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基本情報

研究

社会活動

その他の活動

西内 智彦

Nishiuchi Tomohiko

理学研究科 化学専攻,助教

keyword 芳香族性・反芳香族性,非平面π共役系炭化水素,構造有機化学

学歴

  • 2007年04月 ~ 2010年03月,首都大学東京大学院,理工学研究科,分子物質化学専攻

経歴

  • 2010年04月 ~ 2013年03月,マックスプランク高分子研究所,博士研究員(10年4月~12年2月)・プロジェクトリーダー(12年3月~13年3月)

研究内容・専門分野

  • ライフサイエンス,生物有機化学,構造有機化学
  • ナノテク・材料,構造有機化学、物理有機化学,構造有機化学

所属学会

  • 基礎有機化学会
  • 近畿化学協会
  • 有機合成化学協会
  • 日本化学会

論文

  • Synthesis of Anthracene‐Based Cyclic π‐Clusters and Elucidation of their Properties Originating from Congested Aromatic Planes,Tomohiko Nishiuchi,Kazuki Kisaka,Takashi Kubo,Angewandte Chemie International Edition,Wiley,Vol. 60,p. 5400-5406,2020年11月20日,研究論文(学術雑誌)
  • Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene,Tomohiko Nishiuchi,Ryuoh Ito,Erik Stratmann,Takashi Kubo,The Journal of Organic Chemistry,American Chemical Society (ACS),Vol. 85,No. 1,p. 179-186,2020年01月03日,研究論文(学術雑誌)
  • Anthracene-Attached Persistent Tricyclic Aromatic Hydrocarbon Radicals.,Nishiuchi T,Ito R,Takada A,Yasuda Y,Nagata T,Stratmann E,Kubo T,Chemistry, an Asian journal,Vol. 14,No. 10,p. 1830-1836,2019年01月,研究論文(学術雑誌)
  • Synthesis and Properties of a Highly Congested Tri(9-anthryl)methyl Radical,Tomohiko Nishiuchi,Takashi Kubo,Seito Aibara,Angewandte Chemie International Edition,Wiley,Vol. 57,No. 50,p. 16516-16519,2018年12月,研究論文(学術雑誌)
  • Intramolecular Interaction, Photoisomerization, and Mechanical C-C Bond Dissociation of 1,2-Di(9-anthryl)benzene and Its Photoisomer: A Fundamental Moiety of Anthracene-Based π-Cluster Molecules,Tomohiko Nishiuchi,Shin Ya Uno,Yasukazu Hirao,Takashi Kubo,Journal of Organic Chemistry,Vol. 81,No. 5,p. 2106-2112,2016年03月,研究論文(学術雑誌)
  • The Precise Synthesis of Phenylene-Extended Cyclic Hexa-peri-hexabenzocoronenes from Polyarylated [n]Cycloparaphenylenes by the Scholl Reaction,Martin Quernheim,Florian E. Golling,Wen Zhang,Manfred Wagner,Hans-Joachim Raeder,Tomohiko Nishiuchi,Klaus Muellen,ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,WILEY-V C H VERLAG GMBH,Vol. 54,No. 35,p. 10341-10346,2015年08月,研究論文(学術雑誌)
  • Design and Synthesis of New Stable Fluorenyl-Based Radicals,Yi Tian,Kazuyuki Uchida,Hiroyuki Kurata,Yasukazu Hirao,Tomohiko Nishiuchi,Takashi Kubo,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,AMER CHEMICAL SOC,Vol. 136,No. 36,p. 12784-12793,2014年09月,研究論文(学術雑誌)
  • Concise synthesis of 3D π-extended polyphenylene cylinders,Florian E. Golling,Florian E. Golling,Martin Quernheim,Manfred Wagner,Tomohiko Nishiuchi,Tomohiko Nishiuchi,Klaus Müllen,Angewandte Chemie - International Edition,Vol. 53,No. 6,p. 1525-1528,2014年02月,研究論文(学術雑誌)
  • Three-Dimensionally Arranged Cyclic p-Hexaphenylbenzene: Toward a Bottom-Up Synthesis of Size-Defined Carbon Nanotubes,Tomohiko Nishiuchi,Xinliang Feng,Volker Enkelmann,Manfred Wagner,Klaus Muellen,CHEMISTRY-A EUROPEAN JOURNAL,WILEY-V C H VERLAG GMBH,Vol. 18,No. 52,p. 16621-16625,2012年12月,研究論文(学術雑誌)
  • Acceleration of Electrochemical CO2 Reduction to Formate at the Sn/Reduced Graphene Oxide Interface,Takuya Tsujiguchi,Yusuke Kawabe,Samuel Jeong,Tatsuhiko Ohto,Suresh Kukunuri,Hirotaka Kuramochi,Yasufumi Takahashi,Tomohiko Nishiuchi,Hideki Masuda,Mitsuru Wakisaka,Kailong Hu,Ganesan Elumalai,Jun-ichi Fujita,Yoshikazu Ito,ACS Catalysis,American Chemical Society ({ACS}),p. 3310-3318,2021年03月19日,研究論文(学術雑誌)
