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Nishiuchi Tomohiko

西内 智彦

Graduate School of Science Department of Chemistry, Assistant Professor

keyword Aromaticity and Anti-aromaticity,Nonplanar pi-conjugated PAHs,Physical Organic Chemistry

Education

  • 2007/04 - 2010/03, Tokyo Metropolitan University, Graduate School of Science and Engineering, Department of Chemistry

Research History

  • 2010/04 - 2013/03, Max Planck Institute for Polymer Research, Project Leader

Research Areas

  • Life sciences, Bioorganic chemistry
  • Nanotechnology/Materials, Structural/physical organic chemistry

Professional Memberships

  • 基礎有機化学会
  • KINKI CHEMICAL SOCIETY, JAPAN
  • THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
  • THE CHEMICAL SOCIETY OF JAPAN

Papers

  • Synthesis of Anthracene‐Based Cyclic π‐Clusters and Elucidation of their Properties Originating from Congested Aromatic Planes, Tomohiko Nishiuchi,Kazuki Kisaka,Takashi Kubo, Angewandte Chemie International Edition, Wiley, Vol. 60, p. 5400-5406, 2020/11/20
  • Switchable Conformational Isomerization of an Overcrowded Tristricyclic Aromatic Ene, Tomohiko Nishiuchi,Ryuoh Ito,Erik Stratmann,Takashi Kubo, The Journal of Organic Chemistry, American Chemical Society (ACS), Vol. 85, No. 1, p. 179-186, 2020/01/03
  • Anthracene-Attached Persistent Tricyclic Aromatic Hydrocarbon Radicals., Nishiuchi T,Ito R,Takada A,Yasuda Y,Nagata T,Stratmann E,Kubo T, Chemistry, an Asian journal, Vol. 14, No. 10, p. 1830-1836, 2019/01
  • Synthesis and Properties of a Highly Congested Tri(9-anthryl)methyl Radical, Tomohiko Nishiuchi,Takashi Kubo,Seito Aibara, Angewandte Chemie International Edition, Wiley, Vol. 57, No. 50, p. 16516-16519, 2018/12
  • Intramolecular Interaction, Photoisomerization, and Mechanical C-C Bond Dissociation of 1,2-Di(9-anthryl)benzene and Its Photoisomer: A Fundamental Moiety of Anthracene-Based it pi-Cluster Molecules, Tomohiko Nishiuchi,Shin-ya Uno,Yasukazu Hirao,Takashi Kubo, JOURNAL OF ORGANIC CHEMISTRY, AMER CHEMICAL SOC, Vol. 81, No. 5, p. 2106-2112, 2016/03
  • The Precise Synthesis of Phenylene-Extended Cyclic Hexa-peri-hexabenzocoronenes from Polyarylated [n]Cycloparaphenylenes by the Scholl Reaction, Martin Quernheim,Florian E. Golling,Wen Zhang,Manfred Wagner,Hans-Joachim Raeder,Tomohiko Nishiuchi,Klaus Muellen, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 54, No. 35, p. 10341-10346, 2015/08
  • Design and Synthesis of New Stable Fluorenyl-Based Radicals, Yi Tian,Kazuyuki Uchida,Hiroyuki Kurata,Yasukazu Hirao,Tomohiko Nishiuchi,Takashi Kubo, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 136, No. 36, p. 12784-12793, 2014/09
  • Concise Synthesis of 3D pi-Extended Polyphenylene Cylinders, Florian E. Golling,Martin Quernheim,Manfred Wagner,Tomohiko Nishiuchi,Klaus Muellen, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, WILEY-V C H VERLAG GMBH, Vol. 53, No. 6, p. 1525-1528, 2014/02
  • Three-Dimensionally Arranged Cyclic p-Hexaphenylbenzene: Toward a Bottom-Up Synthesis of Size-Defined Carbon Nanotubes, Tomohiko Nishiuchi,Xinliang Feng,Volker Enkelmann,Manfred Wagner,Klaus Muellen, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 18, No. 52, p. 16621-16625, 2012/12
