 693,No. 5,p. 894-898,2008年03月,研究論文(学術雑誌)
  • Mono- and dipalladium movement on the π-conjugated five-carbon chain,Vol. 27,No. 2,p. 276-280,2008年01月28日,研究論文(学術雑誌)
  • Formation of an aza-nickelacycle by reaction of an imine and an alkyne with nickel(0): Oxidative cyclization, insertion, and reductive elimination,Vol. 46,No. 26,p. 4930-4932,2007年,研究論文(学術雑誌)
  • Discrete triangular tripalladium sandwich complexes of arenes,Vol. 46,No. 28,p. 5440-5443,2007年,研究論文(学術雑誌)
  • Sandwich complexes containing bent palladium chains,Vol. 45,No. 35,p. 5799-5803,2006年,研究論文(学術雑誌)
  • New chemistry of eta(3)-allenyl/propargyl complexes of palladium and platinum,Vol. 61,No. 1,p. 14-23,2003年01月,研究論文(学術雑誌)
  • Novel role of carbon monoxide as a Lewis acid catalyst for Friedel-Crafts reaction,Vol. 123,No. 35,p. 8626-8627,2001年09月,研究論文(学術雑誌)

MISC

  • Palladium-Catalyzed Cross-Coupling Reactions of Perfluoro Organic Compounds,Vol. 4,No. 3,p. 321-345,2014年09月,書評論文,書評,文献紹介等
  • Molecular Transformation via Nickelacycle Intermediate,Vol. 71,No. 1,p. 14-24,2013年01月,書評論文,書評,文献紹介等
  • Ni(O)-Catalyzed Formation of Azaaluminacyclopentenes via Azanickelacyclopentenes: A Unique Nickel/Aluminum Double Transmetalation Reaction,Vol. 131,No. 26,p. 9160-+,2009年07月
  • Ni(O)-Catalyzed Formation of Azaaluminacyclopentenes via Azanickelacyclopentenes: A Unique Nickel/Aluminum Double Transmetalation Reaction,Vol. 131,No. 26,p. 9160-+,2009年07月
  • Hetero-Nickelacycles as Key Reaction Intermediate in Catalytic Reactions,Vol. 67,No. 5,p. 507-516,2009年05月,書評論文,書評,文献紹介等
  • Synthesis and Reactivity of Six-Membered Oxa-Nickelacycles: A Ring-Opening Reaction of Cyclopropyl Ketones,Vol. 15,No. 39,p. 10083-10091,2009年
  • Synthesis and Reactivity of Six-Membered Oxa-Nickelacycles: A Ring-Opening Reaction of Cyclopropyl Ketones,Vol. 15,No. 39,p. 10083-10091,2009年
  • Intramolecular arylcyanation of alkenes catalyzed by nickel/AlMe2CI,Vol. 130,No. 39,p. 12874-+,2008年10月
  • Intramolecular arylcyanation of alkenes catalyzed by nickel/AlMe2CI,Vol. 130,No. 39,p. 12874-+,2008年10月
  • Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain,Vol. 4061,No. 34,p. 4061-4063,2008年09月
  • Structures of two haptotropic isomers generated by the sliding of 1,3,5-triene ligands on a Pd-Pd-Pd chain,Vol. 4061,No. 34,p. 4061-4063,2008年09月
  • Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde,Vol. 1347,No. 11,p. 1347-1349,2008年03月
  • Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde,Vol. 1347,No. 11,p. 1347-1349,2008年03月
  • A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands,Vol. 477,No. 4,p. 477-479,2008年
  • Formation of Acylruthenium Promoted by Coordination of AlMe3 to (η4-Cyclopentadienone)Ru(CO)3,Dalton Transaction,Vol. 2232,No. 17,p. 2232-2234,2008年
  • A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands,Vol. 477,No. 4,p. 477-479,2008年
  • Formation of acylruthenium promoted by coordination of AlMe3 to (eta(4)-cyclopentadienone)Ru(CO)(3),Vol. 2232,No. 17,p. 2232-2234,2008年