  • Circularly Polarized Luminescence of a Stereogenic Curved Paraphenylene Anchoring a Chiral Binaphthyl in Solution and Solid State,Kenta Sato,Masashi Hasegawa,Yuki Nojima,Nobuyuki Hara,Tomohiko Nishiuchi,Yoshitane Imai,Yasuhiro Mazaki,Chemistry – A European Journal,Wiley,2020年11月23日,研究論文(学術雑誌)
  • Low-Temperature Removal of Dissociated Bromine by Silicon Atoms for an On-Surface Ullmann Reaction,Kewei Sun,Tomohiko Nishiuchi,Keisuke Sahara,Takashi Kubo,Adam S. Foster,Shigeki Kawai,The Journal of Physical Chemistry C,American Chemical Society (ACS),Vol. 124,No. 36,p. 19675-19680,2020年09月10日,研究論文(学術雑誌)
  • Three-dimensional graphene nanoribbons as a framework for molecular assembly and local probe chemistry,Shigeki Kawai,Ondřej Krejčí,Tomohiko Nishiuchi,Keisuke Sahara,Takuya Kodama,Rémy Pawlak,Ernst Meyer,Takashi Kubo,Adam S. Foster,Science Advances,Vol. 6,No. 9,2020年02月28日,研究論文(学術雑誌)
  • Synthesis of Cyclic Oligomers of 4,4 ''-Diethynyl-4 ',5 '-dioctyl-o-terphenyl Using Eglington Coupling Reaction: Formation of Large Cyclic Oligomers as Major Products under Standard Conditions,Ikumi Sako,Naoki Kishimoto,Hiroyuki Otani,Tomohiko Nishiuchi,Hideyuki Shimizu,Masahiko Iyoda,BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN,CHEMICAL SOC JAPAN,Vol. 90,No. 11,p. 1244-1250,2017年11月,研究論文(学術雑誌)
  • Elucidation of Intramolecular Through-Space Electronic Communication in a Propeller-Shaped Molecule,Takuya Kodama,Yasukazu Hirao,Tomohiko Nishiuchi,Takashi Kubo,CHEMPLUSCHEM,WILEY-V C H VERLAG GMBH,Vol. 82,No. 7,p. 1006-1009,2017年07月,研究論文(学術雑誌)
  • Direct quantitative measurement of the C═O⋅⋅⋅H–C bond by atomic force microscopy,Kawai Shigeki,Nishiuchi Tomohiko,Kodama Takuya,Spijker Peter,Pawlak Remy,Meier Tobias,Tracey John,Kubo Takashi,Meyer Ernst,Foster Adam S,Science Advances,Vol. 3,No. 5,2017年05月,研究論文(学術雑誌)
  • Stable Delocalized Singlet Biradical Hydrocarbon for Organic Field-Effect Transistors,Harunobu Koike,Masayuki Chikamatsu,Reiko Azumi,Jun'ya Tsutsumi,Kazumichi Ogawa,Wataru Yamane,Tomohiko Nishiuchi,Takashi Kubo,Tatsuo Hasegawa,Kaname Kanai,ADVANCED FUNCTIONAL MATERIALS,WILEY-V C H VERLAG GMBH,Vol. 26,No. 2,p. 277-283,2016年01月,研究論文(学術雑誌)
  • Improvement of properties of an ambipolar organic field-effect transistor by using a singlet biradicaloid film,Wataru Yamane,Harunobu Koike,Masayuki Chikamatsu,Takashi Kubo,Tomohiko Nishiuchi,Kaname Kanai,JAPANESE JOURNAL OF APPLIED PHYSICS,IOP PUBLISHING LTD,Vol. 55,No. 1,2016年01月,研究論文(学術雑誌)
  • Bent π-conjugated systems composed of three-dimensional benzoannulenes,Tomohiko Nishiuchi,Masahiko Iyoda,Chemical Record,Vol. 15,No. 1,p. 329-346,2015年02月,研究論文(学術雑誌)
  • Bent π-Conjugated System Composed of Two Dibenzocyclooctatetraene Units: Multifunctional Properties of Dynamic Molecular Tweezers in Solution and the Solid State,Tomohiko Nishiuchi,Masahiko Iyoda,Bulletin of the Chemical Society of Japan,The Chemical Society of Japan,Vol. 87,No. 9,p. 960-973,2014年09月15日,研究論文(学術雑誌)