  • Acceleration of Electrochemical CO2 Reduction to Formate at the Sn/Reduced Graphene Oxide Interface, Takuya Tsujiguchi,Yusuke Kawabe,Samuel Jeong,Tatsuhiko Ohto,Suresh Kukunuri,Hirotaka Kuramochi,Yasufumi Takahashi,Tomohiko Nishiuchi,Hideki Masuda,Mitsuru Wakisaka,Kailong Hu,Ganesan Elumalai,Jun-ichi Fujita,Yoshikazu Ito, ACS Catalysis, American Chemical Society ({ACS}), p. 3310-3318, 2021/03/19
  • Circularly Polarized Luminescence of a Stereogenic Curved Paraphenylene Anchoring a Chiral Binaphthyl in Solution and Solid State, Kenta Sato,Masashi Hasegawa,Yuki Nojima,Nobuyuki Hara,Tomohiko Nishiuchi,Yoshitane Imai,Yasuhiro Mazaki, Chemistry – A European Journal, Wiley, 2020/11/23
  • Low-Temperature Removal of Dissociated Bromine by Silicon Atoms for an On-Surface Ullmann Reaction, Kewei Sun,Tomohiko Nishiuchi,Keisuke Sahara,Takashi Kubo,Adam S. Foster,Shigeki Kawai, The Journal of Physical Chemistry C, American Chemical Society (ACS), Vol. 124, No. 36, p. 19675-19680, 2020/09/10
  • Three-dimensional graphene nanoribbons as a framework for molecular assembly and local probe chemistry, Shigeki Kawai,Ondřej Krejčí,Tomohiko Nishiuchi,Keisuke Sahara,Takuya Kodama,Rémy Pawlak,Ernst Meyer,Takashi Kubo,Adam S. Foster, Science Advances, Vol. 6, No. 9, 2020/02/28
  • Synthesis of Cyclic Oligomers of 4,4 ''-Diethynyl-4 ',5 '-dioctyl-o-terphenyl Using Eglington Coupling Reaction: Formation of Large Cyclic Oligomers as Major Products under Standard Conditions, Ikumi Sako,Naoki Kishimoto,Hiroyuki Otani,Tomohiko Nishiuchi,Hideyuki Shimizu,Masahiko Iyoda, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, CHEMICAL SOC JAPAN, Vol. 90, No. 11, p. 1244-1250, 2017/11
  • Elucidation of Intramolecular Through-Space Electronic Communication in a Propeller-Shaped Molecule, Takuya Kodama,Yasukazu Hirao,Tomohiko Nishiuchi,Takashi Kubo, CHEMPLUSCHEM, WILEY-V C H VERLAG GMBH, Vol. 82, No. 7, p. 1006-1009, 2017/07
  • Direct quantitative measurement of the C=O center dot center dot center dot H-C bond by atomic force microscopy, Shigeki Kawai,Tomohiko Nishiuchi,Takuya Kodama,Peter Spijker,Remy Pawlak,Tobias Meier,John Tracey,Takashi Kubo,Ernst Meyer,Adam S. Foster, SCIENCE ADVANCES, AMER ASSOC ADVANCEMENT SCIENCE, Vol. 3, No. 5, 2017/05
  • Stable Delocalized Singlet Biradical Hydrocarbon for Organic Field-Effect Transistors, Harunobu Koike,Masayuki Chikamatsu,Reiko Azumi,Jun'ya Tsutsumi,Kazumichi Ogawa,Wataru Yamane,Tomohiko Nishiuchi,Takashi Kubo,Tatsuo Hasegawa,Kaname Kanai, ADVANCED FUNCTIONAL MATERIALS, WILEY-V C H VERLAG GMBH, Vol. 26, No. 2, p. 277-283, 2016/01
  • Improvement of properties of an ambipolar organic field-effect transistor by using a singlet biradicaloid film, Wataru Yamane,Harunobu Koike,Masayuki Chikamatsu,Takashi Kubo,Tomohiko Nishiuchi,Kaname Kanai, JAPANESE JOURNAL OF APPLIED PHYSICS, IOP PUBLISHING LTD, Vol. 55, No. 1, 2016/01
  • Bent pi-Conjugated Systems Composed of Three-Dimensional Benzoannulenes, Tomohiko Nishiuchi,Masahiko Iyoda, CHEMICAL RECORD, WILEY-V C H VERLAG GMBH, Vol. 15, No. 1, p. 329-346, 2015/02
  • Bent π-Conjugated System Composed of Two Dibenzocyclooctatetraene Units: Multifunctional Properties of Dynamic Molecular Tweezers in Solution and the Solid State, Tomohiko Nishiuchi,Masahiko Iyoda, Bulletin of the Chemical Society of Japan, The Chemical Society of Japan, Vol. 87, No. 9, p. 960-973, 2014/09/15