  • Reaction of (eta(2)-arylaldehyde)nickel(0) complexes with Me3SiX(X=OTf, Cl). Application to catalytic reductive homocoupling reaction of arylaldehyde,Vol. 62,No. 32,p. 7583-7588,2006年08月
  • Reversible carbon-carbon bond formation between 1,3-dienes and aldehyde or ketone on nickel(0),Vol. 128,No. 21,p. 7077-7086,2006年05月
  • Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition,Vol. 128,No. 16,p. 5350-5351,2006年04月
  • Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition,Vol. 128,No. 16,p. 5350-5351,2006年04月
  • AlMe3-promoted oxidative cyclization of eta(2)-alkene and eta(2)-ketone on nickel(0). Observation of intermediate in methyl transfer process,Vol. 127,No. 37,p. 12810-12811,2005年09月
  • AlMe3-promoted oxidative cyclization of eta(2)-alkene and eta(2)-ketone on nickel(0). Observation of intermediate in methyl transfer process,Vol. 127,No. 37,p. 12810-12811,2005年09月
  • Direct Observation of Oxidative Cyclization of η<sup>2</sup>-Alkene and η<sup>2</sup>-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me<sub>3</sub>SiOTf,Journal of the American Chemical Society,Vol. 126,No. 38,p. 11802-11803,2004年09月
  • Direct observation of oxidative Cyclization of eta(2)-alkene and eta(2)-aldehyde on Ni(0) center. Significant acceleration by addition of Me3SiOTf,Vol. 126,No. 38,p. 11802-11803,2004年09月
  • Reaction of eta(2)-enone and enal-platinum(0) complexes with Lewis acidic compounds,Vol. 689,No. 5,p. 894-898,2004年03月
  • Reaction of eta(2)-enone and enal-platinum(0) complexes with Lewis acidic compounds,Vol. 689,No. 5,p. 894-898,2004年03月
  • Convenient synthesis of Pt(0) olefin complexes by colorimetric reduction of Pt(II) complexes with SMI2,Vol. 689,No. 3,p. 662-665,2004年02月
  • Convenient synthesis of Pt(0) olefin complexes by colorimetric reduction of Pt(II) complexes with SMI2,Vol. 689,No. 3,p. 662-665,2004年02月
  • Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphine ligand,Vol. 23,No. 23,p. 2732-2733,2004年
  • Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphine ligand,Vol. inpress,No. 23,p. 2732-2733,2004年
  • Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphine ligand,Vol. inpress,No. 23,p. 2732-2733,2004年
  • Reaction of palladium and platinum complexes bearing alpha,beta-unsaturated carbonyl compounds with carbon electrophiles: Control over site of electrophilic attack, oxygen or metal,Vol. 22,No. 26,p. 5468-5472,2003年12月
  • Reaction of Palladium and Platinum Complexes Bearing α,β-Unsaturated Carbonyl Compounds with Carbon Electrophiles: Control over Site of Electrophilic Attack, Oxygen or Metal,MORITA M,INOUE K,OGOSHI S,KUROSAWA H,Organometallics,Vol. 22,No. 26,p. 5468-5472,2003年12月
  • Reaction of palladium and platinum complexes bearing alpha,beta-unsaturated carbonyl compounds with carbon electrophiles: Control over site of electrophilic attack, oxygen or metal,Vol. 22,No. 26,p. 5468-5472,2003年12月