  • Octafunctionalized Biphenylenes: Molecular Precursors for Isomeric Graphene Nanostructures,Florian Schlütter,Tomohiko Nishiuchi,Volker Enkelmann,Klaus Müllen,Angewandte Chemie International Edition,Wiley,Vol. 53,No. 6,p. 1538-1542,2014年02月03日,研究論文(学術雑誌)
  • Multifunctional π-expanded macrocyclic oligothiophene 6-mers and related macrocyclic oligomers,Masahiko Iyoda,Keita Tanaka,Hideyuki Shimizu,Masashi Hasegawa,Tohru Nishinaga,Tomohiko Nishiuchi,Yoshihito Kunugi,Takayuki Ishida,Hiroyuki Otani,Hiroyasu Sato,Koji Inukai,Kazukuni Tahara,Yoshito Tobe,Journal of the American Chemical Society,Vol. 136,No. 6,p. 2389-2396,2014年02月,研究論文(学術雑誌)
  • Solvent-induced crystalline-state emission and multichromism of a bent π-surface system composed of dibenzocyclooctatetraene units,Tomohiko Nishiuchi,Tomohiko Nishiuchi,Keita Tanaka,Yoshiyuki Kuwatani,Jooyoung Sung,Tohru Nishinaga,Dongho Kim,Masahiko Iyoda,Chemistry - A European Journal,Vol. 19,No. 13,p. 4110-4116,2013年03月,研究論文(学術雑誌)
  • π-Congested poly(paraphenylene) from 2,2′,6,6′-tetraphenyl- 1,1′-biphenyl units: Synthesis and structural characterization,Florian Schlütter,Tomohiko Nishiuchi,Volker Enkelmann,Klaus Müllen,Polymer Chemistry,Vol. 4,No. 10,p. 2963-2967,2013年,研究論文(学術雑誌)
  • Conjugated Molecular Belts Based on 3D Benzannulene Systems,Masahiko Iyoda,Yoshiyuki Kuwatani,Tohru Nishinaga,Masayoshi Takase,Tomohiko Nishiuchi,Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry,John Wiley and Sons,p. 311-342,2011年10月12日,論文集(書籍)内論文
  • McMURRY COUPLING OF DIFORMYLDITHIENYLACETYLENE: SYNTHESIS OF [24]-, [36]-, AND [48]ANNULENES COMPOSED OF THIOPHENE, ACETYLENE, AND ETHYLENE UNITS,Masahiko Iyoda,Pochi Huang,Tomohiko Nishiuchi,Masayoshi Takase,Tohru Nishinaga,HETEROCYCLES,PERGAMON-ELSEVIER SCIENCE LTD,Vol. 82,No. 2,p. 1143-+,2011年03月,研究論文(学術雑誌)
  • Dynamic Molecular Tweezers Composed of Dibenzocyclooctatetraene Units: Synthesis, Properties, and Thermochromism in Host-Guest Complexes,Tomohiko Nishiuchi,Yoshiyuki Kuwatani,Tohru Nishinaga,Vlasahiko Iyoda,CHEMISTRY-A EUROPEAN JOURNAL,WILEY-V C H VERLAG GMBH,Vol. 15,No. 28,p. 6838-6847,2009年
  • SYNTHESES, STRUCTURES, AND PROPERTIES OF BITHIOPHENOPHANES BRIDGED AT 1,8-POSITIONS OF NAPHTHALENES,Kazumi Nakao,Tomohiko Nishiuchi,Masahiko Iyoda,HETEROCYCLES,PERGAMON-ELSEVIER SCIENCE LTD,Vol. 76,No. 1,p. 727-745,2008年09月,研究論文(学術雑誌)
  • Synthesis and properties of cyclic [5]meta-phenyleneacetylene and its corresponding cyclophane polyone, [2(5)](1,3)cyclophanedecaone,Jun Yamakawa,Masanori Ohkoshi,Futoshi Takahashi,Tomohiko Nishiuchi,Yoshiyuki Kuwatani,Tohru Nishinaga,Masato Yoshida,Masahiko Iyoda,CHEMISTRY LETTERS,CHEMICAL SOC JAPAN,Vol. 37,No. 7,p. 784-785,2008年07月,研究論文(学術雑誌)

受賞

  • 若い世代の特別講演会,西内智彦,日本化学会第100回春季年会(2020),2020年03月
  • ダイセル研究企画賞,西内智彦,有機合成化学協会,2016年12月

講演・口頭発表等

  • Synthesis and Properties of Highly Congested Triacenomethyl Radicals,西内智彦,The 18th International Symposium on Novel Aromatic Compounds (ISNA-18),2019年07月21日
  • Tri(9-anthryl)methyl Species: Synthesis and Properties of The Highly Congested Novel Hydrocabons,西内智彦,The 10th Singapore International Chemistry Conference (SICC-10),2018年12月16日