  • Octafunctionalized Biphenylenes: Molecular Precursors for Isomeric Graphene Nanostructures, Florian Schlütter,Tomohiko Nishiuchi,Volker Enkelmann,Klaus Müllen, Angewandte Chemie International Edition, Wiley, Vol. 53, No. 6, p. 1538-1542, 2014/02/03
  • Multifunctional pi-Expanded Macrocyclic Oligothiophene 6-Mers and Related Macrocyclic Oligomers, Masahiko Iyoda,Keita Tanaka,Hideyuki Shimizu,Masashi Hasegawa,Tohru Nishinaga,Tomohiko Nishiuchi,Yoshihito Kunugi,Takayuki Ishida,Hiroyuki Otani,Hiroyasu Sato,Koji Inukai,Kazukuni Tahara,Yoshito Tobe, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMER CHEMICAL SOC, Vol. 136, No. 6, p. 2389-2396, 2014/02
  • Solvent-Induced Crystalline-State Emission and Multichromism of a Bent pi-Surface System Composed of Dibenzocyclooctatetraene Units, Tomohiko Nishiuchi,Keita Tanaka,Yoshiyuki Kuwatani,Jooyoung Sung,Tohru Nishinaga,Dongho Kim,Masahiko Iyoda, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 19, No. 13, p. 4110-4116, 2013/03
  • pi-Congested poly(paraphenylene) from 2,2 ',6,6 '-tetraphenyl-1,1 '-biphenyl units: synthesis and structural characterization, Florian Schluetter,Tomohiko Nishiuchi,Volker Enkelmann,Klaus Muellen, POLYMER CHEMISTRY, ROYAL SOC CHEMISTRY, Vol. 4, No. 10, p. 2963-2967, 2013
  • Conjugated Molecular Belts Based on 3D Benzannulene Systems, Masahiko Iyoda,Yoshiyuki Kuwatani,Tohru Nishinaga,Masayoshi Takase,Tomohiko Nishiuchi, Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry, John Wiley and Sons, p. 311-342, 2011/10/12
  • McMURRY COUPLING OF DIFORMYLDITHIENYLACETYLENE: SYNTHESIS OF [24]-, [36]-, AND [48]ANNULENES COMPOSED OF THIOPHENE, ACETYLENE, AND ETHYLENE UNITS, Masahiko Iyoda,Pochi Huang,Tomohiko Nishiuchi,Masayoshi Takase,Tohru Nishinaga, HETEROCYCLES, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 82, No. 2, p. 1143-+, 2011/03
  • Dynamic Molecular Tweezers Composed of Dibenzocyclooctatetraene Units: Synthesis, Properties, and Thermochromism in Host-Guest Complexes, Tomohiko Nishiuchi,Yoshiyuki Kuwatani,Tohru Nishinaga,Vlasahiko Iyoda, CHEMISTRY-A EUROPEAN JOURNAL, WILEY-V C H VERLAG GMBH, Vol. 15, No. 28, p. 6838-6847, 2009
  • SYNTHESES, STRUCTURES, AND PROPERTIES OF BITHIOPHENOPHANES BRIDGED AT 1,8-POSITIONS OF NAPHTHALENES, Kazumi Nakao,Tomohiko Nishiuchi,Masahiko Iyoda, HETEROCYCLES, PERGAMON-ELSEVIER SCIENCE LTD, Vol. 76, No. 1, p. 727-745, 2008/09
  • Synthesis and properties of cyclic [5]meta-phenyleneacetylene and its corresponding cyclophane polyone, [2(5)](1,3)cyclophanedecaone, Jun Yamakawa,Masanori Ohkoshi,Futoshi Takahashi,Tomohiko Nishiuchi,Yoshiyuki Kuwatani,Tohru Nishinaga,Masato Yoshida,Masahiko Iyoda, CHEMISTRY LETTERS, CHEMICAL SOC JAPAN, Vol. 37, No. 7, p. 784-785, 2008/07

Awards

  • 若い世代の特別講演会, 西内智彦, 日本化学会第100回春季年会(2020), 2020/03
  • ダイセル研究企画賞, 西内智彦, 有機合成化学協会, 2016/12

Presentations

  • Synthesis and Properties of Highly Congested Triacenomethyl Radicals, Tomohiko Nishiuchi, The 18th International Symposium on Novel Aromatic Compounds (ISNA-18), 2019/07/21
  • Tri(9-anthryl)methyl Species: Synthesis and Properties of The Highly Congested Novel Hydrocabons, Tomohiko Nishiuchi, The 10th Singapore International Chemistry Conference (SICC-10), 2018/12/16