  • Synthesis, Structure and Reactivity of η<sup>3</sup>-1-Hydroxyallyl Complex: Protonation of α, β-Unsaturated Carbonyl Compound Bound to Palladium (0) and Platinum (0),OGOSHI S,MORITA M,KUROSAWA H,Jouranl of the American Chemicul Society,Vol. 125,No. 30,p. 9020-9021,2003年07月
  • Synthesis, structure, and reactivity of a eta(3)-1-hydroxyallyl complex: Protonation of an alpha,beta-unsaturated carbonyl compound bound to palladium(0) and platinum(0),Vol. 125,No. 30,p. 9020-9021,2003年07月
  • New chemistry of η<sup>3</sup>-allenyl/propargyl complexes of palladium and platinum,Yuki Gosei Kagaku Kyokaishi,Vol. 61,No. 1,p. 16-25,2003年
  • New direction in organopalladium chemistry: Structure and reactivity of unsaturated hydrocarbon ligands bound to multipalladium units,Vol. 3,No. 2,p. 101-111,2003年
  • New chemistry of η<sup>3</sup>-allenyl/propargyl complexes of palladium and platinum,Vol. 61,No. 1,p. 16-25,2003年
  • New direction in organopalladium chemistry: Structure and reactivity of unsaturated hydrocarbon ligands bound to multipalladium units,Vol. 3,No. 2,p. 101-111,2003年
  • Palladium/Me3SiOTf-Catalyzed Bis-silylation of α,β-Unsaturated Carbonyl Compounds without Involving Oxidative Addition of Disilanes,OGOSHI S,TOMIYASU S,MORITA M,KUROSAWA H,Journal of the American Chemical Society,Vol. 124,No. 39,p. 11598-11599,2002年10月
  • Palladium/Me3SiOTf-catalyzed bis-silylation of alpha,beta-unsaturated carbonyl compounds without involving oxidative addition of disilane,Vol. 124,No. 39,p. 11598-11599,2002年10月
  • Novel role of carbon monoxide as a Lewis acid catalyst for Friedel-Crafts reaction (vol 123, pg 8626, 2001),Vol. 124,No. 7,p. 1553-1553,2002年02月
  • Key Process Palladium-Catalyzed Asymonetric Transformation of Propargyl Elctrophile. Racemization of Optically Active η<sup>3</sup>-Allenylpalladium,OGOSHI S,NISHIDA T,SHINAGAWA T,KUROSAWA H,The Journal of the American Chemical Society,Vol. 123,No. 29,p. 7164-7165,2001年07月
  • Key process in palladium-catalyzed asymmetric transformation of propargyl electrophiles. Racemization of optically active eta(1)-allenylpalladium(II),Vol. 123,No. 29,p. 7164-7165,2001年07月
  • Synthesis and destannylation of η<sup>3</sup>-1-stannylallylpalladium((]G0002[)),Journal of Organometallic Chemistry,Vol. 625,No. 1,p. 54-57,2001年04月15日
  • Synthesis and destannylation of η3-1-stannylallylpalladium(II) complexes,Vol. 625,No. 1,p. 54-57,2001年04月15日
  • Carbon-Carbon Bond Formation by Electrophilic Addition at Central Carbon of μ-η<sup>3</sup>-Allenyl/Propargyl Ligand on Pd-Pd Bond,OGOSHI S,NISHIDA T,TSUTSUMI K,OOI M,SHINAGAWA T,AKASAKA T,YAMANE M,KUROSAWA H,Journal of the American Chemical Society,Vol. 123,No. 14,p. 3223-3228,2001年04月
  • Carbon-carbon bond formation by electrophilic addition at the central carbon of the mu-eta(3)-allenyl/propargyl ligand on the Pd-Pd bond,Vol. 123,No. 14,p. 3223-3228,2001年04月
  • Coordination of Lewis Acid to η<sup>2</sup>-Enonepalladium(0)Leading to Continuous Structure Variation from η<sup>2</sup>-Olefin Type to η<sup>3</sup>-Allyl Type,OGOSHI S,YOSHIDA T,NISHIDA T,MORITA M,KUROSAWA H,Journal of the American Chemical Society,Vol. 123,No. 9,p. 1944-1950,2001年03月
  • Coordination of Lewis acid to eta(2)-enonepalladium(0) leading to continuous structure variation from eta(2)-olefin type to eta(3)-allyl type,Vol. 123,No. 9,p. 1944-1950,2001年03月
  • Intermolecular propargyl/allenyl group transfer from Pd(II) to Pt(0) and Pt(II) to Pd(0). Key reaction in metal-catalyzed isomerization between propargyl and allenyl metal complexes,Vol. 620,No. 1-2,p. 190-193,2001年02月
  • Intermolecular propargyl/allenyl group transfer from Pd(II) to Pt(0) and Pt(II) to Pd(0). Key reaction in metal-catalyzed isomerization between propargyl and allenyl metal complexes,Vol. 620,No. 1-2,p. 190-193,2001年02月
  • Co-catalyst dependent cycloisomerization or ring closing metathesis of α, ω-dienes catalyzed by arene ruthenium complex with side-arm alcohol,MIYAKI Y,ONISHI T,OGOSHI S,KUROSAWA H,Journal of Organometallic Chemistry,Vol. 616,No. 1-2,p. 135-139,2000年12月
  • Co-catalyst dependent cycloisomerization or ring closing metathesis of alpha,omega-dienes catalyzed by arene ruthenium complex with side-arm alcohol,Vol. 616,No. 1-2,p. 135-139,2000年12月
  • Kinetic Evidence for π-Complex Formation Prior to Oxidative Addition of Propargyl Halides to Triphenylphosphine-Platinum(0) Complexes(共著),NISHIDA T,OGOSHI S,TSUTSUMI K,FUKUNISHI Y,KUROSAWA H,Organometallics,Vol. 19,No. 22,p. 4488-4491,2000年10月
  • Kinetic evidence for pi-complex formation prior to oxidative addition of propargyl halides to triphenylphosphine - Platinum(0) complexes,Vol. 19,No. 22,p. 4488-4491,2000年10月
  • Synthesis and Characterization of Some Cationic η<sup>3</sup>-Propargylpalladium Complexes(共著),Bulletin of the Chemical Society of Japan,Vol. 72,No. 12,p. 2687-2692,1999年12月
  • Cross-Coupling Reactions Proceeding through η<sup>1</sup>-and η<sup>3</sup>-Propargyl/allenyl-palladium((]G0002[))Intermediate(共著),TSUTSUMI K,OGOSHI S,KAKIUCHI K,NISHIGUCHI S,KUROSAWA H,Inorganica Chimica Acta,Vol. 296,No. 1,p. 37-44,1999年12月
  • Synthesis and characterization of some cationic eta(3)-propargylpalladium complexes,Vol. 72,No. 12,p. 2687-2692,1999年12月
  • Cross-coupling reactions proceeding through eta(1)- and eta(3)-propargyl/allenyl-palladium(II) intermediates,Vol. 296,No. 1,p. 37-44,1999年12月
  • Carbon-carbon Bond Forming Reactions of μ-Vinylcarbenedipalladium Complexes,Chemistry Letters,No. 2,p. 123-124,1999年02月
  • Carbon-carbon bond forming reactions of μ-Vinylcarbenedipalladium complexes,No. 2,p. 123-124,1999年
  • Structure-reactivity relationship in allyl and 2-propynyl complexes of group 10 metals relevant to homogeneous catalysis,Vol. 71,No. 5,p. 973-984,1998年05月,書評論文,書評,文献紹介等
  • Radical Reactions of Titanium(III)Propargyl Complexes. Titanacydobutene Formation by Dimerization and by Regioselective Addition of Organic Free Radicals(共著),OGOSHI S,STRYKER J M,Journal of the American Chemical Society,Vol. 120,No. 14,p. 3514-3515,1998年04月
  • Radical reactions of titanium(III) propargyl complexes. Titanacyclobutene formation by dimerization and by regioselective addition of organic free radicals,Vol. 120,No. 14,p. 3514-3515,1998年04月
  • Synthesis, structure, and reactivity of neutral η3-propargylpalladium complexes,Vol. 120,No. 8,p. 1938-1939,1998年03月04日
  • Synthesis, Structure and Reactivity of Neutral η<sup>3</sup>-Prapargylpalladium Complexes(共著),TSUTSUMI K,OGOSHI S,NISHIGUCHI S,KUROSAWA H,Journal of the American Chemical Society,Vol. 120,No. 8,p. 1938-1939,1998年03月
  • Structure-Reactivity Relationship in Allyl and 2-Propynyl Complexes of Group 10 Metals Relevant to Homogeneous Catalysis(共著),Bulletin of the Chenical Society of Japan,Vol. 71,No. 5,p. 973-984,1998年
  • Mechanistic Studies on Mutual Isomerization of Propargyl-and Allenylplatinum(II)Complexes(共著),OGOSHI S,FUKUNISHI Y,TSUTSUMI K,KUROSAWA H,Inorganica Chimica Acta,Vol. 265,No. 1-2,p. 9-15,1997年11月
  • Mechanistic studies on mutual isomerization of propargyl- and allenylplatinum(II) complexes,Vol. 265,No. 1-2,p. 9-15,1997年11月
  • New Insights into Structures, Stability and Bonding of μ-Allyl Ligands Coordinated with Pd-Pd and Pd-Pt Fragments(共著),KUROSAWA H,HIRAKO K,NATSUME S,OGOSHI S,KANEHISA N,KAI Y,SAKAKI S,TAKEUCHI K,Organometallics,Vol. 15,No. 8,p. 2089-2097,1996年04月
  • New insights into structures, stability, and bonding of mu-allyl ligands coordinated with Pd-Pd and Pd-Pt fragments,Vol. 15,No. 8,p. 2089-2097,1996年04月
  • Synthesis and Reactivity of Palladium Multi Nudear Conplexes,Hyoumen,Vol. 34,No. 4,1996年
  • Synthesis and Reactivity of Palladium Multi Nudear Conplexes,Vol. 34,No. 4,1996年
  • Mvtual Isomerisation of η<sup>1</sup>-Allenyl and η<sup>1</sup>-Propargyl Complexes of Platinvm Via Five-coordinate η<sup>3</sup>-Allenyll Propargyl Intermediate.(共著),OGOSHI S,FUKUNISHI Y,TSUTSUMI K,KUROSAWA H,Journal of Chemical Society, Chemical Communication,No. 24,p. 2485-2486,1995年12月
  • Mutual isomerization of eta(1)-allenyl and eta(1)-propargyl complexes of platinum via a five-coordinate eta(3)-allenyl/propargyl intermediate,No. 24,p. 2485-2486,1995年12月
  • Palladium-catalyzed Reductive Homocoupling Reaction of 3-Silylpropargyl Carbonates New Entryinto Allene-Yne Compounds(共著),OGOSHI S,NISHIGUCHI S,TSUTSUMI K,KUROSAWA H,The Journal of Organic Cmistry,Vol. 60,No. 14,p. 4650-4652,1995年07月,記事・総説・解説・論説等(学術雑誌)
  • PALLADIUM-CATALYZED REDUCTIVE HOMOCOUPLING REACTION OF 3-SILYLPROPARGYL CARBONATES - NEW ENTRY INTO ALLENE-YNE COMPOUNDS,Vol. 60,No. 14,p. 4650-4652,1995年07月,記事・総説・解説・論説等(学術雑誌)
  • Syuthesis, Structure and Reactivity of 3<sup>3</sup>-Allenyllpropargyl Dinucleear Palladium Complexes(共著),OGOSHI S,TSUTSUMI K,OOI M,KUROSAWA H,Journal of the American Chemical Society,Vol. 117,No. 41,p. 10415-10416,1995年
  • Syuthesis and Structure of Cationic 3<sup>3</sup>-Allenyllpropargyl-palladium Complexes(共著),Journal of Organometallic Chemistry,Vol. 493,1995年
  • Synthesis, Structure and Reactivity of η3-Allenyl/ Propargyl Dinuclear Palladium Complexes,Vol. 117,No. 41,p. 10415-10416,1995年
  • Syuthesis and Structure of Cationic 3<sup>3</sup>-Allenyllpropargyl-palladium Complexes(共著),Vol. 493,1995年
  • Synthesis of η<sup>3</sup>-2-stannylmethylallylpalladium complexes and their destannylation leading to trimethylenemethanepalladium species,WATANABE S,OGOSHI S,KAKIUCHI K,KUROSAWA H,Journal of Organometallic Chemistry,Vol. 481,No. 1,p. 19-25,1994年11月
  • SYNTHESIS OF ETA(3)-2-STANNYLMETHYLALLYLPALLADIUM COMPLEXES AND THEIR DESTANNYLATION LEADING TO TRIMETHYLENEMETHANE-PALLADIUM SPECIES,Vol. 481,No. 1,p. 19-25,1994年11月
  • NUCLEOPHILIC-SUBSTITUTION AT THE CENTRAL ALLYL CARBON-ATOM OF A (PI-ALLYL)PLATINUM COMPLEX,Vol. 116,No. 9,p. 4125-4126,1994年05月,記事・総説・解説・論説等(学術雑誌)
  • Nuclephilic Substitution at the Central Allyl Carbon Atom of a (π-Allyl)platinum Complex(共著),OHE K,MATSUDA H,MORIMOTO T,OGOSHI S,CHATANI N,MURAI S,Journal of the American Chemical Society,Vol. 116,No. 9,p. 4125-4126,1994年
  • Redox Transmetalation Reaction Involving η<sup>3</sup>-Allyl Group Transfer from Palladium(II) to Platinum(O)(共著),Organometallics,Vol. 12,No. 7,p. 2869-2871,1993年07月
  • REDOX TRANSMETALATION REACTION INVOLVING ETA(3)-ALLYL GROUP-TRANSFER FROM PALLADIUM(II) TO PLATINUM(0),Vol. 12,No. 7,p. 2869-2871,1993年07月
  • Palladium-Catalyzed Reaction of 5-Methylene-1,3-dioxolan-2-ones. A New Access to and Reactivity of Oxatrimethylene-methane-Palladium(共著),The Journal of Organic Chemistry,Vol. 58,No. 5,p. 1173-1177,1993年02月
  • Convenient synthesis of [η<sup>3</sup>-1-(formyl)allyl]-and [η<sup>3</sup>-1-(dimethoxymethyl)allyl]palladium chlorides(共著),Journal of Organometallic Chemistry,Vol. 445,No. 1-2,p. C13-C14,1993年02月
  • Reaction of Palladium(II) Complexes with Allylsilanes : Convenient Synthesis of [η<sup>3</sup>-1-(Silyl)allyl] palladium Complexes(共著).,Organometallics,Vol. 12,No. 2,p. 578-579,1993年02月,記事・総説・解説・論説等(学術雑誌)
  • PALLADIUM-CATALYZED REACTION OF 5-METHYLENE-1,3-DIOXOLAN-2-ONES - A NEW ACCESS TO AND REACTIVITY OF OXATRIMETHYLENEMETHANE PALLADIUM,Vol. 58,No. 5,p. 1173-1177,1993年02月
  • Palladium-Catalyzed Reactions of Ketone α-Carbonate with Norbornenes. An Unusual Cyclopropanation(共著),OGOSHI S,MORIMOTO T,NISHIO K,OHE K,MURAI S,The Journal of Organic Chemistry,Vol. 58,No. 1,p. 9-10,1993年01月,速報,短報,研究ノート等(学術雑誌)
  • Convenient synthesis of [η<sup>3</sup>-1-(formyl)allyl]-and [η<sup>3</sup>-1-(dimethoxymethyl)allyl]palladium chlorides(共著),Vol. 445,C13/,,1993年
  • Reaction of Palladium(II) Complexes with Allylsilanes : Convenient Synthesis of [η<sup>3</sup>-1-(Silyl)allyl] palladium Complexes(共著).,Vol. 12,578/,,1993年
  • PALLADIUM-CATALYZED REACTIONS OF KETONE ALPHA-CARBONATES WITH NORBORNENES - AN UNUSUAL CYCLOPROPANATION,Vol. 58,No. 1,p. 9-10,1993年01月,速報,短報,研究ノート等(学術雑誌)
  • NOVEL SYN OXIDATIVE ADDITION OF ALLYLIC HALIDES TO OLEFIN COMPLEXES OF PALLADIUM(O) AND PLATINUM(O),Vol. 114,No. 22,p. 8417-8424,1992年10月
  • NOVEL SYN OXIDATIVE ADDITION OF ALLYLIC HALIDES TO OLEFIN COMPLEXES OF PALLADIUM(O) AND PLATINUM(O),Vol. 114,No. 22,p. 8417-8424,1992年10月
  • Reaction of 1-Silyl Dienol Silyl Ethens with Palladium(II) Complexes : Novel Formation of Several Types of (η<sup>3</sup>-Allyl) Palladium(II) Complexes via the Versatile Complex (η<sup>3</sup>-1-(Silylcarboryl)allyl) palladium Chloride,Organometallics,Vol. 10,No. 11,p. 3813-3818,1991年11月
  • REACTION OF 1-SILYL DIENOL SILYL ETHERS WITH PALLADIUM(II) COMPLEXES - NOVEL FORMATION OF SEVERAL TYPES OF (ETA-3-ALLYL)PALLADIUM(II) COMPLEXES VIA THE VERSATILE COMPLEX (ETA-3-1-(SILYLCARBONYL)ALLYL)PALLADIUM CHLORIDE,Vol. 10,No. 11,p. 3813-3818,1991年11月
  • Novel Decarbonyzation of a Formal Homoacyl-Palladium Linkage, PdCH(CR=CH<sub>2</sub>)C(0)SiR'<sub>3</sub>, Affording a PdCH(CR=CH<sub>2</sub>)SiR'<sub>3</sub> Moiety(共著),Organometallics,Vol. 9,No. 12,p. 3021-3022,1990年12月,記事・総説・解説・論説等(学術雑誌)
  • NOVEL DECARBONYLATION OF A FORMAL HOMOACYL PALLADIUM LINKAGE, PDCH(CR=CH2)C(O)SIR'3, AFFORDING A PDCH(CR=CH2)SIR'3 MOIETY,Vol. 9,No. 12,p. 3021-3022,1990年12月,記事・総説・解説・論説等(学術雑誌)
  • Allyl Group Transfer between M(II) and M(0) Centers (M=Pd, Pt) Proceeding through Anti Nucleophilic Attack at η<sup>3</sup>-Allyl Ligand,CHEMISTRY LETTERS,Vol. 1745,No. 9,p. 1745-1748,1990年09月
  • ALLYL GROUP TRANSFER BETWEEN M(II) AND M(O) CENTERS (M = PD, PT) PROCEEDING THROUGH ANTI NUCLEOPHILIC-ATTACK AT ETA-3-ALLYL LIGAND,Vol. 1745,No. 9,p. 1745-1748,1990年09月
  • Novel Dependency of Stereochemistry upon Metal, Ligand, and Solvent in Oxidative Addition of Allylic Chloride to Pd(0) and Pt(0) Complexes(共著),the Journal of the American Chemical Society,Vol. 112,No. 7,p. 2813-2814,1990年03月,記事・総説・解説・論説等(学術雑誌)
  • NOVEL DEPENDENCY OF STEREOCHEMISTRY UPON METAL, LIGAND, AND SOLVENT IN OXIDATIVE ADDITION OF ALLYLIC CHLORIDE TO PD(0) AND PT(0) COMPLEXES,Vol. 112,No. 7,p. 2813-2814,1990年03月,記事・総説・解説・論説等(学術雑誌)

特許・実用新案・意匠

  • Preparation of aromatic compounds by Friedel-Crafts reaction
  • Preparation of aromatic compounds by Friedel-Crafts reaction

作品

  • 遷移金属触媒-典型金属協奏作用に基づく立体選択的環化反応,2008年 ~
  • ニッケルにπ配位した炭素-ヘテロ原子二重結合の活性化と小分子への展開,2008年 ~
  • ニッケル触媒存在下、二酸化炭素を取り込む環状カーボネート合成,2007年 ~
  • 遷移金属触媒-典型金属協奏作用に基づく立体選択的環化反応,2007年 ~
  • ニッケルにπ配位した炭素-ヘテロ原子二重結合の活性化と小分子への展開,2007年 ~
  • 有機オキシアルミニウム化合物とニッケルの生み出す新しいカップリング反応,2007年 ~
  • 小さな遷移金属と大きな配位子で実現する酸化的環化反応,2007年 ~
  • ニッケルにπ配位した炭素-ヘテロ原子二重結合の活性化と合成展開,2006年 ~
  • 小さな遷移金属と大きな配位子で実現する酸化的環化反応,2006年 ~
  • グラファイト層間化合物の最小単位モデル合成とその可能性,2005年 ~

受賞

  • 日本化学会進歩賞,1999年
  • The Chemical Society of Japan Award for Young Chemists,1999年